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State-selective Dissociation of Water Molecules on MgO Films Using LT-STM

  • Shin, Hyung-Joon;Jung, J.;Motobayashi, K.;Kim, Y.;Kawai, M.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.112-112
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    • 2011
  • The interaction of water molecules with solid surfaces has been a subject of considerable interests, due to its importance in the fields from atmospheric and environmental phenomena to biology, catalysis and electrochemistry [1,2]. Among various kinds of surfaces, a lot of theoretical and experimental studies have been performed regarding water on MgO(100), however, to date, there has been no direct observation of water molecules on MgO by scanning tunneling microscope (STM) as compared with those on metal surface. Here, we will present the direct observation and manipulation of single water molecules on ultrathin MgO(100) films using low-temperature scanning tunneling microscope (LT-STM) [3]. Our results rationalize the previous theoretical predictions of isolated water molecules on MgO including the optimum adsorption sites and non-dissociative adsorption of water. Moreover, we were able to dissociate a water molecule by exciting the vibrational mode of water, which is unattainable on metal surfaces. The enhanced residual time of tunneling electrons in molecules on the insulating film is responsible for this unique pathway toward dissociation of water.

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A Study on Application of Bottom Ash with Grouting Improvement and Waterproof Grouting (지반보강 및 차수 그라우팅재로서의 Bottom Ash 활용에 관한 연구)

  • Kwon, Hyuk-Doo;Lee, Bum-Jun;Doh, Young-Gon;Lee, Song
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.1075-1082
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    • 2008
  • Recently, coal ashes which are increasing annually are buried in ash ponds as industrial wastes. However, buried coal ashes can pollute ground water and ground due to leachate from coal ashes, which are serious environmental problem. Even though a lot of researches on recycling of coal ashes have been conducted, only 15% of coal ashes are recycled up to now. And those recycled coal ashes are not bottom ashes but fly ashes. So in this study, it was proved that Bottom Ash can be used as an alternative material to O.P.C(Ordinary Portland Cement) according to laboratory test results and test field construction. Also bottom ash is more economical and environmentally friendly than O.P.C.

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Development of the Fabrication Technology of High Tc Superconductor for Electrical Energy Storage (전기 에너지 저장을 위한 초전도 나노 합성 기술)

  • Lee, Sang-Heon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.9
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    • pp.442-445
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    • 2006
  • In order to realize the commercial application of HTSC materials, it is necessary to develop the fabrication process of high Tc oxide superconductor materials with desired shape and for practical application and high critical current density as well as good mechanical strength which can withstand high lorenz force generated at high magnetic field. Much studies have been concentrated to develop the fabrication technique for high critical current density but still there are a lot of gap which should be overcome for large scale application of HTSC materials at liquid nitrogen temperature. Recently some new fabrication techniques have been developed for YBaCuO bulk superconductor with high mechanical strength and critical current density. In this project, the establishment of fabrication condition and additive effects of second elements were examined so as to improve the related properties to the practical use of YBaCuO superconductor, and we reported the production of the YBaCuO high Tc superconductor by the pyrolysis method.

Fabrication Technology of high Tc Superconductor for Electrical Equipment (전력기기 초전도 합성기술)

  • Lee, Sang-Heon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.7
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    • pp.364-366
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    • 2006
  • In order to realize the commercial application of HTSC materials, it is necessary to develop the fabrication process of high Tc oxide superconductor materials with desired shape and for practical application and high critical current density as well as good mechanical strength which can withstand high lorenz force generated at high magnetic field. Much studies have been concentrated to develop the fabrication technique for high critical current density but still there are a lot of gap which should be overcome for large scale application of HTSC materials at liquid nitrogen temperature. Recently some new fabrication techniques have been developed for YBaCuO bulk superconductor with high mechanical strength and critical current density. In this project, the establishment of fabrication condition and additive effects of second elements were examined so as to improve the related properties to the practical use of YBaCuO superconductor, and we reported the production of the YBaCuO high Tc superconductor by the pyrolysis method.

KIC06118779 and KIC08682849: Extremely low mass ratio contact binaries with quasi-cyclically varying O'Connell effects and strong anti-correlations in their ETV diagrams

  • Jeong, Min-Ji;Kim, Chun-Hwey
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.78.3-78.3
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    • 2016
  • The Kepler mission of NASA has enabled to discover a lot of new W UMa-type binaries with continuous light curves measured with unprecedented accuracy. Interestingly, their eclipsing time variation (hereafter ETV) diagrams show anti-correlation between primary and secondary minima, presumably occurred by continuous spot variation (Tran et al. 2013; Balaji et al. 2014). Two active Kepler binaries (KIC06118779 & KIC08682849), reported as showing the anti-correlation in ETV diagram, were investigated to see that the anti-correlations are correlated with time-variable O'connell effects appeared in their light curves. As a result, it was found that the O'connell effects for two binary stars have varied in quasi-sinusoidal ways similar to the patterns of their anti-correlation variations. In addition, our light curve syntheses of two binary stars with the latest version of the Wilson-Devinney code (Wilson & devinney 1971) show that they are very deep-contact binary system with extremely low mass ratios.

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Comparative Study and Simulation of P&O Algorithm using Boost Converter for a Photovoltaic System

  • Ganzorig, Batdelger;Song, Han-Jung
    • Journal of the Korean Society of Industry Convergence
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    • v.22 no.4
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    • pp.395-403
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    • 2019
  • The excessive need of power is creating an unbalance situation in power sector, where solar energy is one of the best solutions among other energy sources to mitigate this demand. It is globally accepted because of its flexibility and long life compared to others. A lot research is going on to enhance the energy efficiency by introducing photovoltaic (PV) power generation technology, but still irradiation of PV power is the major problem. In this manuscript, we have designed PV module using single diode methodology and also the solar conversion efficiency was boosted with maximum power point tracking (MPPT) by using perturb and observe (P&O) algorithm. The simulation was done for $1000W/m^2$ and $800W/m^2$ at solar irradiance in cell temperature of 25C and 40C degree levels in PSIM tool.

A Simulation of Vehicle Parking Distribution System for Local Cultural Festival with Queuing Theory and Q-Learning Algorithm (대기행렬이론과 Q-러닝 알고리즘을 적용한 지역문화축제 진입차량 주차분산 시뮬레이션 시스템)

  • Cho, Youngho;Seo, Yeong Geon;Jeong, Dae-Yul
    • The Journal of Information Systems
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    • v.29 no.2
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    • pp.131-147
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    • 2020
  • Purpose The purpose of this study is to develop intelligent vehicle parking distribution system based on LoRa network at the circumstance of traffic congestion during cultural festival in a local city. This paper proposes a parking dispatch and distribution system using a Q-learning algorithm to rapidly disperse traffics that increases suddenly because of in-bound traffics from the outside of a city in the real-time base as well as to increase parking probability in a parking lot which is widely located in a city. Design/methodology/approach The system get information on realtime-base from the sensor network of IoT (LoRa network). It will contribute to solve the sudden increase in traffic and parking bottlenecks during local cultural festival. We applied the simulation system with Queuing model to the Yudeung Festival in Jinju, Korea. We proposed a Q-learning algorithm that could change the learning policy by setting the acceptability value of each parking lot as a threshold from the Jinju highway IC (Interchange) to the 7 parking lots. LoRa Network platform supports to browse parking resource information to each vehicle in realtime. The system updates Q-table periodically using Q-learning algorithm as soon as get information from parking lots. The Queuing Theory with Poisson arrival distribution is used to get probability distribution function. The Dijkstra algorithm is used to find the shortest distance. Findings This paper suggest a simulation test to verify the efficiency of Q-learning algorithm at the circumstance of high traffic jam in a city during local festival. As a result of the simulation, the proposed algorithm performed well even when each parking lot was somewhat saturated. When an intelligent learning system such as an O-learning algorithm is applied, it is possible to more effectively distribute the vehicle to a lot with a high parking probability when the vehicle inflow from the outside rapidly increases at a specific time, such as a local city cultural festival.

A Study on the Business Investment and Operation of O2O (Online-To-Offline) Combined Services by Industry (산업별 O2O 결합 서비스의 비즈니스 투자 및 운영에 관한 연구)

  • Jung, Byoungho;Joo, Hyungkun
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.18 no.2
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    • pp.93-110
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    • 2022
  • The purpose of this study is to explore business investment and operation of O2O (Online-To-Offline) combined service. The study will analyze the necessary factors for growing the business by dividing the O2O service by industry. The Online-to-Offline is a method of inducing purchases of products and services by connecting between online and offline This research methodology organized the four stages of the analysis process. The analysis of all stages was performed with association rules in big data techniques. It is divided into the start-up period, growth period, maturity period, and decline period, and analysis is conducted on the business investment, expenditure cost, business operation, and conflict factors. As the research result, the first analysis has shown commonality with government subsidies, bank loans, and personal funds in all industries. The second analysis showed a lot of expenditure on labor costs of internal employees, marketing/sales, facility facilities, equipment, and equipment purchase costs. The third analysis showed difficulty in raising the investment resources necessary for business operations in all industries. The last analysis showed conflicts in the industry, businesses license, legal systems, and small business owners in all industries. This study contributed to the abundance and diversity of research methodologies in management information systems using association rules. In addition, the description of organizational development theory was updated while explaining the business investment and operation of O2O combined services. In practical implication, the O2O services include environmental factors that cause convergence between industries. Accordingly, this is required for new O2O services through new laws and systems and reorganization of existing laws and regulations.

SYNTHESIS AND CHARACTERIZATION OF THE POLYCATIONS FOR THE PREPAEATION OF POLYION COMPLEX MEMBRANS

  • Jegal, J.G.;park, Y.I.;Kim, J.H.;Lee, K.H.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.10a
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    • pp.58-58
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    • 1993
  • Pervaporation has become important as a method to separate liquid mixtures, sepecially azeotropic and close boiling-point mixtures. Especially, water-alcohol separations have been carried out a lot because of the practical interests in the industries. However, outstanding membranes with high selectivity and high permeability have not been available in common use yet. In order to separate selectively out the water mixed with alcohols with an aim of the purification of the alcohols, a membrane has tO have excellent affinity to water. Among the hydrophilic polymers, polyacrylic acid and poly(vinyl alcohol) are used widely. In recent years, ionomers and polyion complexes, better hydrophitic materials, start to be used. The polyion complex membranes, consisting of polyacrylic acid (PAA) and polycation, showed excellent permeation rates and selectivities. It was known that among the polycations, ioneries, which have quaternary ammonium groups in the backbone chain, were more effective in giving membranes of higher permselectivities. On this base, syntheses and characterizations of the polycations, with different chemical structures from the published ones, for the polyion complex membrane formation were studied in this paper.

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The Extraction of Manganese from the Medium-Low Carbon Ferromanganese Dust with Nitric Acid (질산에 의한 중.저탄소페로망간제조분진에 함유된 망간의 침출)

  • 이계승;한기천;송영준;신강호;조동성
    • Resources Recycling
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    • v.9 no.1
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    • pp.21-26
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    • 2000
  • Extraction of manganese was investigated with nitric acid from the dust which was generated in the AOD process producing a medium-low carbon ferromanganese from a high carbon ferromanganese. Content of manganese oxide in the dust was about 90%, and phase of it was confirmed as $Mn_3O_4$, The $Mn_3O_4$ particles was agglomerated as spherical shape, and had a lot of pore and crack inside. Maximum recovery of Mn from the sample in the leaching step was about 67% and residue was the amorphous $MnO_2$. The extraction of Mn increased with increasing temperature, but decreased in proportion to concentration of nitric acid. The extraction rate was in good agreement with the pore diffusion model.

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