• Title/Summary/Keyword: O-D analysis

Search Result 1,898, Processing Time 0.031 seconds

Luminescence properties of a new $Tb^{3+}$ ion activated long persistent phosphor (새로운 $Tb^{3+}$ 이온 활성 축광성 형광체의 발광 특성)

  • Park, Byeong-Seok;Choi, Jong-Geon
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.19 no.3
    • /
    • pp.130-134
    • /
    • 2009
  • A new long persistent phosphors of $CaZrO_3$ was synthesized at high temperature with weak reduction atmosphere by a traditional solid state reaction method. Photoluminescence spectra analysis showed that the $CaZrO_3$ doped with $Tb^{3+}$ emitted green-yellow emission caused by the energy level transition from the $^5D_3$ and $^5D_4$ to $^7F_1{\sim}^7F_6$. The main emission spectra of 542 nm peak by the $^5D_4{\rightarrow}^7F_5$ transition was revealed through synthesizing at high temperature in $N_2$ gas atmosphere. The afterglow emission spectra of $CaZrO_3:Tb^{3+}$ long persistent phosphores arise at 546 nm peak of narrow range. After the 254 nm ultraviolet light excitation source was switched off, the green-yellow long persistent phosphor can be observed which could last for 8 h in the limit of light perception of dark-adapted human eyes ($0.32\;mcd/m^2$).

Synthesis and Characteristics of Type-II ZnO/ZnSe Core/Shell Heterostructures for High Efficient Photocatalytic Activity (Type-II ZnO/ZnSe 코어/쉘 이종 구조 합성 및 광촉매활성 평가)

  • Lee, Woo-Hyoung;Choi, Kwang-Il;Kang, Dong-Cheon;Beak, Su-Woong;Lee, Suk-Ho;Lim, Cheol-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.27 no.3
    • /
    • pp.178-183
    • /
    • 2014
  • Recently, various type of nanomaterials such as nanorod, nanowire, nanotube and their core/shell nanostructures have attracted much attention in photocatalyst due to their unique properties. Among them, Type-II core/shell heterostructures have extensively studied because it has exhibited improved electrical and optical properties against their single-component nanostructure. Such structures are expected to offer high absorption efficiency and fast charge transport due to their stepwised energetic combination and large internal surface area. Thus, it has been considered as potential candidates for high efficient photocatalytic activity. In this work, we introduce a novel chemical conversion process to synthesize Type-II ZnO/ZnSe core/shell heterostructures. A plausible conversion mechanism to ZnO/ZnSe core/shell heterostructres was proposed based on SEM, XRD, TEM and XPS analysis. The ZnO/ZnSe heterostructures exhibited excellent photocatalytic activity toward the decomposition of RhB dye compared to the ZnO nanorod arrays due to enhanced light absorption and the type-II cascade band structure.

Influence of post-annealing on DC degradation characteristics in $ZnO-Bi_2O_3$ Varistor ($ZnO-Bi_2O_3$ 계 바리스터에서 후열처리가 DC 열화 특성에 미치는 영향)

  • 소순진;김영진;소병문;박춘배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1999.05a
    • /
    • pp.333-336
    • /
    • 1999
  • The relationship between the DC degradation characteristics of the $ZnO-Bi_2O_3$ varistor and post-annealing is investigated in this study. $ZnO-Bi_2O_3$ varistors containing $SiO_2$ range 0.3 mol% were fabricated by standard ceramic techniques. The post- annealing is performed at $550^{\circ}C$ for 0, 1.5 and 5h. A little phase transition is found according to the analysis of X-ray diffraction. DC degradation tests were conducted at $115\pm3^{\circ}C$ for periods up to 22h. Current-voltage analysis was used to determine nonlinear coefficients($\alpha$). Capacitance-voltage analysis enable the donor density($N_d$) and the barrier height($E_B$) to be determined. From above analysis, it is found that the past-annealing for 5h improved degradation characteristics in $ZnO-Bi_2O_3$ with Si additive.

  • PDF

Analysis of a Fire Case Caused by Heat Generation due to Cu2O Breeding (아산화동증식 발열에 의한 화재 사례의 분석)

  • Park, Jin-Young;Lee, Eui-Pyeong
    • Fire Science and Engineering
    • /
    • v.34 no.2
    • /
    • pp.54-63
    • /
    • 2020
  • Although fires caused by heat generation due to Cu2O breeding in wire connections are well-known among fire investigators, there are few papers on the analysis and introduction of fire cases by heat generation due to Cu2O breeding. This study analyzed fire statistics caused by heat generation in electrical connections and the phenomena and features of heat generation due to Cu2O breeding. Then, a fire which occurred in the wire connection in a university lab by heat generation due to Cu2O breeding was analyzed in more detail. This fire case could reach a conclusion that heat generation due to Cu2O breeding caused a fire in the wire connection through the fire pattern investigation of fire origin, the visual investigation of wire connection, 3D CT, power-on-test, and stereoscopic microscopy, SEM and EDS analysis.

Cloning and Sequenece Analysis of the hpa D Gene Responsible for Homoprotocatechuate 2, 3-Dioxgenae from Pseudomonas sp. DJ-12

  • Lee, Sang-Maha;Chae, Jong-Chan;Kim, Young-Soo;Kim, Chi-Kyung
    • Journal of Microbiology
    • /
    • v.39 no.4
    • /
    • pp.334-337
    • /
    • 2001
  • The degradative pathway of homoprotocatechuate (HPC) is the bacterial routhe wherby 3,4-dihydrox-yphenylactic acid is catabolized to pyruvate and succinate by a series of sequential reactions . The HPC is catalzed by homoprotocatechuate 2, 3-dioxygenase(HPC-2,3O) to from 5-carboxymethy1-2-hydroxy-muco semialdehyde. In this study, the hha D gene encoding. HPC, 2, 3O was Cloned from the chromo-somal DNA of Pseudomonas sp. DJ-12 and its nucleotide sequence was analyzed. The open reding frame of hpaD gene was found to be composed of 864 nucleotide pairs and to encode a poypetide with 287 amino acide residues. The deduced amino acid sequence of the HPC-2,3O from Pseudomonas. sp. DJ-12 exhibited 60~64% homology with those of the corresponding enzymes from E. coli. Salmonella enterica, and Klebsiella pneumoniae.

  • PDF

Phenolic Compounds Isolated from Opuntia ficus-indica Fruits

  • Kim, Jung Wha;Kim, Tae Bum;Yang, Heejung;Sung, Sang Hyun
    • Natural Product Sciences
    • /
    • v.22 no.2
    • /
    • pp.117-121
    • /
    • 2016
  • On the phytochemical investigation of a 70% ethanol extract of the fruits of Opuntia ficus-indica, (Cacataceae), we could result in the isolation of thirteen phenolic compounds including seven flavonoids (1 - 9) and four simple phenolic glycosides (10 - 13) by column chromatographic methods. Among the isolated compounds, picein (11), androsin (12), and $1-O-feruloyl-{\beta}-{\small{D}}-glucopyranoside$ (13) were isolated for the first time from O. ficus-indica; additionally, this is the first report $benzyl-O-{\beta}-{\small{D}}-glucopyranoside$ (10) from the genus Opuntia. The structures of the compounds were determined by spectral data analysis which included 1D, 2D NMR spectrum and ESIMS.

Isolation of Flavone-7-O-Glycosides from the Aerial Parts of Angelica keiskei and Anti-hyperlipidemic Effect (Angelica keiskei의 고지혈증 개선효과 및 2종의 플라본 7-O-배당체의 분리)

  • Park, Jong-Cheol;Cho, Young-Sook;Park, Seok-Kyu;Park, Jeong-Ro;Chun, Soon-Sil;Ok, Kwang-Dae;Choi, Jong-Won
    • Korean Journal of Pharmacognosy
    • /
    • v.26 no.4
    • /
    • pp.337-343
    • /
    • 1995
  • Two flavone glycosides were isolated from the aerial part of Angelica keiskei Koidz and identified by means of spectral analysis as luteolin-$7-O-{\beta}-{_D}-glucoside$ and Iuteolin-7-O-rutinoside. Intraperitoneal administration of methanolic extract(100mg/kg) and $luteolin-7-O-{\beta}-{_D}-glucoside(5mg/kg)$ isolated from this plant produced a significant hypolipemic activity.

  • PDF

The Estimation of Water Mass Mixing Ratio by Oxygen and Hydrogen Isotopes in the Southern Yellow Sea (황해 남부해역 해수에서 산소와 수소동위원소를 이용한 혼합비율 추정)

  • Kim, Kee-Hyun;Han, Jeong-Hee
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
    • /
    • v.5 no.4
    • /
    • pp.357-362
    • /
    • 2000
  • Stable isotope ratios of oxygen and hydrogen were investigated in southern Yellow Sea in August 1997. Salinity showed good positive correlation with ${\delta}^{18}$O and ${\delta}$. The correlation between ${\delta}^{18}$O and ${\delta}$D is good. From the relationship between these parameters, we obtained two lines of conclusion: 1) seawater of study area I in summer is a mixture of Changjiang Water and modified Kuroshio Water; 2) stable isotopes are very useful tracers in studying property and behavior of water masses in the study area. In case when water masses can not be easily distinguished by T-S analysis, the stable isotopes seem to be powerful tools for this purpose.

  • PDF