• Title/Summary/Keyword: O-D Matrix

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X-Ray Fluorescence Analysis of Iron and Titanium in Iron Ores by Dilution Parameter Method (희석 파라미터법에 의한 철광석 중 철과 티탄의 X-선 형광분석)

  • Young Sang Kim;Lee Chong Wook
    • Journal of the Korean Chemical Society
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    • v.25 no.3
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    • pp.183-189
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    • 1981
  • Iron and titanium, the major constituents in iron ores, were X-ray spectrometrically determined by using the dilution parameter method. A standard and samples possessing a similar composition were diluted with the diluent $ZrO_2$ to their proper respective ratios. After measuring the intensity of the fluorescent X-ray, the dilution parameter was calculated from the following equation. $Pa=\frac{\frac{I_{as}}{(I_{as})_d}}{D-1}{^{-1}}$The dilution parameters were used to correct the difference between the matrix effect of the standard and that of the sample. The content of the major constituents was calculated, without using any standard calibration curves, from the following equation;$W_a=W_a^*{\cdot}{\frac{I_as}{I_{as}^*}{\cdot}\frac{P_a^*}{P_a}$where asterisks indicate the standard. The results agreed with those of the wet analysis within 2% of relative error, and the precision of the experiment was also tolerably good.

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Antioxidant Constituents from Melothria heterophylla; Regulation of Matrix Metalloproteinase-1 Expression in Ultraviolet A-irradiated Human Dermal Fibroblasts (백렴으로부터 항산화 물질의 분리와 자외선이 조사된 사람 섬유아세포의 Matrix Metalloproteinase-1 발현에 미치는 영향)

  • Cho, Young-Ho;Kim, Jin-Hui;Sim, Gwan-Sub;Lee, Bum-Chun;Pyo, Hyeong-Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.31 no.4 s.54
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    • pp.323-327
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    • 2005
  • Although many studies have been performed to elucidate the molecular consequence of ultraviolet irradiation on an aging, little is known about the effect of natural products. Matrix metalloproteinases (MMPs) we known to play an important role in (a) photoaging. Hete we investigated the effect of $1,2,4,6-tetra-O-galloyl-{\beta}-{_D}-gluco- pyranose (1)$ and 3,4,5-trihydroxybenzoic acid (2) on the expression of MMP-1 in UVA-irradiated human skin fibroblasts (products), (on the) activity of MMP-1, and (on the) scavenging activities of free radicals. Compounds 1 and 2 were isolated from Melothria heterophylla (Cucurbitaceae). These compounds were found to scavenge free radicals and reactive oxygen species (ROS) and were measured to have the $SC_{50}$ values of $3.9{\mu}M\;and\;13.3{\mu}M$ against the 1,1-diphenyl-2-picrylhydrazyl (DPPH) radicals and $4.3{\mu}M\;and\; 4.0{\mu}M$ against superoxide radicals in the xanthine/xanthine oxidase system, respectively. Compounds 1 and 2 showed a dose-dependent inhibitory effect on the e):pression and activity of MMP-1 in the UVA-irradiated human skin fibroblasts. Therefore, we concluded that compounds 1 and 2 significantly inhibited MMP-1 expression at the protein level. Also, these compounds were determined to have a potent antioxidant activity. From these results, we suggest that these compounds nay be used as (a) new anti-aging agents for the photo-damaged skin.

The Study on the Improvement of the Strength and the Thermal Shock Resistance of $Al_2O_3-ZrO_2$ Composites ($Al_2O_3-ZrO_2$ 복합체의 강도 및 열충격 저항의 향상에 관한 연구)

  • Hwang, K.H.;Bae, W.T.;Choi, M.D.;Oh, K.D.;Kim, K.U.;Kim, H.
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.225-230
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    • 1988
  • The strength and thermal shock resistance of $Al_2O_3-ZrO_2$ composites have been studied. The tetragonal $ZrO_2$ powder containing 1 mol.% $Y_2O_3$ and monoclinic $ZrO_2$ powder were prepared by coprecipitation method and subsequently mixed with $Al_2O_3$ powder and granulated by sieving. Duplex composites were prepared by dry mixing matrix agglomerate with 15 to 30 vol.% of dispersion agglomerate, followed by pressing and sintering at 1$600^{\circ}C$ for1 hr. These $Al_2O_3-ZrO_2$ 2 composites having heterogeneous structure showed improved thermal shock behaviors because of the microcracking and pores in dispersed granules, and compressive stresses around dispersed granules resulting from $ZrO_2$ transformation.

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A study on searching image by cluster indexing and sequential I/O (연속적 I/O와 클러스터 인덱싱 구조를 이용한 이미지 데이타 검색 연구)

  • Kim, Jin-Ok;Hwang, Dae-Joon
    • The KIPS Transactions:PartD
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    • v.9D no.5
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    • pp.779-788
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    • 2002
  • There are many technically difficult issues in searching multimedia data such as image, video and audio because they are massive and more complex than simple text-based data. As a method of searching multimedia data, a similarity retrieval has been studied to retrieve automatically basic features of multimedia data and to make a search among data with retrieved features because exact match is not adaptable to a matrix of features of multimedia. In this paper, data clustering and its indexing are proposed as a speedy similarity-retrieval method of multimedia data. This approach clusters similar images on adjacent disk cylinders and then builds Indexes to access the clusters. To minimize the search cost, the hashing is adapted to index cluster. In addition, to reduce I/O time, the proposed searching takes just one I/O to look up the location of the cluster containing similar object and one sequential file I/O to read in this cluster. The proposed schema solves the problem of multi-dimension by using clustering and its indexing and has higher search efficiency than the content-based image retrieval that uses only clustering or indexing structure.

Hemodynamically Induced Aneurysm-mimicking Findings at Anterior Communicating (A-com) Artery Area due to Anatomical Variation on 3D-TOF MRA

  • 강원석;정태섭;심용운;유병규;박인국
    • Proceedings of the KSMRM Conference
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    • 2001.11a
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    • pp.133-133
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    • 2001
  • Purpose: To determine the relationship between anatomical variation at A-com. artery area an hemodynamically induced aneurysm-mimicking findings on 3D-TOF MRA clinically a experimentally. Method: Sixty-two patients who had no aneurysm at A-com artery on DSA were evalua with MRA. MRA was performed with 1.5T MR machine(Vision, Siemens). Scan parameters o MRA included TR/TE/FA=30/6.4/25$\psi$$\circledR$˙¡, 512*192 of matrix with MIP technique. The occurrence of signal defect at shoulder area of bifurcated A-com artery on MRA was evalua for the relationship between the symmetricity of bilateral ACA and the patency of A-c artery. DSA images were acquired at both ICA and VA. To analyze hemodynamical facto of signal defect, experimental studies of MRA and DSA were peformed with elastic silic phantom using conducting pulsatile pump. We also compared the results with those o computational fluid dynamics(CFD).

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Fabrication and characterization of optical fiber fabry-perot tunable filter for WDM transmission (WDM 전소용 광섬유 fabry-perot 가변 광필터의 제작 및 특성 분석)

  • 김윤중;김창민;김명진;윤대원
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.3
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    • pp.70-81
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    • 1998
  • Fiber-Fabry-Perot (FFP) tunable filters, the essential component of WDM transmission, were designed, fabricated and characterized. Multi-layered thin film mirrors that consists of an optical collimater's corss section as a substrate and TiO$_{2}$SiO$_{2}$ alternating multi-layered films as a filter wer designed by means of the transfer matrix method. Fabricated mirrors showed the high reflectivity over around 98% as expected. After fabricating the tuneable filters using PZT, we measured FSR, FWHM, finesse , crosstalk and insertion loss, confirming that the built devices satisfied the optical filter's specifications required in the SEDM transmission systems.

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$^{11}B $Nutation NMR Study of Powdered Borosilicates

  • 우애자;한덕영;양경화
    • Bulletin of the Korean Chemical Society
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    • v.19 no.5
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    • pp.519-524
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    • 1998
  • In this work, we applied the 1D 11B nutation NMR method for the analysis of the local structural environments in powdered borosilicates (SiO2-B2O3). Spin dynamics during a rf irradiation for spin I=3/2 was analytically calculated with a density matrix formalism. Spectral simulation programs were written in MATLAB on a PC. Two borosilicates prepared by the sol-gel process at different stabilization temperature were used for the 1D 11B nutation NMR experiment. The 11B NMR parameters, quadrupole coupling constants (e2qQ/h) and asymmetry parameters (η), for each borosilicate were extracted from the nonlinear least-squares fitting. The effects of heat treatments on the local structures of boron sites in borosilicates were discussed.

Polynomial Time Algorithm for Multi-Beam SS/TDMA Satellite Communications Scheduling Problem with Frequency-Hopping Ground Stations

  • Lee, Sang-Un
    • Journal of the Korea Society of Computer and Information
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    • v.20 no.7
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    • pp.33-40
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    • 2015
  • The time slot assignment problem (TSAP) or Satellite Communications scheduling problem (SCSP) for a satellite performs $n{\times}n$ ground station data traffic switching has been known NP-hard problem. This paper suggests $O(n^2)$ time complexity algorithm for TSAP of a satellite that performs $n^2{\times}n^2$ ground station data traffic switching. This problem is more difficult than $n{\times}n$ TSAP as NP-hard problem. Firstly, we compute the average traffic for n-transponder's basic coverage zone and applies ground station exchange method that swap the ground stations until all of the transponders have a average value as possible. Nextly, we transform the D matrix to $D_{LB}$ traffic matrix that sum of rows and columns all of transponders have LB. Finally, we select the maximum traffic of row and column in $D_{LB}$, then decide the duration of kth switch mode to minimum traffic from selected values. The proposed algorithm can be get the optimal solution for experimental data.

The Crystal Structure of N-(Diphenylmethylene) aminomethylphosphonate (N-(Diphenylmethylene)aminomethylphosphonate의 결정 구조)

  • 김문집;박호종;김대영
    • Korean Journal of Crystallography
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    • v.13 no.2
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    • pp.86-90
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    • 2002
  • The structure of N-(Diphenylmethylene)aminomethylphosphonate has been determined by X-ray diffraction methods. The crystal system is triclinic, space group P(equation omitted), unit cell constants, a=8.967(2) (equation omitted), b=9.309(2) (equation omitted), c= 10.981(2) (equation omitted), α=101.42(2)°, β=92.22(2)°, γ=92.23(2)°, V=896.8(3) (equation omitted), T=296 K, Z=2, D/sub c/=1.227 Mgm/sup -3/. The intensity data were collected on an Enraf-Nonius CAD-4 Diffractometer with graphite monochromated MoKα radiation (λ=0.7107(equation omitted)). The molecular structure was solved by direct methods and refined by full-matrix least-squares to a final R=7.3% for 979 unique observed F/sub o/>4σ(F/sub o/) refections and 209 parameters.

Site spectroscopy probing of Eu3+ incorporated into novel LiYxSryZrO3+α host matrix

  • Ahemen, I.;Dejene, F.B.
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1359-1367
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    • 2018
  • In this work, we investigated the spectroscopic properties of $LiY_xSr_yZrO_{3+{\alpha}:Eu^{3+}$, a red emitting nanophosphor based on $SrZrO_3$ perovskite. The synthesis process was an auto-combustion process. X-ray diffractograms show the orthorhombic structure of $SrZrO_3$. Photoluminescence (PL) excitation spectra display a split charge transfer band revealing the presence of two possible sites for the $Eu^{3+}$ ions. The emission spectra at 231 nm excitation illustrate the dominance of the $^5D_0-^7F_1$ transition, which is an indication that the smaller sized $Eu^{3+}$ ions are mostly situated at the more ordered (symmetric) $Sr^{2+}$ sites. The emission spectra at 292 nm & 397 nm excitations show the dominance of $^5D_0-^7F_2$ transition which suggests some of the $Eu^{3+}$ ions are also situated at the distorted $Zr^{4+}$ sites. Both the intensity parameters, asymmetry ratio and the decay lifetimes of the nanophosphors show dependence on $Y^{3+}$ concentration, signifying a modification in the host structure. Maximum quantum efficiency value of ${\approx}46%$ was obtained for the nanophosphors which indicate the need for improvement for practical applications. CIE coordinates show the suitability of this phosphor for both red emission in LED and as a complementary colour for white LED applications.