• Title/Summary/Keyword: O-D Matrix

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The Fatigue Behavior of Mechanically Alloyed Al-4Mg Alloys Dispersed with Oxide Particles (기계적합금화된 분산형 Al-4Mg기 합금의 피로거동)

  • Pyun, J.W.;Cho, J.S.;Kwun, S.I.;Jo, Y.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.4
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    • pp.237-242
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    • 1993
  • The fatigue behaviors of mechanically alloyed Al-4Mg alloys dispersed with either $Al_2O_3$ or $MgAl_2O_4$ oxide particles were investigated. This study maily concerned with the role of coherency of dispersed particles with the matrix on the fatigue behavior of the alloys. The $MgAl_2O_4$ which has a spinel structure with the lattice parameter of exactly the twice of Al showed the habit relation with the matrix. The mechanically alloyed Al-4Mg alloys showed stable stress responses with fatigue cycles from start to failure regadless of strain amplitudes and of existence of dispersoids. The Al-4Mg alloy dispersed with $MgAl_2O_4$ showed not only the better static mechanical properties but also the better low cycle fatigue resistance than that with $Al_2O_3$, i.e., much higher plastic strain energy dissipated to failure, at low strain amplitude. However, this alloy showed inferior fatigue resistance to that dispersed with $Al_2O_3$ or that without dispersion at high strain amplitude. These results imply that $MgAl_2O_4$ may promote lowering the stacking fault energy of the alloy inherited from the coherency with the matrix so that dislocations shuttle back and forth on the same slip plane without cross slipping to other planes during fatigue at low strain amplitude resulting in long fatigue life.

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Antioxidants and Inhibitor of Matrix Metalloproteinase-1 Expression from Leaves of Zostera marina L

  • Kim, Jin-Hui;Cho, Young-Ho;Park, Sung-Min;Lee, Kyung-Eun;Lee, Jeong-Jae;Lee, Bum-Chun;Pyo, Hyeong-Bae;Song, Kyung-Sik;Park, Hum-Dai;Yun, Yeo-Pyo
    • Archives of Pharmacal Research
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    • v.27 no.2
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    • pp.177-183
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    • 2004
  • In order to develop new anti-photoaging agents, we examined the antioxidative activity and the inhibition effect of matrix metalloproteinase-1 (MMP-1) on the extracts of a marine product, Zostera marina L., which is known for its potent activity. Three compounds (compounds 1, 2, and 3) were isolated from an ethyl acetate (EtOAc) soluble fraction of the product; they were identified as apigenin-7 -O-$\beta$-D-glucoside (1), chrysoeriol (2), and luteolin (3). These compounds were found to scavenge radicals and reactive oxygen species (ROS) and were measured to have $SC_{50}$/ values of 0.18 mM, 0.68 mM, and 0.01 mM against the 1, 1-diphenyl-2-picrylhydrazyl (DPPH) radical and 0.04 mM, 0.03 mM, and 0.01 mM against the superoxide radical in the xanthine/xanthine oxidase system, respectively. Compound 3 suppressed the expression of MMP-1 by up to 44% at 4.0 $\mu$M and inhibited the production of interleukin 6 (IL-6), which is known as a cytokine that induces MMP-1 expression. From these results, compound 3 and the other compounds were determined to have antioxidative activity and to inhibit MMP-1 expression. Thus, the three compounds are expected to be useful for preventing the photoaging of skin.

An Analysis of Continuous Beam by Material Non-linear Transfer Matrix Method (재료비선형 전달행렬법에 의한 연속보의 해석)

  • Seo, Hyun Su;Kim, Jin Sup;Kwon, Min Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.1
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    • pp.77-84
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    • 2011
  • This study is to develop nonlinear analysis algorithm for transfer matrix method, which can be applied to continuous beam analysis. Gauss-Lobatto integral rule is adopted and the transfer matrix is derived from stiffness matrix. In the transfer matrix method, the system equation has a constant number of unknowns regardless of number of D.O.F. Therefore, the transfer matrix method has computational efficiencies not only in linear elastic analysis but also in nonlinear analysis. To verify the developed method, the analysis results of several examples are compared with commercial code in moment-curvature, moment-displacement and load-displacement relation.

A Study on Trip Distribution Estimation Model's Accuracy: Using Daegu City O-D Tables (통행분포 예측모형별 예측 정확도(精確度)에 관한 연구: 대구시 O-D표를 대상으로)

  • Ryu, Yeong-Geun;Woo, Yong Han
    • Journal of Korean Society of Transportation
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    • v.30 no.5
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    • pp.43-59
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    • 2012
  • It is generally assumed about trip distribution estimation model that growth factor model's estimation accuracy is higher than that of other models in short-term and that gravity model's estimation accuracy is higher than that of other models in long-term. For validation of such assumptions, this study compares estimation accuracies of each estimation model using 3year(1988, 1992, 2004) O-D tables from Daegu city. Each estimation model's accuracy were compared by mid-size and large-size zone as well as short-term and long-term target years. The results show that the trip distribution estimation model selection by usual assumption is not always right.

The X-Ray Fluorescent Spectrographic Analysis of Silicate Minerals (X線螢光分析에 依한 珪酸鹽鑛物의 分析)

  • Chan Kuk Kim;Ki Nam Sang;Hwang Am Kim
    • Journal of the Korean Chemical Society
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    • v.13 no.1
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    • pp.49-55
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    • 1969
  • X-ray Fluorescence Spectrographic method has been applied for the rapid determination of main components, such as $SiO_2$, $Al_2O_3$, $Fe_2O_3$, CaO, MgO and $K_2O$ in Silicate Minerals. In this method, Boric Acid was used as a binder after fusion with Lithium Tetraborate in the briquet-making process. The Lithium Flubride, Ammonium di-Hydrogen Phosphate and Ethylene Diamine d-Tartrate crystals were used with Scintillation counter and Gas Flow counter as the detectors. Several influences on this method were discussed, including the particle size of samples and reducing of the matrix effects by dilution with Boric Acid and addition of Lanthanum Oxide with the diluent. In order to test the reproducibility of this method described above, the determination of the same kind of samples were carried out repeatedly, and the results obtained were presented in the table. Calibration curves for each element were presented, and the application of the method was tested with International Rock Standard T-Ⅰ. All the results obtained by X-Ray Fluorescence Spectrographic method were compared with the results by conventional chemical method.

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Optical Properties of (V, Pr)-doped ZrSiO4 Green Pigments (바나듐과 프라세오디뮴을 사용한 지르콘녹색안료의 광학적 특성)

  • Pyon, Kyu-Ri;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.47 no.3
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    • pp.249-255
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    • 2010
  • To investigate optical properties of (V, Pr)-doped $ZrSiO_4$ green pigments, samples were prepared by the ceramic method using NaF and NaCl as mineralizers. They were characterized by X-ray diffraction, UV-Vis spectroscopy and Raman spectroscopy. The changes of color in the samples during heating and effect of mineralizers were studied in terms of valence of the vanadium and praseodymium in the zircon matrix. (V, Pr)-doped $ZrSiO_4$ pigments give rise to green coloration in $800^{\circ}C$. The oxidation state of V and Pr ions of pigments in the glazed samples were confirmed by UV-Vis absorption spectra. This absorption spectra showed three typical bands of trivalent Pr at the 445, 480~490, 592 nm due to f-f transitions and two broad bands of 302~380, 400~500 nm due to f-d transitions of tetravalent Pr. According to the increasing amounts of $Pr_6O_{11}$, the two broad bands showed decreasing intensity at 290, 640 nm due to d-d transitions of tetravalent V.

Analysis of Heavy Water Separation Cascade Using Bithermal ${H_2}$/$H_2$O Exchange Process

  • Ahn, Do-Hee;Paek, Seung-Woo;Lee, Han-Soo;Hongsuk Chung;Masami Shimizu
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.571-576
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    • 1996
  • The 3-stage cascade composed of the multisection-type bithermal $H_2$/$H_2O$-exchange columns was suggested for heavy water separation. In order to study the separation characteristics for the cascade, a matrix equation with 18 simultaneous equations was composed and the concentrations and flow rates were calculated for the all parts of the cascade. Product D-concentration decreases and extraction yield increases with increasing cut in each stage, which is one of the principal parameters of the separation characteristics. The optimization of the 3-stage cascade can be made by case study using the matrix equation.

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The stabillty of Double-Capsulated Retinol on O/W Eulsion

  • Park, Dong-Soon;Lee, Ok-Sub;Kang, Hak-Hee;Kim, Jong-Il
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.24-38
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    • 1997
  • Using the all-trans-retinol which is double-capsulated with matrix, we investigated its stability and the change of the epidermal thickness. The proprietary MDC comprise two steps of capsulation of retinol, i.e., primary microcapsulation with collagen and then secondary capsulation with gellan gum. We compared the activity of all-trans-retinol in various forms such as (1) simply in O/W, (2) in W/O emulsion, (3) in primary capsulted form in O/W emulsion, or (4) in MDC in O/W emulsion. After storage at 45$^{\circ}C$ for 4 weeks, retinol in MDC in O/W emulsion retained 92% of the activity compared to the standard material upon HPLC analysis, whereas the primary capsule gave 70%, the O/W emulsion form 47% and the W/O emulsion 78%. The retinol in MDC in O/W induced the siginificant increase in epidermal thickness compared to the vehicle.

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Effect of Solution Treatment on Corrosion Behavior of AZ91-2%Ca Magnesium Casting Alloy (주조용 AZ91-2%Ca 마그네슘 합금의 부식 거동에 미치는 용체화처리의 영향)

  • Moon, Jung-Hyun;Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.4
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    • pp.190-199
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    • 2015
  • The study is intended to investigate the effect of solution treatment on microstructure and corrosion behavior of AZ91(Mg-9%Al-1%Zn-0.3%Mn)-2%Ca casting alloy. In as-cast state, the AZ91-2%Ca alloy consisted of intermetallic ${\beta}(Mg_{17}Al_{12})$, $Al_8Mn_5$ and $Al_2Ca$ phases in ${\alpha}-(Mg)$ matrix. After the solution treatment, Al within the ${\alpha}-(Mg)$ matrix was distributed more homogeneously, along with the slight decrease in the total amount of intermetallic compounds. The corrosion resistance of the AZ91-2%Ca alloy was improved after the solution treatment. The microstructural examinations for the solution-treated samples revealed that the better corrosion resistance may well be related to the incorporation of more oxides and hydroxides such as $Al_2O_3$, $Al(OH)_3$, CaO and $Ca(OH)_2$ into the surface corrosion product without dissolution of the intermetallic phases along the grain boundaries.