• Title/Summary/Keyword: O:N ratio

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ASSESSMENT OF THE TiO2/WATER NANOFLUID EFFECTS ON HEAT TRANSFER CHARACTERISTICS IN VVER-1000 NUCLEAR REACTOR USING CFD MODELING

  • MOUSAVIZADEH, SEYED MOHAMMAD;ANSARIFAR, GHOLAM REZA;TALEBI, MANSOUR
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.814-826
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    • 2015
  • The most important advantage of nanoparticles is the increased thermal conductivity coefficient and convection heat transfer coefficient so that, as a result of using a 1.5% volume concentration of nanoparticles, the thermal conductivity coefficient would increase by about twice. In this paper, the effects of a nanofluid ($TiO_2$/water) on heat transfer characteristics such as the thermal conductivity coefficient, heat transfer coefficient, fuel clad, and fuel center temperatures in a VVER-1000 nuclear reactor are investigated. To this end, the cell equivalent of a fuel rod and its surrounding coolant fluid were obtained in the hexagonal fuel assembly of a VVER-1000 reactor. Then, a fuel rod was simulated in the hot channel using Computational Fluid Dynamics (CFD) simulation codes and thermohydraulic calculations (maximum fuel temperature, fluid outlet, Minimum Departure from Nucleate Boiling Ratio (MDNBR), etc.) were performed and compared with a VVER-1000 reactor without nanoparticles. One of the most important results of the analysis was that heat transfer and the thermal conductivity coefficient increased, and usage of the nanofluid reduced MDNBR.

CJ-11668, a new selective and potent cox-2 inhibitor, has long-acting pharmacokinetic profiles

  • Park, Hyun-Jung;Kang, Hye-Jung;Chung, Young-Mee;Chun, Hyung-Ok;Hong, Kwang-Hee;Kim, Il-Hwan;Kim, Taek-Rho;Noh, Hyun-Jung;Kim, Deog-Yeor
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.88.1-88.1
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    • 2003
  • CJ-11668 is a new potent and selective COX-2 inhibitor (IC$\sub$50/ COX-2 65nM; COX-l/COX-2 ratio 770). The pharmacokinetic profile of CJ-11668 (20 mg/kg, p.o.) in the rat was characterized by high bioavailability (90%) and long plasma half-life (11.7 hr) with low clearance (0.4 L/hr/kg). In the dog, the PK profiles (2 mg/kg, p.o.) also showed long plasma half-life (l7.9hr) with low clearance (0.5 L/hr/kg), and the bioavalability of 60%. The inhibition of CJ-11668 infive different cytochrome P450 isozymes (1A2, 2C9, 2C19, 2D6 and 3A4) was determined in vitro and had observed no significant effect. (omitted)

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Crystal Structure and Electrical Transport Characteristics of ${La_{1-x}}{Sr_x}{MnO_{3-{\delta}}}$(0.19$\leq$x$\leq$0.31) Thin Films (${La_{1-x}}{Sr_x}{MnO_{3-{\delta}}}$(0.19$\leq$x$\leq$0.31) 박막의 결정구조 및 전기전도 특성)

  • Heo, H.;Lim, S.J.;Cho, N-H.
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.437-444
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    • 2000
  • We investigated the effect of substrate temperature, chemical composition and post-deposition heat-treatment on the crystal structure and electrical transport of $La_{1-x}Sr_xMnO_{3-{\delta}}$(0.19${\leq}x{\leq}$0.31) thin films. As-prepared $La_{1-x}Sr_xMnO_{3-{\delta}}$ films grown at $500^{\circ}C$ by sputter techniques were found to have the pseudo-tetragonal system(a/c=0.97) and a highly preferential <001> orientation. The films were changed to be of the cubic system by post-deposition annealing at around $900^{\circ}C$. A main target of $La_{0.67}Sr_{0.33}MnO_3$ as well as auxliary targets of $La_{0.3}Sr_{0.7}MnO_3$ ceramics were co-sputtered to control the chemical composition of the film. The Sr content(x) of the film ranged from 0.19 to 0.31, depending on the number of the auxiliary target. When x increased from 0.19 to 0.31, the electrical resistivity of the film decreased and the transition temperature between metal and semiconductor shifted to higher temperature. With a magnetic field of 0.18 T, the magneto-resistance ratio (MR(%) = (${\rho}_o-{\rho}_H/{\rho}_H$) of the $La_{0.69}Sr_{0.31}MnO_3$ thin film was about 390%.

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Effect of Al Precursor Addition Time on Catalytic Characteristic of Cu/ZnO/Al2O3 Catalyst for Water Gas Shift Reaction (Water Gas Shift 반응을 위한 Cu/ZnO/Al2O3 촉매에서 Al 전구체 투입시간에 따른 촉매 특성 연구)

  • BAEK, JEONG HUN;JEONG, JEONG MIN;PARK, JI HYE;YI, KWANG BOK;RHEE, YOUNG WOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.5
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    • pp.423-430
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    • 2015
  • $Cu/ZnO/Al_2O_3$ catalysts for water gas shift (WGS) reaction were synthesized by co-precipitation method with the fixed molar ratio of Cu/Zn/Al precursors as 45/45/10. Copper and zinc precursor were added into sodium carbonate solution for precipitation and aged for 24h. During the aging period, aluminum precursor was added into the aging solution with different time gap from the precipitation starting point: 6h, 12h, and 18h. The resulting catalysts were characterized with SEM, XRD, BET surface measurement, $N_2O$ chemisorption, TPR, and $NH_3$-TPD analysis. The catalytic activity tests were carried out at a GHSV of $27,986h^{-1}$ and a temperature range of 200 to $400^{\circ}C$. The catalyst morphology and crystalline structures were not affected by aluminum precursor addition time. The Cu dispersion degree, surface area, and pore diameter depended on the aging time of Cu-Zn precipitate without the presence of $Al_2O_3$ precursor. Also, the interaction between the active substance and $Al_2O_3$ became more stronger as aging duration, with Al precursor presented in the solution, increased. Therefore, it was confirmed that aluminum precursor addition time affected the catalytic characteristics and their catalytic activities.

Preparation of Zirconia Nanocrystalline Powder by the Hydrothemal Treatment at low Temperature (수열법에 의한 저온 결정형 지르코니아 나노 분말의 제조)

  • Noh, Hee-Jin;Lee, Jong-Kook;Seo, Dong-Seok;Hwang, Kyu-Hong
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.308-314
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    • 2002
  • The nanocrystalline zirconia powder was synthesized from the zirconium hydroxide precipitate by hydrothermal process with the reaction temperature range 100∼250$^{\circ}$C, reaction time 1∼48 hours and additive concentration 1, 5 N NaOH solutions. The lower hydrothermal treatment temperature, the inner spherical tetragonal zirconia was synthesized. The fraction of monoclinic phase zirconia with rod shape increased with increasing the hydrothermal treatment temperature. As the concentration of the NaOH solution increases, the synthesized particle in breadth and length increased; breadth and length ratio decreased. In the case of the low concentration of NaOH solution, however, the particle length became relatively larger than its breadth resulting in the rod-shaped particles with bigger aspect ratio.

Effect of NPK-Application and utilization on the Productivity of Dry Matter and Nutrient of Forages in Hilly Pasture (산지초지에서 3요소 시비수준 및 초지이용방법이 건물 및 양분생산성에 미치는 영향)

  • 박근제;최기준;이필상
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.18 no.3
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    • pp.251-258
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    • 1998
  • To find out the effect of NPK-fertilization level and utilization method of pasture plants on the productivity of dry matter and nutrient of forages in hilly pasture, this experiment was arranged as a split block design with six treatments of 2 mainplots(N-$P_2O_5$-$K_2O$=210-150-180(wntrol), 280-200-240Kg/ha) and 3 subplots (cutting, grazing cutting+grazing alternative), and conducted at hilly land in Yeoju, Kyonggi Province 6om February, 1992 to October, 1993. In the treatment of grazing the early growth and cover degree of pasture plants wintered were more favorable. With increased NPK-application for two years, the average dry matter(DM) yield of 9,862kglha was incerased by 18% than that of the control, and the average DM yield of the cutting treatment of 10,434kaa was higher than that of others. In all treatments for two years, the average DM yield was composed of 94.0~95.1% grasses, 1.8~2.0% legumes and 2.8~4.2% weeds. The crude protein and energy productivity of forages in the treatment with increased NPK-fertilizer application increased by 20~23% than those of control, and those of cutting treatment were greatly increased than those of the grazing treatment. The average mineral content of forages in all treatments tended to be similar, Ca and Mg content and Ca/P ratio were slightly lower, and K content and K/(Ca+Mg) equivalent ratio of forages tended to be higher than the most desirable value of forages.

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Transport Properties of $MgB_2$ Films Grown by Hybrid Physical Chemical Vapor Deposition Method (HPCVD 방법으로 성장된 $MgB_2$ 박막의 수송 특성)

  • Kim, Hye-Young;Hwang, Tae-Jong;Kim, D.H.;Seong, Won-Kyung;Kang, W.N.
    • Progress in Superconductivity
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    • v.9 no.1
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    • pp.5-10
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    • 2007
  • We prepared four different $MgB_2$ films on $Al_2O_3$ by hybrid physical chemical vapor deposition method with thicknesses ranging from $0.65\;{\mu}m$ to $1.2\;{\mu}m$. X-ray diffraction patterns confirm that all the $MgB_2$ films are c-axis oriented perpendicular to $Al_2O_3$ substrates. The superconducting onset temperature of $MgB_2$ films were between 39.39K and 40.72K. The residual resistivity ratio of the $MgB_2$ films was in the range between 3.13 and 37.3. We measured the angle dependence of critical current density ($J_c$) and resistivity, and determined the upper critical field ($H_{c2}$) from the temperature dependence of the resistivity curves. The anisotropy ratios defined as the ratio of the $H_{c2}$ parallel to the ab-plane to that perpendicular to the ab-plane were in the range of 2.13 to 4.5 and were increased as the temperature was decreased. Some samples showed increase of $J_c$ and decrease of resistivity when a magnetic field in applied parallel to the c-axis. We interpret this angle dependence in terms of enhanced flux pinning due to columnar growth of $MgB_2$ along the c-axis.

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Novel Polyurethane Binder for Propellant based on Hydroxyl-terminated Copolyether (폴리에테르 공중합체 디올(HTPE)을 사용한 새로운 추진제용 폴리우레탄 바인더)

  • Song Jong-Kwon;Pan Xiao;Lee Bum-Jae;Jeon Jun-Pyo;Hwang Gab-Sung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.417-421
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    • 2005
  • Novel two synthetic technics using cationic ring-opening copolymerization of tetrahydrofuran (THF) and ethylene oxide (EO), or just polymerized EO on Poly-THF, could lead to random hydroxyl-terminated poly(EO-ran-THF) or tri-block PEG-PTHF-PEC, respectively. These reactions were carried out using $BF_3O(C_2H_5)_2$ as catalyst, 1,4-butanediol or PTHF as diol initiator. Copolymer structures were controlled by monomer feed ratio, or initial PTHF and EO monomer added amount. The molecular weight of polymer was merely dependant on the ratio of [monomer]/[diol], but not on catalyst. Well-defined random and block hydroxyl-terminated copolyether was found to be as the prepolymer for the propellant binder from the experiment to polyurethane with them.

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A Study on the Electrochemical Properties of Langmuir-Blodgett Monolayer Film for the Changes of Concentration with Polyamic Acid and Sphingomyelin Mixture (Sphingomyelin과 Polyamic Acid의 농도 변화에 대한 단분자 LB막의 전기화학적 특성에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.754-760
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    • 2013
  • We investigated an electrochemical properties for Langmuir-Blodgett (LB) monolayer films of sphingomyelin(SP) and polyamic acid(PAA) mixture(1:1, 2:1 and 3:1 molar ratio). LB monolayer films of mixture was deposited by the LB method on the indium tin oxide(ITO) glass. The electrochemical properties measured by cyclic voltammetry with three-electrode system in 0.1N $KClO_4$ solution. As a result, LB monolayer films of SP and PAA mixture was appeared on irreversible process caused by the reduction current from the cyclic voltammogram. Diffusion coefficient(D) in the SP and PAA mixture was calculated $2.670{\times}10^{-5}$, $3.562{\times}10^{-5}$ and $1.005{\times}10^{-5}cm^2s^{-1}$ at 1:1, 2:1 and 3:1 molar ratio, respectively.

Development of Hybrid Rocket(KHyRoc-II) with 1000 kgf Thrust level (추력 1000 kgf급 하이브리드 로켓(KHyRoc-II)의 개발)

  • Moon, Keun-Hwan;Oh, Ji-Sung;Rhee, Sun-Jae;Choi, Won-Jun;Kim, Hak-Chul;Lee, Jung-Pyo;Moon, Hee-Jang;Sung, Hong-Gye;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.58-62
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    • 2012
  • In this study, the hybrid rocket was developed that has a thrust of 1000 kgf level. The static fire test was shown that the thrust was 700 kgf level and trajectory was predicted by the maximum altitude of 12.5 km. The L/D ratio of KHyRoc-I has 28, but the KHyRoc-II were designed the small L/D ratio(18.3) using the seamless aluminium tube(Diameter : 250 mm). And KHyRoc-II has a thrust of 900 kgf level, that is designed with internal ballistics and trajectory was predicted by the maximum altitude of 7.4 km.

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