• Title/Summary/Keyword: O:N ratio

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The Effect of Synthetic Antioxidants on the proteolytic Enzymes-The Effect of Synthetic Antioxidants on the Activity of the Pepsin and Synthesis of Octapeptide as a Substrate- (합성 항산화제가 단백질 분해효소에 미치는 영향-Pepsin의 활성에 미치는 합성 항산화제의 영향 및 기질 Octapeptide의 합성-)

  • Kim, Sang-Ock
    • Journal of Nutrition and Health
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    • v.14 no.3
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    • pp.124-128
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    • 1981
  • This study was carried out to understand the activity of pepsin, the proteolytic enzyme, to octapeptide (angiotensin II) in the presence of various synthetic antioxidants as food additives. 1) Dibutyl hydroxy toluene, butyl hydroxyanisole and ethyl protocathechuate did not influence the inhibitory activity of pepsin an the octapeptide as a substrate, but sodium-L-ascorbate inhibited pepsin activity at above 100ppm. However sodium L-ascorbate was completely removed after 30 minutes. 2) Pepsin brought about a quick break up the octapeptide, Asp-Arg-Val-Tyr-Ile-His-Gly-Phe, by splitting the Gly-Phe and Val-Tyr bond. 3) The melting point of synthetized octapeptide was $209-212^{\circ}C$, chemical formula and molecula weight were $C_{43}H_{65}N_{13}O_{12}{\cdot}CH_3COOH{\cdot}H_2O$ and 956.05, respectively. 4) The amino acid mole ratio of synthetized octapeptide by acid hydrolysis were Asp:0.98, Arg: 1.02, Val: 1.00. Tyr: 0.95, Ile: 1.00, His: 1.03, Gly: 0.96, Phe: 1.00.

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CO Selox Reaction Using Y-type Zeolite Catalytic Membranes

  • Bemardo, P.;Algieri, C.;Barbieri, G.;Drioli, E.
    • Korean Membrane Journal
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    • v.8 no.1
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    • pp.13-20
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    • 2006
  • The production of CO-free hydrogen streams for feeding PEM-Fuel Cells using catalytic zeolite membrane reactors was analysed by means of selective oxidation. Tubular FAU (Na-Y) zeolite membranes, prepared by a secondary growth method and Pt-loaded, were used in a flow-through MR configuration. The catalytic tests were carried out at $200^{\circ}C$ and at different pressures with a simulated dry reformate shifted gas mixture ($H_2$ ca. 60%, CO 1 %, plus $O_2,\;N_2,\;CO_2$). The operative $O_2/CO$ stoichiometric equivalent feed ratio was ${\lambda}= 2$. These catalytic tests, reducing the CO concentration down to $10{\sim}50$ ppm, verified the possibility of MR integration after using a low temperature water-gas shift unit of a fuel processor to convert hydrocarbons into hydrogen-rich gas.

V-I Characteristics of SCT Thin Film by RF Sputtering Method (RF 스퍼터링법에 의한 SCT 박막의 전압-전류 특성)

  • 김진사;조춘남;신철기;최운식;김충혁;이준웅
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.9
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    • pp.745-750
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    • 2000
  • The (S $r_{0.85}$C $a_{0.15}$) Ti $O_3$(SCT) thin films are deposited on Pt-coated electrode (Pt/TiN/ $SiO_2$/Si) using RF sputtering method at various deposition temperature. The crystallinity of SCT thin films were increased with increase of deposition temperature in the temperature range of 200~500[$^{\circ}C$]. Also, the composition of SCT thin films were closed to stoichiometry (1.080~1.111 in A/B ratio). V-I characteristics of SCT thin films show the increasing leakage current with the increases of deposition temperature. The conduction mechanism of the SCT thin films observed in the temperature range of 25~100[$^{\circ}C$] can be divided into four regions with different mechanism by the increasing current. The region I below 0.8[MV/cm]shows the ohmic conduction. The region II between 0.9~2[MV/cm] is in proportion to J∝ $E^{1.5}$ , the region III between 2~4[MV/cm] can be explained by the Child’s law, and the region IV above 4[MV/cm]is dominated by the tunneling effect.ect.

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Dynamic Behavior of the Plane Circular Arches with the Shape Imperfections (형상불완전을 갖는 평면 원호 아치의 동적 거동)

  • 조진구
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.3
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    • pp.85-93
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    • 2001
  • In this study, a computer program considering shape imperfections of arch under dynamic loading was developed. The shape imperfection of arch was assumed as higher degree polynomial expressed as $\omega$$_{i}$ = $\omega$$_{o}$ (1-(2$\chi$/L)$^{m}$ )$^n$and sinusoidal curve such as $\omega$$_{i}$ = $\omega$$_{o}$ sin(η$\pi$$\chi$/L). In finite element formulation, the material nonlinear behavior was assumed the elasto-viscoplastic model highly corresponding to the real behavior of the material and the geometrically nonlinear behavior was modeled using Lagrangian description of motion. Also, the behavior of steel was modeled by applying yield criteria of Von Mises. The developed program was applied to the analysis of the dynamic behavior for the clamped beam subjected to the concentrated load at midspan and the results were compared with those from other research to investigate accuracy of the presented finite element program. In numerical examples, the shape imperfections of L/500, L/1,000 and L/2,000 were considered and the modes of shape imperfections of the symmetric and antisymmetric were adopted. The effects of the shape imperfections on the dynamic behavior of arch were conspicuous and results of analysis indicate that the reasonable values of arch rise to arch span ratio ranged between 0.1 and 0.3.

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Analysis of organic germanium, Ge-132 (유기게르마늄 화합물인 Ge-132의 분석법)

  • Park, Man Ki;Park, Jeong Hill;Han, Sang Beom;Park, Il Ho
    • Analytical Science and Technology
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    • v.8 no.3
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    • pp.371-374
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    • 1995
  • An organic germanium compound, Ge-132, was reported to have interferon inducer activity, anti-tumor activity and anti-viral activity. ICP, AA and colorimetry methods were used for the determination of germanium in Ge-132. However these methods have a problem that they only give an information on the total amount of germanium element, and consequently Ge-132 connot be distinguished form toxic inorganic Ge compounds. To overcome this problem, ion chromatography was used to analyze Ge-132. Ge-132 was separated on Ionpac AS4A column with 1.3mM $Na_2B_4O_7$ buffer(pH=9.2) solution as an eluent and detected by the conductivity detector. Correlation coefficient of the calibration curve was 0.999 and the detection limit measured at S/N ratio of 3 was 50pmol. This method was applicable to the analysis of Ge-132 raw material and Ge-132 preparations.

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A Study on the Electroless Ni-Cu-P Alloy Plating of Al Base Hard Disk(I)Effect on some Properties of Electroless Ni-Cu-P Deposits by Electrolyte and Heat Treatment Condition (알루미늄 기판의 무전해 니켈-구리-인 합금도금에 관한 연구(I) 전해액 및 열처리 조건이 무전해 니켈-구리-인 도금층의 제 물성에 미치는 영향)

  • 오이식;황용길
    • Journal of the Korean institute of surface engineering
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    • v.24 no.2
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    • pp.103-113
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    • 1991
  • Electroless Ni-Cu-P alloy plating of Al base hard disk was performed to investigate some properties according to the change of composition. It was found that the composition of Ni and Cu in deposits changed linearly with increasing the mole ratio of NiSO4.6H2O/CuSO4.5H2O. The increase in hardness by heat - treatment was confirmed to be associated with small size grained crystallization of the amorphous deposits. Acid resistance of all deposits layer. which had been heated up to 30$0^{\circ}C$, was found to be exellent when immersed in 1N-H2SO4 solution, and it showed more superior acid resistance with decreasing Cu content and with increasing P. The resistivity of the deposits heat treated became smaller at temperature more than 50$0^{\circ}C$, and it became largerly with increasing P content. Cu 44.1wt% alloy(C bath) showed the most superior non-magnetically stable characteristics after heat treatment. It was superiorly with higher temperature and with decreasing P content.

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Room Temperature Growth of Magnetite Films on Arachic Acid Monomolecular Layers

  • Ishihara, Takashi;Kitamoto, Yoshitaka;Shirasaki, Fumio;Abe, Masanori
    • The Korean Journal of Ceramics
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    • v.6 no.4
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    • pp.401-404
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    • 2000
  • Mimicking the bacterial synthesis of magnetosomes, in which the functionalized surface of a cytoplasmic (lipid) membrane is considered to be stimulating the crystal growth of magnetite, we have successfully grown magnetite films at $30^{\circ}C$ using an arachic acid monomolecular layer as a functionalized surface. The lipid monomolecular layer was spread on an aqueous solution of FeCl$_2$ which was oxidized by flowing a mixed gas, with ratio $O_2$/$N_2$=1/2000, on the surface of the lipid layer. Mossbauer and X-ray diffraction analyses revealed that the Fe$_3$O$_4$ films contain small amounts of ferric hydroxyl impurity phases of ${\alpha}$-FeOOH and ${\tau}$-FeOOH. This is because the oxygen partial pressure at the ferrite/aqueous interface changed as the film (through which the gas penetrated) increased in thickness. Methods to obtain single phase magnetite films are proposed.

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Fabrication and Electrical Properties of SCT thin Film with Substitution Contents of Ca (Ca 치환량에 따른 SCT 박막의 제조 및 전기적 특성)

  • Kim, Jin-Sa;Lee, Joon-Ung
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.10
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    • pp.559-563
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    • 2000
  • The $(Sr_{1-x}Ca_x)TiO_3(SCT)$ thin films are deposited on Pt-coated(Pt/TiN/$SiO_2$/Si) using RF sputtering method with substitutional contents of Ca. The maximum grain of thin films is obtained by substitution of Ca at 15[mol%]. Also the composition of SCT thin films were closed to stoichiometry(1.081∼1.117 in A/B/ ratio). The dielectric constant was increased with increasing the substitutional contents of Ca, while it was decreased if the substitutional contents of Ca exceeded over 15[mol%]. The dielectric constant changes almost linearly in temperature ranges of -80∼+90[^${\circ}C$]. The temperature properties of the dielectric loss have a stable value within 0.02 independent of the substitutional contents of Ca. All SCT thin films used in this study show the phenomena of dielectric relaxation with the increase of frequency, and the relaxation frequency is observed above 2000[kHz]. The current-voltage characteristics of SCT15 thin films showed the increasing leakage current as the measuring temperature increase.

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Hydrochloric Acid Leaching of Arsenic from Arsenic-Bearing Copper Slime. (동전련 부산물인 함비소 동슬라임으로부터 염산에 의한 비소의 침출)

  • 유용주;황필규
    • Resources Recycling
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    • v.1 no.1
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    • pp.51-57
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    • 1992
  • The hydrochloric acid leaching has been studied as a fundamental experiment on the recovery of arsenic from arsenic-bearing copper slime in copper electrorefining. The slime is mainly composed of $\beta-Cu_3As$ Which is intermetallic compound of CU and As. And the minor components are $CU_2O$ and CusAs in the slime. The optimum conditions of leaching of the slime were found to be as follows : 6N hydrochloric acid, particle size passed through 140 mesh, leaching for 150 min at $60^{\circ}C$, ratio of HCI/slime of 3 to 1 ; where 98 percent of arsenic were leached out of the As-bearing slime.

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Deposition and Properties of Pt/ST/Pt Thin Film Structure (Pt/ST/Pt 소자 구조의 박막증착 및 특성)

  • Kim, Jin-Sa;Cho, Choon-Nam;Oh, Yong-Cheul;Shin, Cheol-Gi;Song, Min-Jong;So, Byeong-Mun;Choi, Woon-Shick;Kim, Chung-Hyeok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.472-473
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    • 2007
  • The $(Sr_{1-x}Ca_x)TiO_3$(ST) thin films are deposited on Pt-coated electrode(Pt/TiN/$SiO_2$/Si) using RF sputtering method with substitutional contents of Ca. The maximum grain of thin films is obtained by substitution of Ca at 15[mol%]. Also, the composition of ST thin films were closed to stoichiometry(1.081~1.117 in A/B ratio). The dielectric constant changes almost linearly in temperature ranges of -80~+90[$^{\circ}C$]. The current-voltage characteristics of ST15 thin films showed the increasing leakage current as the measuring temperature increases.

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