• Applied Chemistry for Engineering
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• v.27 no.1
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• pp.92-100
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• 2016

Low-temperature conversion of nitrogen oxides using plasma-assisted hydrocarbon selective catalytic reduction of (HC-SCR) was investigated. Plasma was created in the catalyst-packed bed so that it could directly interact with the catalyst. The effect of the reaction temperature, the shape of catalyst, the concentration of n-heptane as a reducing agent, the oxygen content, the water vapor content and the energy density on $NO_x$ removal was examined. $NO_x$ conversion efficiencies achieved with the plasma-catalytic hybrid process at a temperature of $250^{\circ}C$ and an specific energy input (SIE) of $42J\;L^{-1}$ were 83% and 69% for one-dimensional Ag catalyst ($Ag\;(nanowire)/{\gamma}-Al_2O_3$) and spherical Ag catalyst ($Ag\;(sphere)/{\gamma}-Al_2O_3$), respectively, whereas that obtained with the catalyst-alone was considerably lower (about 30%) even with $Ag\;(nanowire)/{\gamma}-Al_2O_3$ under the same condition. The enhanced catalytic activity towards $NO_x$ conversion in the presence of plasma can be explained by the formation of more reactive $NO_2$ species and partially oxidized hydrocarbon intermediates from the oxidation of NO and n-heptane under plasma discharge. Increasing the SIE tended to improve $NO_x$ conversion efficiency, and so did the increase in the n-heptane concentration; however, a further increase in the n-heptane concentration beyond $C_1/NO_x$ ratio of 5 did not improve the $NO_x$ conversion efficiency any more. The increase in the humidity affected negatively the $NO_x$ conversion efficiency, resulting in lowering the $NO_x$ conversion efficiency at the higher water vapor content, because water molecules competed with $NO_x$ species for the same active site. The $NO_x$ conversion efficiency increased with increasing the oxygen content from 3 to 15%, in particular at low SIE values, because the formation of $NO_2$ and partially oxidized hydrocarbon intermediates was facilitated.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.4
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• pp.390-393
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• 2005

N-nitrosodimethylamine (NDMA), a potent carcinogenic, has recently been observed at drinking water supply systems in USA and Canada. The NDMA formation was studied as a function of chloramine concentration (0.001-0.1 mM) at a fixed dimethylamine (DMA) concentration of 0.05 mM at different initial pH (6, 7, 8). It was found that the NDMA formation rate varied with pH values. The formation of NDMA increased with increasing chloramine concentration and showed maximum yields of 2.4% and 1.6% at pH 7 and 8, respectively. A good correlation ($r^2>0.99$) was observed between the molar ratio (chloramine/DMA) and NDMA formation at pH 7 and 8. Linearity of the NDMA formation appeared to be related to chloramine concentrations.

• Magazine of the Korean Society of Agricultural Engineers
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• v.23 no.3
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• pp.78-87
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• 1981

This study was attempted to get dimensionless unit hydrograph by linear model which can be used to the estimation of flood for the development of Agricultural water resources and laid emphasis on the application of dimensionless unit hydrographs for the ungaged watersheds by applying linear model. The results summarized through this study are as follows. 1.Peak discharge is found to be Qp= CAR (C =0. 895A-o.145) having high significance between peak discharge, Qp and effective rainfall, R within the range of small watershed area, 84 to 470km2. consequently, linearity was acknowledged between rainfall and runoff. Reasonability is confirmed for the derivation of dimensionless unit hydrograph by linear model. 2.Through mathematical analysis, formula for the derivation of dimensionless unit hydrograph was derived. qp--p=(tp--t)n-1[e-(n-1)](tp--t-1) 3.Moment method was used for the evaluation of storage constant, K and shape parameter, n for the derivation of dimensionless unit hydrograph. Storage constant, K is more closely related with the such watershed characteristics as length of main stream and slopes. On the other hand, the shape parameter, n was derived with such watershed characteristics as watershed area, river length, centroid distance of the basin and slopes. 4.Time to peak discharge, Tp could be expressed as Tp=1. 25 (√s/L)0.76 having a high significance. 5.Dimensionless unit hydrographs by linear model stood more closely to the observe dimensionless unit hydrographs On the contrary, dimensionless unit hydrographs by S.C. S. method has much difference in comparison with linear model at the falling limb of hydrographs. 6.Relative errors in the q/qp at the point of 0.8 and 1.2 for the dimensionles ratio by linear model and S. C. S. method showed to be 2.41, 1.57 and 4.0, 3.19 percent respectively to the q/qp of observed dimensionless unit hydrographs. 7.Derivation of dimensionless unit hydrograph by linear model can be accomplished by linking the two empirical formulars for storage constant, K, and shape parameter, n with derivation formular for dimensionless unit hydrograph for the ungaged small watersheds.

• Journal of Chest Surgery
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• v.25 no.1
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• pp.1-16
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• 1992

The quantitatively measured local myocardial perfusion rates with microspheres are used as an objective indicator of even distribution of cardioplegic solution, and the efficacy of the retrograde right atrial route of cardioplegia is evaluated in hearts with various levels of coronary arterial obstruction. After initial antegrade cardioplegia under the median sternotomy and aortic cannulation, 60 hearts from anesthetized New Zealand white rabbits are divided in random order as normal group [ligated left main coronary artery ; MA, MR] and diagonal group [ligated proximal diagonal artery ; LA, LR]. Half of each group [N=10] are perfused with antegrade cardioplegia[A] under the pressure of 100 cmH2O and the other half with retrograde right atrial route[R] under the pressure of 60 cmH2O[St. Thomas cardioplegic solution mixed with measured amount of microspheres]. The myocardium is subdivided into segments as A[atria], RV[right ventricle]. S[septum], LV[normally perfused left ventricular free wall], ROI[ischemic myocardium of left ventricular free wall]. LV and RQI are further divided into N[subendocardium] and P[subepicardium]. The resulting local myocardial perfusion rates and N /P of each group are compared with Wilcoxon rank sum test. The weight of the hearts is 5.94$\pm$0.66g, and there are no statistically significant dif-ferences[p>0.05, ANOVA] between six compared group. The mean flow rate[F: ml /g / min] of MR group is comparable with MA group[p>0.05], but in N and L group, there are significantly depressed F with right atrial route of cardioplegia, which means elevated perfusion resistance with this route. In spite of no significant differences in delivered doses of microsphere[DEL] between compared groups[p>0.05, ANOVA], there are significantly depressed REC and NF in hearts with right atrial cardioplegia which suggests increased requirement of cardioplegic solution with this route. The interventricular septum shows poor perfusion with right atrial route of cardioplegia without obstruction of supplying coronary arteries. But, with obstruction of coronary artery supplying septum as in M group, the flow rate is superior with right atrial route of infusion. The left ventricular free wall perfusion rates of every RQI with R route are superior to that of A route[p<0.05]. But, in LV segments, there are unfavorable effects of right atrial cardioplegia in L group, although the subendocardial perfusion is well maintained in N group. The LV free wall of left main group shows depressed perfusion rates with antegrade route as compared with RQI segments of diagonal group. But, by contraries, there are increased perfusion rates and superior N /P ratio with retrograde right atrial route. It implies more effective perfusion with right atrial route of cardioplegia in more proximal coronary arterial obstruction[i.e., M group as compared with L group]. As a conclusion, all region of ischemia have superior perfusion rates with right atrial car-dioplegia as compared with antegrade route, and especially excellent results can be obtained in hearts with more proximal obstruction of coronary arteries which would otherwise result in more severe ischemic damage. But, the depressed perfusion rates of the segments with normal coronary artery in hearts with coronary arterial obstruction may be a problem of concern with right atrial cardioplegia and needs solution.

• Journal of the Korean Chemical Society
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• v.47 no.1
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• pp.13-18
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• 2003

The effect of ultrasonic decomposition was introduced to develop a pretreatment method for the analysis of potassium ion in human urine by potentiometry. N-(4’-benzo-15-crown-5)-anthracene-9-imine, which has a good selectivity coefficient for potassium against ammonium, was used as an ion-selective material for the determination of potassium in urine with relatively high concentration of $NH_4{^+}$. Protenis in urine be removed by 85.1% when the sample acidified with 1.0 M $HNO_3$ was preteated for 100 s by sonication. Potential response of the membrane electrode in the pretreated urine had a slope of 54.6(${\pm}0.2,\;n=5$) mV/decade over the linear range of log $[K^+]$=-5~-1(r=0.9997). When an oxidant, $H_2O_2$, was addwd to the urine sonicated with $HNO_3$, the deproteinization increased 10% more than that in case if only $HNO_3$ and then the maximum ratio of ca. 95% was obtained. Moreover, the Nernstian slope for $K^+$ added to the urinary sample increased to 56.7(${\pm}0.1,\;n=3$) mV/decade. When the calibration curves were measured, the slopes did not vary even after the electrode was successively used 20 times with ultrasonic cleaning. The results showed that an ultrasonic pretreatment method provides simplicity in use, reduced treatment time and improved potentiometric characteristics of the membrane as the method effectively removes ca. 95% of proteins in urine.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.8 no.2
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• pp.94-94
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• 1999

Natural gas is considered to be on e of the most promising candidates for a clean substitute fuel and a great amount of research on the compressed natural gas(CNG) fueled vehicle has been performed. In this s tudy, we try to understand the property of CNG fuel with using CNG engine experiment. In order to present the direction and application of CNG, we experiment with various operating conditions that is, spark timing, A/F ratio, air quantity and fuel quantity, etc. 11,967 cc engine was used in the experiment and the engine fuel ratio was determined in the way that the performance of dedicated CNG engine is corresponded to that of existing diesel engine. The performance and dedicated CNG engine were measured by changing the fuel injection timing. The dedicated CNG engine was proved to be good in describing the experimental results and according to the actual road test, acceleration and constant speed driving for dedicated CNG engine was better than existing diesel engine.

• Textile Coloration and Finishing
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• v.28 no.1
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• pp.33-39
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• 2016

The crystal structure of nylon 56 fibers post extended by drawing process was investigated by synchrotron x-ray scattering measurement. In as-cast fiber, distinct (004) and (020) diffraction peaks were observed and they were related to initial metastable alignment of nylon molecules. With increase in the drawing ratio, (110) peak intensity was increased in vertical direction with decreasing (020) peak. At the same time, (004)' peak evolved position tilted to 29 degrees from the (004) peak. This evolution is directly related to stable crystalline phase of nylon 56 originated from additional formation of hydrogen bondings between N-H and C=O by post drawing process. We also compared density variation, stress-strain curves of the fiber as a function of drawing ratio and strain. The variations of density and tanacity also supported the increase of stable structure of nylon 56.

• Nuclear Engineering and Technology
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• v.52 no.8
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• pp.1764-1770
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• 2020

The present work was mainly concerned with studying the operation of RC-phase shift oscillator based on MOSFET type 2N6660 under the influence of different temperature levels ranging from room temperature (25 ℃) up-to135 ℃ and gamma-irradiation up-to 3.5 kGy. In this concern, both the static (I-V) characteristic curves of MOSFET devices and the output signal of the proposed oscillator were recorded under ascending levels of both temperature and gamma-irradiation. From which, it is clearly shown that the drain current was decreased from 0.22 A, measured at 25 ℃, down to 0.163 A, at 135 ℃. On the other hand, its value was increased up-to 0.49 A, whenever the device was exposed to gamma-rays dose of 3.5 kGy. Considering RC-phase shift oscillator, the oscillation frequency and output pk-pk voltage were decreased whenever MOSFET device exposed to gamma radiation by ratio 54.9 and 91%, respectively. While, whenever MOSFET device exposed to temperature the previously mentioned parameters were shown to be decreased by ratio 2.07 and 46.2%.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07a
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• pp.519-522
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• 2002

Ag (silver) can be used for YBa$_2$Cu$_3$O$\_$7-$\delta$/(YBCO) coated conductor tape as the substrate on which YBCO can be deposited directly because of the chemical compatibility of Ag with YBCO. We have fabricated rolled Ag tapes with various total reduction ratios and different thicknesses. As-rolled Ag tape was recrystallized at 750$^{\circ}C$ for 30min in air and vacuum of 10$\^$-3/ torr. The orientation distribution functions (ODF) calculated from three x-ray pole figures of as-rolled and recrystallized tapes were analysed. As the total reduction ratio increased from 94 to 98%, the development of {110}texture of as-rolled Ag improved. Under the present experimental condition, maximum {110}ODF value of Ag tape was obtained for the sample with 94% total reduction ratio which was recrystallized at 750$^{\circ}C$ for 30min in vacuum of 10$\^$-3/ torr.

• Journal of Environmental Science International
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• v.17 no.3
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• pp.269-273
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• 2008

The objective of this study was to evaluate the relationship between nutrients and phytoplankton. This study was done by the comparison to two costal areas Mokpo, which inflow fresh water, and Wando. In August, salinity of the sea water decreased by 3.5-4.5%o in Mokpo coastal area, but was not nearly decreased in Wando coastal area. This suggests a lot of fresh water inflow in Mokpo coastal area. DIN and DIP were decreased by water temperature increasing in Wando. However, in Mokpo, DIN and DIP were increased greatly during the summer season. Nitrogen was limited to a 10 NIP ratio especially during the summer season in Wando coastal area while phosphorus in Mokpo coastal area was limited with over 28 N/P ratio in all the seasons. Coefficient of determination$(r^2)$ between DIP and Chl.-a was 0.91 in Mokpo coastal area. On the other hand, Coefficient of determination$(r^2)$ between Chl.-a and DIN, DIP were 0.93 and 0.89, respectively, in Wando coastal area. These results suggest DIP in Mokpo and DIN and DIP in Wando might be limited at the increase of phytoplankton.