• Title/Summary/Keyword: O:N ratio

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Hydrogeochemical and geostatistical study of shallow alluvial groundwater in the Youngdeok area

  • Kim, Nam-Jin;Yun, Seong-Taek;Kwon, Man-Jae;Kim, Hyoung-Soo;Kim, Chang-Hoon;Koh, Yong-Kwon
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.232-236
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    • 2000
  • Multi-regression statistical analyses were applied for the water quality data of shallow alluvial ground water (n = 47) collected from the Youngdeok area, in order to quantitatively generalize the natural (non-anthropogenic) causes of regional water quality variation. Seven samples having the high contamination index ( $C_{a}$ > 3) reflect the striong effects by anthropogenic activity. Most of the alluvial groundwaters have acquired their quality primarily due to the dissolution of carbonate minerals. The results of multi-regression analysis show that chlorine is mainly derived from seawater effect. Sulfur isotopic compositions of dissolved sulfur and the S $O_4$/Cl ratio also enable us to discriminate the samples (n = 18) which are affected by atmospheric input of marine aerosol (sea-spray) and also by mixing between freshwater and seawater. Hydrogen and oxygen isotope data of the samples collected lie close to the local meteoric water line obtained from nearby Pohang city but has lower slope (5.45) on the $\delta$D-$^{18}$ O plot, indicating that alluvial groundwater was recharged from infiltrated meteoric water which has undergone some degree of kinetic evaporation. The estimated initial isotopic composition of the recharged water ($\delta$D = -74.8$^{0}$ /$_{00}$, $\delta$$^{18}$ O = -10.8$^{[-1000]}$ /$_{[-1000]}$ ) suggests that the alluvial ground water recharge largely occurs during summer storm events.s.s.

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On the error rate of multicode-CDMA system in frequency selective fading channel (주파수 선택적 페이딩 채널에서 멀티코드 CDMA 시스템의 성능 분석)

  • 김연진;김남수;김민택
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.23 no.4
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    • pp.932-939
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    • 1998
  • In this paper, we analyze the performance of a multicode-CDMA system which have been proposed for the multimedia communications. The performance of a multicode-CDMA system, providing good spectrum efficiency as well as serving various bit rates, is analyzed with multipath, frequency selective, slowly fading Rayleigh channel. Also the proposed scheme adopting RAKE receiver with MRC(Maximal Ratio Combine) is advantageous to multipath channel. For a practical channel modeling, the JTC(Joint Technical Committee) recommended channel model(JTC(AIR) 23-065R6) is applied to simulation. The proposed schemehas serial-to-parallel convertor which splits input data stream of 2 Mits/s into 20 branches o 100 kbits/s. From the result of simulation, the case of RAKE receiver with 3 fingers to reduce the system complexity required the relatively large $E_{b}/N_O$ of 0 dB~1.5 dB, compared to the case of RAKE receiver with the number of path finger to keep the average error rate to be $1{\times}10^{-3}$ in channel A.

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Analysis of Variables Influencing the Pressure Build-up and Volume Expansion of Kimchi Package (김치포장의 압력 및 부피 변화에 영향을 미치는 인자의 분석)

  • 이동선;최홍식;박완수
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.2
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    • pp.429-437
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    • 1999
  • A mathematical model was established for estimating changes in pressure and volume of permeable kimchi packages. The model comprises the CO2 gas production from kimchi and permeation of O2, CO2 and N2 through the permeable film or sheet. Using the developed model, the effects of various packaging variables on the pressure and volume changes were analyzed for rigid and flexible packag es of kimchi(3% salt content) at 15oC, and then effect of storage temperature was also looked into. In case of rigid pack of 400g, using the plastic sheet of high CO2 permeability and initial vacuumizing can help to relieve the problem of pressure build up. The lower fill weight can further reduce the pressure, but will result in higher packaging cost. For the flexible package of 3 kg, highly permeable films such as low density polyethylene(LDPE) and polypropylene can reduce the volume expansion. Higher ratio of CO2 permeability to O2 and N2 permeabilities are effective in reducing the volume expansion. Increased surface area cannot contribute to reduction of volume expansion for highly permeable flexible packages of kimchi. For the impermeable packages, pressure and volume at over ripening stage (acidity 1.0%) increase with decreased temperature, while those at optimum ripening stage(acidity 0.6%) change little with temperature. Pressure of permeable rigid LDPE package increases with tem perature at any ripening stage, and temperature affects the volume of flexible LDPE package very slightly. Experimental verification of the present results and package design with economical consid eration are needed as a next step for practical application.

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A Two-Stage Process, $O_3$ and Subsequent $O_3/H_2O_2$, for Effective Color Removal from Leather-Dyeing Wastewater: Case Study in the D Industrial Wastewater Treatment Plant (피혁염색폐수의 색도저감을 위한 오존, 오존/과산화수소 2단 공정에 관한 연구: D 산업폐수처리장 사례연구)

  • Yoon, Yeojoon;Park, Moonki;Kwon, Minhwan;Jung, Youmi;Kang, Joon-Wun
    • Journal of Korean Society on Water Environment
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    • v.29 no.1
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    • pp.74-80
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    • 2013
  • The aim of this study is to evaluate color removal from leather-dyeing wastewater using $O_3$ and $O_3/H_2O_2$ unit processes and a serial process for $O_3$, followed by the $O_3/H_2O_2$ process. The color removal rate of the $O_3$ alone process was only 65% effective, and the color increased when an applied $O_3$ dose of more than 40 ~ 50 mg/L was applied. On the other hand, the color was completely removed without increments of color by the $O_3/H_2O_2$ process with $H_2O_2$ injection ratio of 0.2 and 0.3 (wt. $H_2O_2$/wt. $O_3$). Even though the injection of $H_2O_2$ had an effect on color removal, the color removal rates from $O_3$ alone and from $O_3/H_2O_2$ were similar up to the initial $O_3$-demand stage with an application of 0 ~ 40 mg/L $O_3$. In conclusion, it was found that the $O_3$ followed by the $O_3/H_2O_2$ serial process, the method injecting $H_2O_2$ after ozonation with $O_3$-demand (30 ~ 40 mg/L) in the first stage, is the most appropriate process for effective color removal from leather-dyeing wastewater.

Performance Evaluation of Tertiary Post-denitrification Processes for the Reuse of Secondary Effluent from Wastewater Treatment Plant (하수2차처리수의 재이용을 위한 후탈질공정의 평가)

  • Lee, Chanho;Yun, Zuwhan;Yi, Yun Seok;Lee, Han Saem;Ahn, Dong Keun
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.642-649
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    • 2007
  • The effectiveness of add-on tertiary treatment processes for the polishing of the effluent of a biological nutrient removal (BNR) system from a modified $A^2/O$ process has been examined under the field condition with pilot-scale plants. The add-on treatment processes of 1) combined biofilm anoxic reactor and sand filtration, and 2) two-stage denitrification filter had been operated with various operating conditions. The experimental results indicated that two-stage denitrification filter could produced a better polished tertiary effluent. Filtration rate of $150m^3/m^2{\cdot}d$ for the 2-stage denitrifying filter could decrease the nitrate removal probably due to shorter detention time that caused insufficient reaction for denitrification. Two stage denitrification filter operated with M/N ratio of 3.0 and filtration rate of $100m^3/m^2{\cdot}d$ produced the tertiary effluent with nitrate and SS concentraitons of 2.8 mg/L and 2.3 mg/L, respectively. When the operating temperature reduced $30^{\circ}C$ to $18^{\circ}C$, $NO_3{^-}-N$ removal efficiency decreased from 73% to 68%.

Relationship between the Mineral Nutrients up-take and the age of Ginseng Plant (Panax Ginseng C.A. Meyer) (인삼(人蔘)의 연근별(年根別) 무기양분흡수(無機養分吸收)에 관(關)한 연구(硏究))

  • Lee, J.H.;Nam, K.Y.;Kim, M.S.;Bae, H.W.
    • Applied Biological Chemistry
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    • v.21 no.1
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    • pp.58-62
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    • 1978
  • Dry weight, and mineral content in leaves, stems, and roots of the ginseng plant (Panax ginseng C.A. Meyer) were investigated. The highest T/R ratio, 0.52, was observed in a four year old plant due to a vigorous growth of the plant at this age. Also the dry weight increase was rather higher in the younger root than the older one. Mineral content of the plant was rather higher in the younger root than the older one. Potassium content in leaves and stems was higher than those of nitrogen and phosphorus. Generally, the leaves contained more iron and manganese than any other micronutrients. The iron content amounted to $1,000{\sim}2,000ppm$ in leaves. Zinc content was higher in stems and leaves than roots especially in stems of the younger roots. Total amount of the up-taken N, $P_2O_5$, and $K_2O$ per 10a in six years was 10.2kg, 2.3kg and 14.9kg respectively, indicating the considerable abounts of $K_2O$ was absorbed.

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Synthesis and Characterization of Mono-sulfonated Poly(ether sulfone) for a Fuel Cell Application (고분자 전해질 연료전지용 Sulfonated Poly(ether sulfone)의 합성 및 특성 평가)

  • Krishnan N.N.;Kim H.-J.;Prasanna M.;Cho E.-A.;Oh I.-H.;Hong S.-A.;Lim T.-H.
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.235-238
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    • 2005
  • Sulfonated poly(ether sulfone) copolymers (PESs) were synthesized using hydroquinone 2-potassium sulfonate (HPS) with other monomers (bisphenol A and 4-fluorophenyl sulfone). PESs with different $mole\%$ of hydrophilic group were prepared by changing the mole ratio of HPS in the polymerization reaction. The chemical structure and the thermal stability of these polymers were characterized by using $^1H-NMR$, FT-IR and TGA techniques. The PES 60 membrane, which has $60 mole\%$ of HPS unit in the polymer backbone, has a proton conductivity of 0.091 S/cm and good insolubility in boiling water. The TGA showed that PES 60 was stable up to $272^{\circ}C$ with a char yield of about $29\%\;at\;900^{\circ}C\;under\;N_2$ atmosphere. To investigate the single cell performance, the catalyst coated PES 60 membrane was used and a single cell test was carried out using $H_2/O_2$ gases as fuel and oxidant at various temperatures. We observed that the cell performance was enhanced by increasing the cell temperature. A current density of $1400 mA/cm^2$ at 0.60 V was obtained at $70^{\circ}C$.

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A Characteristics of Environmental Fraternitive Photopolymerization and Thermal Degradation on Butyl Methacrylate (부틸메타크릴레이트의 환경친화적인 광중합 및 열분해특성)

  • Choi, Jae-Wook;Seul, Soo-Duck;Lee, Nae-Woo
    • Journal of the Korean Society of Safety
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    • v.17 no.2
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    • pp.45-51
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    • 2002
  • This study is the series of photopolymerization on alkyl methacrylate(AMA) to continue further research. The objective of this work is to investigate the environmental fraternitive characteristics of photopolymerization kinetics on n-Buthyl methacrylate(BMA) and comparing the decomposition behavior to other AMA. The experiment was done in aqueous solution under the influence of photo-initiator concentration$(0.05{\sim}0.25mol/l)$, light intensity$(5000{\sim}9000{\mu}J/cm^{2})$ and monomer concentration$(2.0{\sim}6.0mol/l)$. n-BMA was polymerized to high conversion ratio using hydrogen $peroxide(H_{2}O_{2})$, and the kinetics model we have obtained is as follows. $R_{p}=K_{p}[S]^{0.24}[M]^{0.33}[L]^{153}exp^{(27.19/RT)}$ The differential method of thermogravimetric analysis(Friedman method) was used to obtain value of activation energy on decomposition reaction. The average value of it was 27.5Kcal/mol.

Studies on the Soil Management in Ginseng Preplanting Soil (II) Relationship between the Soil Characteristics of 2-Year-Old Ginseng Field Soil and the Ratio of Missing Plant (인삼식부 예정지의 토양관리에 관한 연구 제2보. 2연근포지의 토양 특성변화 및 결주율과의 관계)

  • 이일호;박찬수
    • Journal of Ginseng Research
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    • v.9 no.1
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    • pp.36-41
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    • 1985
  • The study was conducted to investigate the changes of soil physico-chemical properties between soils of preplanting fields and 2 years old ginseng fields, and compare the missing plant rate among the 2 years 016 ginseng fields. 1, The missing plant rate of 2 years old ginseng was high in sand loam while low in clay loam soil texture, soil porosity and NO3-N were remarkably increased in 2 years old ginseng field than preplanting soil, as the clay content was increased, soil porosity seemed to be increased but exchangeable nitrogen decreased. 2. The preplanting soil management methods did not significantly influenced on the missing plant rate and soil porosity in 2 years old ginseng fields, However NO3-N content and Fusarium density seemed to be decreased as the plow frequency was increased, exchangeable nitrogen content, whereas, seemed to be increased with more organic matter. 3. Differences of clay content (below 15% and above 20% of clay content) was significantly influenced on soil porosity, bulk density, total nitrogen, organic matter and P2O5 content. 4, Missing rate showed negative correlation with clay, soil moisture, and organic matter content but positive corelation with NO3-N in 2 years old ginseng fields.

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Synthesis and Characterization of Thermosensitive Poly(organophosphazenes) with Methoxy-Poly(ethylene glycol) and Alkylamines as Side Groups

  • Lee, Bae-Hoon;Lee, Young-Moo;Sohn, Yoon-Soo;Song, Soo-Chang
    • Bulletin of the Korean Chemical Society
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    • v.23 no.4
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    • pp.549-554
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    • 2002
  • Thermosensitive poly(organophosphazenes) bearing methoxy-poly(ethylene glycol) (MPEG) and alkylamines as substituents have been synthesized and characterized by elemental analysis, NMR spectroscopy, GPC, and DSC. All the polymers exhibited crystallinity, which was probably induced by the MPEG side chain of the polymers. All the polymers exhibited the lower critical solution temperature (LCSTs) in the range of 28 to $94^{\circ}C$ depending on several factors such as mole ratio of the substituents, kinds of PEG and alkylamines. The higher content of MPEG and shorter chain length of alkylamines of the polymers afforded the higher LCST. The LCSTs of the polymers exhibited almost concentration-independent behavior in the range of 3-30 wt % of the polymers in aqueous solutions. The polymers showed the higher LCSTs in the acidic solutions than in the neutral and basic solutions. The ionic strength of the polymer solution affected the LCST, which decreased with increased NaCl concentration. The polymer bearing almost equimolar substitutuents with the -N-P-N- unit has shown the LCST more sensitive to NaCl and pH than that with the -N-P-O- unit. The polymers were found to degrade in acidic solution but be very stable in alkali solution as well as in the buffer solution of pH 7.4.