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A Two-Stage Process, $O_3$ and Subsequent $O_3/H_2O_2$, for Effective Color Removal from Leather-Dyeing Wastewater: Case Study in the D Industrial Wastewater Treatment Plant  

Yoon, Yeojoon (Department of Environmental Engineering, Yonsei University)
Park, Moonki (Department of Environmental Engineering, Yonsei University)
Kwon, Minhwan (Department of Environmental Engineering, Yonsei University)
Jung, Youmi (Department of Environmental Engineering, Yonsei University)
Kang, Joon-Wun (Department of Environmental Engineering, Yonsei University)
Publication Information
Journal of Korean Society on Water Environment / v.29, no.1, 2013 , pp. 74-80 More about this Journal
Abstract
The aim of this study is to evaluate color removal from leather-dyeing wastewater using $O_3$ and $O_3/H_2O_2$ unit processes and a serial process for $O_3$, followed by the $O_3/H_2O_2$ process. The color removal rate of the $O_3$ alone process was only 65% effective, and the color increased when an applied $O_3$ dose of more than 40 ~ 50 mg/L was applied. On the other hand, the color was completely removed without increments of color by the $O_3/H_2O_2$ process with $H_2O_2$ injection ratio of 0.2 and 0.3 (wt. $H_2O_2$/wt. $O_3$). Even though the injection of $H_2O_2$ had an effect on color removal, the color removal rates from $O_3$ alone and from $O_3/H_2O_2$ were similar up to the initial $O_3$-demand stage with an application of 0 ~ 40 mg/L $O_3$. In conclusion, it was found that the $O_3$ followed by the $O_3/H_2O_2$ serial process, the method injecting $H_2O_2$ after ozonation with $O_3$-demand (30 ~ 40 mg/L) in the first stage, is the most appropriate process for effective color removal from leather-dyeing wastewater.
Keywords
Color removal; $H_2O_2$; Leather-dyeing wastewater; $O_3$; $O_3$-demand; Serial process;
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