• Title/Summary/Keyword: O:N ratio

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Effects of Nitrogen , Phosphorus and Potassium Application Rates on Oversown Hilly Pasture under Different Levels of Inclination II. Changes on the properties, chemical composition, uptake and recovery of mineral nutrients in mixed grass/clover sward (경사도별 3요소시용 수준이 겉뿌림 산지초지에 미치는 영향 II. 토양특성 , 목초의 무기양분함량 및 3요소 이용율의 변화)

  • 정연규;이종열
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.5 no.3
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    • pp.200-206
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    • 1985
  • This field experiment was undertaken to assess the effects of three levels of inclination ($10^{\circ},\;20^{\circ},\;and\;30^{\circ}$) and four rates of $N-P_2O_5-K_2O$ (0-0-0-, 14-10-10, 28-25-25, and 42-40-40kg/10a) on establishment, yield and quality, and botanical compositions of mixed grass-clover sward. This second part is concerned with the soil chemical properties, concentrations and uptake of mineral nutrients, and percent recovery and efficiency of NPK. The results obtained after a two-year experiment are summarized as follows: 1. The pH, exchangeable Mg and Na, and base saturation in the surface soils were decreased by increasing the grade of inclination, whereas organic matter and available $P_2O_5$ tended to be increased. However, the changes in the Ca content and equivalent ratio of $K\sqrt{Ca+Mg}$ were not significant. The pH, exchangeable Ca and Mg, and base saturation were reduced by increasing the NPK rate, whereas available $P_2O_5$, exchangeable K, and equivalent ratio of $K\sqrt{Ca+Mg}$ tended to be increased. 2. The concentrations of mineral nutrients in grasses and weeds were not significantly affected by increasing the grade of slope in hilly pasture, whereas the concentrations of N, K, and Mg in legume were the lowest with the steep slope, which seemed to be related to the low legume yield. The Mg concentrations of all forage species were below the critical level for good forage growth and likelihood of grass tetany. 3. The increase of NPK rate resulted in the increment of N, K and Na concentrations, and the decrease of Mg and Ca in grasses. The P concentration was increased with P application, but there were no differences in that among the P rates applied. It resulted also in a slight increase of K, and a decrease of Mg in legume, but the contents of N, Ca, and Na were not affected by that. On the other hand, it has not affected the mineral contents in weeds except a somewhat increase of N. The mixed forages showed a increase of N and K contents, a decrease of Ca and Mg, and a slight change in P and Na. 4. The percent recovery of N, P and K by mixed forages were greatly decreased by increasing the grade of inclination and NPK rate. They were high in the order; K>N>P. The efficiency of mixed NPK applications was decreased by that. The efficiency of mixed NPK fertilizers absorbed was slightly decreased by the increased rate of NPK, but it was not affected by the grade of inclination.

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The Etching Characteristics of the TaN Thin Films Using Inductively Coupled Plasma (유도 결합 플라즈마를 이용한 TaN 박막의 건식 식각 특성)

  • Li, Chen;Joo, Young-Hee;Woo, Jong-Chang;Kim, Han-Soo;Choi, Kyung-Rok;Kim, Chang-Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.1
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    • pp.1-5
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    • 2013
  • In this paper, we investigated the etching characteristics of the TaN thin films and the surface reaction of TaN thin films after etching process. The etching characteristics of the TaN thin films were carried out using inductively coupled plasma (ICP). The etch rate and the selectivity of TaN to $SiO_2$ and TaN to PR were measured by varying the gas mixing ratio, RF power, DC-bias voltage, and process pressure in CF-based plasma. The surface reaction of TaN thin films were determined by x-ray photoelectron spectroscopy (XPS).

An Experimental Study on the NH3-SCR of NOx over a Vanadium-based Catlayst (바나듐 계열 촉매를 통한 NOx의 NH3-SCR에 관한 실험적 연구)

  • Jeong, Hee-Chan;Sim, Sung-Min;Kim, Young-Deuk;Jeong, Soo-Jin;Kim, Woo-Seung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.20-27
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    • 2012
  • The $NH_3$-SCR characteristics of $NO_X$ over a V-based catalyst are experimentally examined over a wide range of operating conditions, i.e., $170-590^{\circ}C$ and $30,000-50,000h^{-1}$, with a simulated diesel exhaust containing $NH_3$, NO, $NO_2$, $O_2$, $H_2O$, and $N_2$. The influences of the space velocity and oxygen concentration on the standard-SCR reaction are analyzed, and it is shown that the low space velocity and high oxygen concentration promote the SCR activity by ammonia. The best $deNO_X$ efficiency is obtained with a $NO_2/NO_X$ ratio of 0.5 because of an enhanced chemical activity induced by the fast-SCR reaction, while at the $NO_2/NO_X$ ratios above 0.5 the $deNO_x$ activity decreases due to the slow-SCR reaction. The oxidation of ammonia begins to take place at about $300^{\circ}C$ and the reaction products, such as $N_2$, NO, $NO_2$, $N_2O$, and $H_2O$, are produced by the undesirable oxidation reactions of ammonia, particularly at high temperatures above $450^{\circ}C$. Also, $NO_2$ decomposes to NO and $O_2$ at temperatures above $240^{\circ}C$. Therefore, $NO_2$ decomposition and ammonia oxidation reactions deteriorate significantly the SCR catalytic activity at high temperatures.

Development of Packaging Materials for MA Packaging(1) (MA포장용 기능성 포장 소재개발에 관한 연구(1))

  • Park, Hyung-Woo;Park, Moo-Hyun;Kim, Hoon;Lee, Jae-Young;Yang, Han-Chul
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.3 no.2
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    • pp.25-31
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    • 1996
  • Various treaments such heating, acid tenting, acid healing, alkaline treating, acid+alkaline renting were attempted to investigate their effects on molar ratio, chemical composition, DTA and specific surface area(SSA) of natural zeolite poder. Molar ratio, Si to AI. of natural zeolite was 4.78, which represented high silica type. Composition of natural zeolite showed that $SiO_2$ was 66.34% $Al_2O_3$ was 13.89%, $Fe_2O_2$ was 1.55% X-ray diffraction showed that main component of natural zeolite was mordenite and clinoptliolite. Differential Thermal Analysis and Thermogravimetry curve of natural zeolite was showed to peak of endothermic peak at $80^{\circ}C$ and it means to the peak of dehydrate reaction, but recristalization was not formed below at $1,000^{\circ}C$. Weight loss during calcination was 16% at $1,000^{\circ}C$. Thermal treatments on SSA of natural zolite powder decreased from $75.2m^2/g\;to\;2.1m^2/g$. In contrast chemical treatments on SSA showed to increase to $300.2m^2/g$(1 N HCl treating), $54.9m^2/g$(1 N NaOH) and $90.9m^2/g$(HCl+NaOH)tudy, it could be proposed to employ acid tret method as packaging materisls for MA packaging.

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Composition of a New Medium for Mycelial Growth of Hericium erinaceus (노루궁뎅이버섯(Hericium erinaceus)의 새로운 균사배양기의 조성)

  • Ko, Han-Gyu;Kim, Dong-Myong;Park, Won-Mok
    • The Korean Journal of Mycology
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    • v.25 no.4 s.83
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    • pp.369-376
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    • 1997
  • These researches were carried out for improvement of medium for mycelial growth of Hericium erinaceus isolate KU-1. It grew well at pH 4 and $25^{\circ}C$. Glucose and sucrose were favorable carbon sources for mycelial growth. As nitrogen sources, ammonium acetate and arginine enhanced mycelial growth. Optimum C/N ratio was 200. Based On the results, the following recipe is suggested for synthetic medium for the mycelial growth: glucose 18.02 g, arginine 2.613 g, ammonium acetate 2.313 g, $CaCl_2\;0.33\;g$, $KH_2PO_4\;8.5\;g$, $MgSO_4{\cdot}7H_2O\;2.0\;g$, $FeSO_4{\cdot}7H_2O\;0.02\;g$, $ZnSO_4{cdot}7H_2O\;0.02\;g$, $MnSO_4{\cdot}7H_2O\;0.02\;g$, water 1 liter. This medium was superior for the mycelial growth to other conventional media such as Yeast malt extract agar (YMA), Park medium, Potato dextrose agar (PDA), Malt extract agar, Czapek-dox agar, Macaya-lizano medium and Yeast extract agar. This new synthetic medium is designated as Ko medium.

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Preparation of NiO/YSZ Ultra-Fine Powder Composites Using Self-Sustaining Combustion Process (Self-Sustaining Combustion Process를 이용한 NiO/YSZ 초미세 복합분말 제조)

  • 김선재;정충환;김경호;김영석;국일현
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.411-417
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    • 1996
  • Ultrafine NiO/YSZ (Yttria Stabilized Zirconia) powders were made by using a glycine nitrate process which is used as anode material for solid oxide fuel cells. The specific surface areas of synthesized NiO/YSZ powders were examined with controlling pH of a precursor solution and the content of glycine. The binding of glycine with metal nitrates occurring in the precursor solution was analyzed by using FTIR. The characteristics of synthesized powders were examined with X-ray diffraction(XRD) Brunauer Emmett Teller with N2 absorption. scanning electron microscopy (SEM). and transmission electron microscopy (TEM). Ultrafine NiO/YSZ powders of 15-18 m2/g were obtained through GNP when the content of glycine was controlled to 1 or 2 times the stoichiometric ratio in the precursor solutions. Strongly acid precursor solution increased the specific surface area of the synthesized powders. This is suggested to be the increased binding of metal nitrates and glycine under a strong acid solution of pH=0.5 that lets glycine consist of mainly the amine group of {{{{ { NH}`_{3 } ^{+ } }}. After sintering and reducing treatment of NiO/YSZ powders synthesized by GNP the Ni/YSZ pellet showed ideal microstructure where very fine Ni particles of 3-5 ${\mu}{\textrm}{m}$ were distributed uniformly and fine pore around Ni metal particles was formed. leading to anincrease of the triple phase boundary among gas Ni and YSZ.

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Optoelectronic Properties of Sol-gel Processed SnO2 Thin Film Transistors (졸-겔 공법으로 제작된 SnO2 박막 트랜지스터의 광전기적 특성)

  • Lee, Changmin;Jang, Jaewon
    • Journal of Sensor Science and Technology
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    • v.29 no.5
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    • pp.328-331
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    • 2020
  • In this study, a highly crystalline SnO2 thin film was formed using a sol-gel process. In addition, a SnO2 thin-film transistor was successfully fabricated. The fabricated SnO2 thin-film transistor exhibited conventional n-type semiconductor properties, with a mobility of 0.1 cm2 V-1 s-1, an on/off current ratio of 1.2 × 105, and a subthreshold swing of 2.69. The formed SnO2 had a larger bandgap (3.95 eV) owing to the bandgap broadening effect. The fabricated photosensor exhibited a responsivity of 1.4 × 10-6 Jones, gain of 1.43 × 107, detectivity of 2.75 × 10-6 cm Hz1/2 W-1, and photosensitivity of 4.67 × 102.

Seasonal Distribution of Water Masses and Spatio-temporal Characteristics of Nutrients in the Coastal Areas of Gangwon Province of the Korean East Sea in 2009 (2009년 강원 연안의 계절별 수괴 분포 및 영양염의 시공간적 특성)

  • Choi, Mi-Yeon;Moon, Deok-Soo;Jung, Dong-Ho;Kim, Hyeon-Ju
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.2
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    • pp.76-88
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    • 2012
  • In order to investigate the distribution of water masses and spatio-temporal variation of nutrients in the coastal areas of Gangwon province of the Korean East Sea, a survey of the physico-chemical parameters (temperature and salinity) and nutrients ($NO_2$-N, $NO_3$-N, $NH_4$-N, $PO_4$-P, and $SiO_2$-Si) was carried out at 5 locations (Goseong, Sokcho, Yangyang, Gangneung, and Donghae) in February, May, August, and November 2009. The water masses included in the study area were divided into 4 groups; 1) Tsushima Surface Water (TSW), 2) Tsushima Middle Water (TMW), 3) North Korean Cold Water (NKCW), and 4) East Sea Proper Water (ESPW). The distribution of water masses was affected by the change of season. In February, surface water was derived from the TMW. The TSW was not observed in May, but only observed in August. In November, as the influence of the TSW weakened, that of the NKCW strengthened. Considering the vertical profiles of nutrients, the concentrations in all the seasons were very low within the surface water, but increased rapidly near the thermocline. Most of nutrient concentrations, except for dissolved silicate, remained constant below the depth of 200 m. However, the dissolved silicate concentration increased with depth, suggesting that silicate has a delayed regenerative pattern. The ESPW had the highest nutrient concentration, followed by the NKCW, TMW, and TSW. In February, May, and November, the N/P ratio in most of the water masses was similar to or larger than the Redfield ratio, indicating that nitrogenous nutrients did not act as a limiting factor for phytoplankton growth. However, in August, the N/P ratio in the TSW was less than the Redfield ratio, and the concentration of $NO_2$-N+$NO_3$-N was 0.86 ${\mu}m$, indicating that nitrogenous nutrients did act as a limiting factor for phytoplankton growth in the study area.

Effects of Heat Treatment Conditions of FeC2O4·2H2O on the Formation of Fe3O4-δ (FeC2O4·2H2O의 열처리 조건이 Fe3O4-δ 형성에 미치는 영향)

  • Oh, Kyoung-Hwan;Park, Won-Shik;Rhee, Sang-In;Suhr, Dong-Soo
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.620-625
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    • 2012
  • A general synthetic method to make $Fe_3O_{4-{\delta}}$ (activated magnetite) is the reduction of $Fe_3O_4$ by $H_2$ atmosphere. However, this process has an explosion risk. Therefore, we studied the process of synthesis of $Fe_3O_{4-{\delta}}$ depending on heat-treatment conditions using $FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. The thermal decomposition characteristics of $FeC_2O_4{\cdot}2H_2O$ and the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ were analyzed with TG/DTA in Ar atmosphere. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method using $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$. The concentration of the solution was 0.1 M and the equivalent ratio was 1.0. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed to $H_2O$ and $FeC_2O$4 from $150^{\circ}C$ to $200^{\circ}C$. $FeC_2O4$ was decomposed to CO, $CO_2$, and $Fe_3O_4$ from $200^{\circ}C$ to $250^{\circ}C$. Single phase $Fe_3O_4$ was formed by the decomposition of ${\beta}-FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. However, $Fe_3C$, Fe and $Fe_4N$ were formed as minor phases when ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed in $N_2$ atmosphere. Then, $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by decomposion of CO. The reduction of $Fe_3O_4$ to $Fe_3O_{4-{\delta}}$ progressed from $320^{\circ}C$ to $400^{\circ}C$; the reaction was exothermic. The degree of exothermal reaction was varied with heat treatment temperature, heating rate, Ar flow rate, and holding time. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was greatly influenced by the heat treatment temperature and the heating rate. However, Ar flow rate and holding time had a minor effect on ${\delta}$-value.

The Effect of Draw Solution Concentration on Forward Osmosis Desalination Performance Using Blended Fertilizer as Draw Solution (유도용액으로 혼합비료를 사용한 정삼투식 해수담수화에서 담수화 성능에 대한 유도용액 농도의 영향)

  • Jeong, Namjo;Kim, Seung-Geon;Kim, Dong Kook;Lee, Ho-Won
    • Membrane Journal
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    • v.23 no.5
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    • pp.343-351
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    • 2013
  • This study is to investigate the effects of the draw solution concentration on forward osmosis desalination performance using blended fertilizer as draw solution. As the concentration of blended fertilizer solution (draw solution) increased, the water permeate flux increased nearly linearly, but PR (performance ratio) was reduced. Using sea water and deionized water as the feed solution, respectively, at the blended fertilizer solution of 600 g/L $H_2O$, the PR obtained were 5.39 and 6.50, respectively. And as the concentration of blended fertilizer solution increased, the reverse solute flux for nitrogen (N), phosphorus (P), and potassium (K) increased nearly linearly, but specific reverse solute flux for them was reduced. The reverse solute flux and specific reverse solute flux became higher in the order of N > K > P.