• Title/Summary/Keyword: O:N ratio

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Fabrication and Characteristics of ZnO TFTs for Flexible Display using Low Temp Process (Flexible Display용 Low Temp Process를 이용한 ZnO TFT의 제작 및 특성 평가)

  • Kim, Young-Su;Kang, Min-Ho;Nam, Dong-Ho;Choi, Kang-Il;Lee, Hi-Deok;Lee, Ga-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.10
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    • pp.821-825
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    • 2009
  • Recently, transparent ZnO-based TFTs have attracted much attention for flexible displays because they can be fabricated on plastic substrates at low temperature. We report the fabrication and characteristics of ZnO TFTs having different channel thicknesses deposited at low temperature. The ZnO films were deposited as active channel layer on $Si_3N_4/Ti/SiO_2/p-Si$ substrates by RF magnetron sputtering at $100^{\circ}C$ without additional annealing. Also, the ZnO thin films deposited at oxygen partial pressures of 40%. ZnO TFTs using a bottom-gate configuration were investigated. The $Si_3N_4$ film was deposited as gate insulator by PE-CVD at $150^{\circ}C$. All Processes were processed below $150^{\circ}C$ which is optimal temperature for flexible display and were used dry etching method. The fabricated devices have different threshold slop, field effect mobility and subthreshold slop according to channel thickness. This characteristics are related with ZnO crystal properties analyzed with XRD and SPM. Electrical characteristics of 60 nm ZnO TFT (W/L = $20\;{\mu}m/20\;{\mu}m$) exhibited a field-effect mobility of $0.26\;cm^2/Vs$, a threshold voltage of 8.3 V, a subthreshold slop of 2.2 V/decade, and a $I_{ON/OFF}$ ratio of $7.5\times10^2$.

Y2O3-stabilized ZrO2, Ni, and graphene-added Mg by reactive mechanical grinding processing for hydrogen storage and comparison with Ni and Fe2O3 or MnO-added Mg

  • Song, Myoung Youp;Choi, Eunho;Kwak, Young Jun
    • Journal of Ceramic Processing Research
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    • v.20 no.6
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    • pp.609-616
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    • 2019
  • The optimum powder to ball ratio was examined, which is one of the important conditions in reactive mechanical grinding processing. Yttria (Y2O3)-stabilized zirconia (ZrO2) (YSZ), Ni, and graphene were chosen as additives to enhance the hydriding and dehydriding rates of Mg. Samples with a composition of 92.5 wt% Mg + 2.5 wt% YSZ + 2.5 wt% Ni + 2.5 wt% graphene (designated as Mg-2.5YSZ-2.5Ni-2.5graphene) were prepared by grinding in hydrogen atmosphere. Mg-2.5YSZ-2.5Ni-2.5graphene had a high effective hydrogen-storage capacity of almost 7 wt% (6.85 wt%) at 623 K in 12 bar H2 at the second cycle (n = 2). Mg-2.5YSZ-2.5Ni-2.5graphene contained Mg2Ni phase after hydriding-dehydriding cycling. Mg-2.5YSZ-2.5Ni-2.5graphene had a larger quantity of hydrogen absorbed for 60 min, Ha (60 min), than Mg-2.5Ni-2.5graphene and Mg-2.5graphene. The addition of YSZ also increased the initial dehydriding rate and the quantity of hydrogen released for 60 min, Hd (60 min), compared with those of Mg-2.5Ni-2.5graphene. Y2O3-stabilized ZrO2, Ni, and graphene-added Mg had a higher initial hydriding rate and a larger Ha (60 min) than Fe2O3, MnO, or Ni and Fe2O3-added Mg at n = 1.

The Research about the Correlation Between the Spontaneous Polarization of LuFe2O4 and Behavior of Iron by Mössbauer (뫼스바우어 분광법을 이용한 LuFe2O4의 자발분극과 철 이온의 거동과의 상관관계에 대한 연구)

  • Bang, Bong-Kyu;Kim, Chul-Sung;Kim, Sung-Baek;Cheong, S.W.
    • Journal of the Korean Magnetics Society
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    • v.17 no.1
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    • pp.10-13
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    • 2007
  • Single crystalline, $LuFe_2O_4$, was grown by the floating zone method. The crystal structure was a two-dimensional layered-type rhombohedral($R\={3}mh$) structure, with an $a_0=3.440(2)\;{\AA}\;and\;a\;c_0=25.263(2)\;{\AA}$. The magnetic $N\'{e}el$ temperature($T_N$) was determined to be 250 K. The $M\"{o}ssbauer$ spectrum at 12 K was fitted with four sextet sets which was resulted from the crystal structure. The spectrm at room temperature consisted of three singlets and a doublet with the electric quadrupole splitting. The isomer shift($\delta$) value of the singlet was $0.20{\pm}0.01mm/s$ relative to the Fe metal indicating the $Fe^{3+}$ valence state, and the value of the doublet was $0.70{\pm}0.01mm/s$ indicating $Fe^{2+}$. The $M\"{o}ssbauer$ absorption area ratio between $Fe^{3+}$ and $Fe^{2+}$ at room temperature was 1:1. The doublet phase of spectra gradually disappears by up to 360 K. At 360 K, the spectrum shows the singlet phase. We suggested that the spontaneous polarization effect of $LuFe_2O_4$ was caused by the change of iron behavior.

Removing High Concentration Nitrogen by Electrolysis (전기분해에 의한 고농도 질소 제거의 특성)

  • Gil, Dae-Soo;Lee, Byung-Hun;Choi, Hae-Kyoung;Kwon, Dong-Min
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.265-277
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    • 2000
  • Laboratory experiments were conducted to investigate characteristics for removing ammonia-nitrogens by electrolysis methods. A stainless steel plate is used as the cathode and either $IrO_2{\backslash}Ti$ plate serves as the anode. Experiments were conducted to examine the effects of the operating conditions, such as the current density, retention time, electrode gap, $Cl^-/NH_4{^+}-N$ on the $NH_4{^+}-N$ removal efficiency. Possible optimum range for these operating variables are experimentally determined. The $NH_4{^+}-N$ removal efficiencies between plate type anode and net type anode were about same effect, but electrolytic power using net type anode is low than plate type anode. The $Cl^-/NH_4{^+}-N$ ratio was about $20.0kgCl^-/kgNH_4{^+}-N$ when $NH_4{^+}-N$ removal obtained 73 %, $Cl^-/NH_4{^+}-N$ ratio needs $27.6kgCl^-/kgNH_4{^+}-N$ so as to $NH_4{^+}-N$ completely remove. The removal efficiency of $NH_4{^+}-N$ increase with current density, retention time and $Cl^-/NH_4{^+}-N$ ratio, but decreased with increasing electrode gap. The relationship of operating conditions and $NH_4{^+}-N$ removal efficiencies are $$NH_4{^+}-N_{re}(%)=14.5364(Current\;density)^{0.7093}{\times}(HRT)^{1.0060}{\times}(Gap)^{-0.9926}{\times}(Cl^-/NH_4{^+}-N)^{1.0024}$$ With adding COD or/and alkalinity, relationships are $$NH_4{^+}-N_{re}(%)=9.8408(Current\;density)^{0.6232}{\times}(HRT)^{1.0534}$$ There existed a competition between the removals for $NH_4{^+}-N$ and $COD_{Cr}$ during electrolysis, the removal of $NH_4{^+}-N$ was shown to be dominant. $NH_4{^+}-N$ removal was high as addition of glucose and alkalinity.

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Performance Analysis of Diversity Received DS-CDMA/MDPSK Signals in m-distribution and Rician Fading Environments (m-분포 페이딩과 라이시안 페이딩 환경 하에서의 다이버시티 수신된 DS-CDMA / MDPSK 신호의 성능 분석)

  • 이정도;강희조
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.9 no.2
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    • pp.191-198
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    • 1998
  • The error are equation of DC-CDMA/MDPSK signal has been derived in m-distribution and Rician fading channels. Predeteception multipath MRC(Maximal Ratio Combining) diversity technique is employed for improving the bit error rate performance. The suitability of modeling a Rician fading environment by properly chosen m-distribution model is examined. Using the derived equation the error performance has been evaluated and shown in figures as a function of PN code sequence length(N), user number(U), multipath number(P), fading index(m), Rician factor(K), number of diversity branches(L) and ($E_b/N_o$). The results show that the error performance in Rician fading agrees well with that in m-distribution fading as fading becomes weak and as user number(U) increases and as multipath number(P) increases and diversity number(L) increases.

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Performance Analysis of Hybrid DS/FH-CDMA over Nakagami Fading Channels with Near-Far Problem (원근문제와 나카가미 페이딩을 고려한 하이브리드 DS/FH-CDMA 방식의 성능 분석)

  • 임태길;강희조
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.10 no.7
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    • pp.1118-1130
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    • 1999
  • In this paper, error performance of DS/FH CDMA system has been analyzed in a radio channel which is characterized by near-far problem and multi-path fading. The DS/FH CDMA system adopts Maximum Ratio Combining(MRC) diversity and BCH(Bose-Chau dhuri-Hocquenghem) coding techniques to enhance system performance. Using the derived error probability equation, the error performance of DS/FH CDMA system has been evaluated and shown in figures to discuss as a function of PN code length(N), hopping rate(q), number of diversity branch(M), coding rate($\gamma$) and bit energy per noise power ratio ${E_b/N_o}$. The results show that DS/FH system is more effective to restrain the affection of near-far problem and multi-path fading than DS system. And there is a substantial enhancement in performance by employing an MRC diversity or BCH coding techniques. Consequently, we expected that proposed system structure is reliable to the voice communication system in near-far problem and multi-path fading channel.

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Design of the Satellite Beacon Receiver Using Array Based Digital Filter (다중배열 디지털필터를 이용한 위성비콘 수신기 설계)

  • Lee, Kyung-Soon;Koo, Kyung-Heon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.27 no.10
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    • pp.909-916
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    • 2016
  • The beacon receiver is an equipment which detects and measures the signal strength of transmitting satellite beacon signal. Beacon signals transmitted by satellites are low power continuous wave(CW) signals without any modulation intended for antenna steering to satellite direction and power control purposes on the earth. The beacon signal detection method using a very narrow band analog filter and RSSI(Received Signal Strength Intensity) has been typically used. However, it requires the implementation to track the frequency at the beacon receiver, thus a beacon frequency variation of the satellite due to temperature changes and long-term operation. Therefore, in this paper, the beacon signal detection receiver is designed by using a very narrow band digital filter array for a faster acquisition and SNR(Signal to Noise Ratio) method detection. For this purpose, by calculating the satellite link budget with the rain attenuation between satellite and ground station, and then extracting the received $C/N_o$ of the beacon signal, this work derives the bandwidth and the array number of the configured digital filter that gives the required C/N.

Analysis on the Field Effect Mobility Variation of Tin Oxide Thin Films with Oxygen Partial Pressure (산소 분압에 따른 산화주석 박막의 전계효과 이동도 변화 분석)

  • Ma, Tae Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.6
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    • pp.350-355
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    • 2014
  • Bottom-gate tin oxide ($SnO_2$) thin film transistors (TFTs) were fabricated on $N^+$ Si wafers used as gate electrodes. 60-nm-thick $SnO_2$ thin films acting as active layers were sputtered on $SiO_2/Al_2O_3$ films. The $SiO_2/Al_2O_3$ films deposited on the Si wafers were employed for gate dielectrics. In order to increase the resistivity of the $SnO_2$ thin films, oxygen mixed with argon was introduced into the chamber during the sputtering. The mobility of $SnO_2$ TFTs was measured as a function of the flow ratio of oxygen to argon ($O_2/Ar$). The mobility variation with $O_2/Ar$ was analyzed through studies on crystallinity, oxygen binding state, optical properties. X-ray diffraction (XRD) and XPS (X-ray photoelectron spectroscopy) were carried out to observe the crystallinity and oxygen binding state of $SnO_2$ films. The mobility decreased with increasing $O_2/Ar$. It was found that the decrease of the mobility is mainly due to the decrease in the polarizability of $SnO_2$ films.

The Relationship between Hydrogenase and Nitrogenase for Hydrogen Evolution in Rhodopseudomonas sp. KCTC 1437 (Rhodopseudomonas sp. KCTC 1437의 수소생성에 있어서의 Hydrogenase와 Nitrogenase의 관계)

  • Seol, Won-Gi;Kho, Yung-Hee
    • Microbiology and Biotechnology Letters
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    • v.14 no.5
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    • pp.385-389
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    • 1986
  • Both hydrogenase and nitrogenase were found to be involved in hydrogen evolution independently in Rhodopseudomonas sp. KCTC 1437. The hydrogen formation in this bacterium was independent on light illumination and presence of N $H_4^{+}$ After establishment of conditions to measure the amount of hydrogen evolved by each of the enzymes in vivo, the several factors affecting on the hydrogen evolution, e.g. presence of gases ( $C_2$ $H_2$, $H_2$, $O_2$ or $N_2$), C/N ratio, were investigated, Hydrogenase was less inhibited than nitrogenase under $O_2$ and was active independent on the presence of $N_2$ or $C_2$ $H_2$ which were the strong inhibitor of nitrogenase. Besides, the hydrogenase activity was increased after incubation with $H_2$. And it was verified that this bacterium consume hydrogen and photoreduce $CO_2$ by hydrogenase. From above results, it is concluded that hydrogenase in Rhodopseudomonas sp. KCTC 1437 can produce hydrogen under more favorable condition that nitrogenase.e.

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Recovery of Ammonium Nitrogen and Phosphate from the Piggery Wastewater as Struvite and Its Assessment for the Reduction of Water Pollution Through the Field Test

  • Daeik Kim;Sun Jin Hwang;Su Ho Bae;Keon Sang Ryoo
    • Korean Journal of Environmental Agriculture
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    • v.42 no.2
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    • pp.83-92
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    • 2023
  • Excess N and P from the livestock manure applied to farmlands, have entered the water systems and poses a serious threat to the natural environment. Consequently, there has been recent awareness towards the management of livestock manure and its related fields. In this study, piggery wastewater was collected from a piggery in Pohang city, Korea. At 800℃, thermal decomposition of a natural stone, magnesite (MgCO3), yielded powered MgO with particle sizes ranging between 10 to 100 ㎛. Furthermore, NH4+-N and PO43--P were recovered as struvite precipitates from the piggery wastewater, by adjusting the pH with MgO and H3PO4. At pH 10, the recovery efficiencies of NH4+-N and PO43--P were found to be 86.1% and 94.1%, respectively. Using an X-ray Diffractometer (XRD), the struvite in the precipitate was confirmed to be consistent with standard pure struvite. Further, the purity of the struvite precipitate was analyzed using an energy dispersive X-ray (EDX) and thermal gravimetry-differential thermal analysis (TG-DTA), and found to be between 79.2% and 93.0%. Additionally, struvite-containing piggery wastewater and sawdust were mixed in a weight ratio of 2.5:1 and processed into a mature compost. The newly manufactured compost passed all quality standards required for first-class graded livestock composts. Moreover, this compost was sprayed directly onto the soil at the test site, and various parameters of the soil's effluent, such as total organic carbon (TOC), total nitrogen (T-N), total phosphorus (T-P), and dissolved oxygen (DO), were analyzed and measured. Based on these results, it is determined that the newly manufactured compost can more significantly reduce water pollution than commercial compost.