• Title/Summary/Keyword: O/M ratio

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Highly transparent and resistive nanocrystalline ZnO-SnO2 films prepared by rf magnetron sputtering

  • Cha, Chun-Nam;Choi, Mu-Hee;Ma, Tae-Young
    • Journal of Electrical Engineering and Technology
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    • v.7 no.4
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    • pp.596-600
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    • 2012
  • ZnO-$SnO_2$ films were deposited by rf magnetron sputtering using a ZnO-$SnO_2$ (2:1 molar ratio) target. The target was made from a mixture of ZnO and $SnO_2$ powders calcined at $800^{\circ}C$. The working pressure was 1 mTorr, and the rf power was 120 W. The ratio of oxygen to argon ($O_2$:Ar) was varied from 0% to 10%, and the substrate temperature was varied from $27^{\circ}C$ to $300^{\circ}C$. The crystallographic properties and the surface morphologies of the films were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and atomic force spectroscopy (AFM). The ZnO-$SnO_2$ films deposited in $O_2$:Ar = 10% exhibited resistivity higher than $10^6{\Omega}cm$ and transmittance of more than 80% in the visible range.

Fabrication of Thin $YBa_{2}Cu_{3}O_{7-\delta}$ Films on $CeO_2$Buffered Sapphire Substrate Using Combined Sputter and Pulsed Laser Deposition (스퍼터링과 펄스 레이저를 이용하여 $CeO_2$완충층 위에 층착된 $YBa_{2}Cu_{3}O_{7-\delta}$박막의 제작)

  • 곽민환;강광용;김상현
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.901-904
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    • 2001
  • For the c-axis oriented epitaxial YBa$_2$Cu$_3$O$_{7-{\delta}}$ thin film on r-cut sapphire substrate it is necessary to deposit buffer layers. The CeO$_2$buffer layer was deposited on sapphire substrate using RF magnetron sputtering system. We investigated XRD pattern of CeO$_2$thin films at various sputtering conditions such as sputtering gas ratio, sputtering power, target to substrate distance, sputtering pressure and substrate temperature. The optimum condition was 15 mTorr with deposition pressure, 1:1.2 with $O_2$and Ar ratio and 9cm with target to substrate distance. The CeO$_2$(200) peak was notable for a deposition temperature above 75$0^{\circ}C$. The YBa$_2$Cu$_3$O$_{7-{\delta}}$ was deposited on CeO$_2$buffered r-cut sapphire substrate using pulsed laser ablation. The YBa$_2$Cu$_3$O$_{7-{\delta}}$CeO$_2$(200)/A1$_2$O$_3$thin film was exhibited a critical temperature of 89K.xhibited a critical temperature of 89K.

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A Study on C-axis Preferred Orientation of ZnO Thin Film at Ar/$O_2$gas ratios (Ar/$O_2$에 따른 ZnO 박막의 C-축 배향성에 관한 연구)

  • Lee, Dong-Yoon;Park, Yong-Wook;Nam, Sahn;Lee, Jeon-Kook;Kim, Hyun-Jai;Yoon, Seok-Jin;Whang, Keum-Chan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.7
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    • pp.617-624
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    • 2000
  • Zinc Oxide(ZnO) thin films on Si(100) substrate were deposited by RF magnetron reactive sputtering. The charcteristics of ZnO thin films on argon/oxygen(Ar/O$_2$)gas ratios RF power and substrate temperature were investigated by XRD, SEM, and AFM analyses. C-axis preferred orientation resistivity and surface roughness highly depended on Ar/O$_2$gas ratios. The resistivity of ZnO thin films rapidly increased with increasing oxygen ratio and the resistivity value of 9$\times$10$^{7}$ $\Omega$cm was obtained at a working pressure of 10 mTorr with Ar/O$_2$=50/50. The surface roughness was also improved with increasing oxygen ratio and the ZnO films deposited with Ar/O$_2$=50/50 showed the excellent roughness value of 28.7$\AA$.

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Thermoluminescent Properties by the Cooling Temperature and Grain Size in the LiYSiO4 : La Phosphors (LiYSiO4: La 열형광체의 온도에 따른 열발광 특성)

  • Kim, Young-Kook
    • Korean Journal of Materials Research
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    • v.19 no.9
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    • pp.494-498
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    • 2009
  • The thermoluminescent phosphors of LiYSi$O_4$ containing rare earth metal(La) dopants of 1 wt.%5 wt.% were prepared, and their TL characteristics have been investigated as a function of parameters such as the doping level and the heating rate. The grain size and cooling temperature of the highly sensitive LiYSi$O_4$: La phosphors have been investigated. The glow curve of LiYSi$O_4$: La has two peaks ($P_1,\;P_2$), and the peak height ratio of the two peaks is called $P_2/P_1$; here, the main peak is $P_2$. Experimental results indicate that the peak height ratios of the glow curve for LiYSi$O_4$: La are clearly correlated with the grain size and cooling temperature. The maximum $P_2/P_1$ ratio 3.25, the maximum sensitivity was observed for a grain size between 100-150 ${\mu}m$. The intensity of the TL peak of the phosphors was linearly proportion to the dose of X-rays.

Effects of Calcination Process and $ZrO_2$ Addition on the Electrical Properties of $BaTiO_3$ Ceramics (하소공정과 $ZrO_2$ 첨가량이 $BaTiO_3$의 전기적 특성에 미치는 영향)

  • 차진이;박재관;오태성;김윤호
    • Journal of the Korean Ceramic Society
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    • v.28 no.11
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    • pp.935-941
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    • 1991
  • Effects of calcination process and ZrO2 addition on the electrical properties of [(Ba0.82Sr0.08Ca0.1)O]m(Ti1-$\chi$Zr$\chi$)O2 ceramics have been investigated. With the variation of A/B-site ratio m of the dielectric formulations, sintering behavior and the resistivity after sintering in a reducing atmosphere have been affected by the calcination process. When the dielectric formulations of m=1.01 were sintered in a reducing atmosphere, the room-temperature resitivity of 109 {{{{ OMEGA }}.cm was obtained for samples processed with two-step calcination, which was much lower than 1012 {{{{ OMEGA }}.cm of samples calcined once. It was confirmed that high resistivity of Ca-doped BaTiO3 ceramics, after sintering in a reducing atmosphere, is maintained by acceptor-like behavior of CaTi" which is formed by Ca substitution to Ti-site. It was also found out that the critical amount of B-site Ca substitution for reduction inhibition of BaTiO3 is around 0.005 mol. With the increasing amount of ZrO2 addition to dielectric formulations, Curie peak was depressed and Curie temperature was lowered due to the enhanced diffuse phase transition.tion.

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Nitrogen Removal in the Multi-stage Bed Attached Growth Process of $A^2/O$ System with Interanal Recycle Ratio (다단층 부착성장 공법($A^2/O$향)에서 순환비에 따른 질소제거)

  • 최규철;윤용수;정일현
    • Journal of environmental and Sanitary engineering
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    • v.12 no.3
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    • pp.95-102
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    • 1997
  • The process which can stabilize water quality of treatment and improve nitrogen removal rate under the condition of high organic loading was developed by charging fibrous HBC media to single sludge nitrification-denitrification process. This process was operated easier, minimized the treatment cost, and shortened the retention time. To improve T-N removal rate, a part of nitrifing liquid at aerobic zone was recycled to anoxic zone by approximate internal recycle ratio. The experimental results are as follows ; T-N removal efficiency in the organic volumetric loading 0.14-0.19 kg/COD/m$^{3}$·d was obtained asmaxium of 85% at internal recycle ratio 2.5 and in more ratio than this it was decreased. Organic removal efficiency was about 91% under the overall experimental conditions and not influenced by recycle ratio.

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Resistivity Analysis to Deposition Parameters of Piezoelectric Thin Film (압전 박막의 증착변수에 따른 비저항 분석)

  • Lee, Dong-Yoon
    • Proceedings of the Korea Contents Association Conference
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    • 2007.11a
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    • pp.804-806
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    • 2007
  • C-axis oriented zinc oxide thin films were deposited on Si(100) substrate by rf magnetron sputtering. The effects of deposition parameters on the crystallinity and electrical properties of ZnO films were investigated. As-deposited ZnO films showed the strong c-axis growth andexcellent crystallinity under the deposition conditions as follows ; substrate temperaturec : $200^{\circ}C$, rf power : 150W, gas ratio : $O_2/Ar=50/50$, chamber pressure : 10mTorr. The resistivity of ZnO films was significantly affected by deposition parameters. With increasing percentage of oxygen, and decreasing substrate temperature, the resistivity of ZnO films increased.

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Deposition of ZnO Thin Films by RF Magnetron Sputtering and Charcaterization of the ZnO thin film SAW filter (RF 마그네트론 스터터링에 의한 ZnO박막증착 및 SAW 필터 특성 분석)

  • Lee, Yong-Ui;Yang, Hyeong-Guk;Kim, Yeong-Jin;Han, Jeong-In;Kim, Hyeong-Jun
    • Korean Journal of Materials Research
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    • v.4 no.7
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    • pp.783-791
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    • 1994
  • Piezoelectric ZnO thin films were deposited on 7059 glass substrate by rf magnetron sputtering. The effects of deposition parameter, such as rf power, gas pressure and $O_{2}$/Ar gas ratio, on the crystallinity and electrical properties of the deposited ZnO thin films were studied. It was found that the deposition rate was higher than the previously reported values. ZnO films were suitable for SAW filter since a standard deviation of XRD (002) peak rocking curve was less than $6^{\circ}$. ZnO thin films, which were deposited at $O_{2}$/Ar ratio larger than 25%, showed high resistance. SAW filter was fabricated using ZnO film, of which thickness was 0.25 of the wavelength of the propatating surface acoustic wave. The measured frequency response was consistent with the calculated one. The SAW filter had center frequency 39.08 MHz, phase velocity 2501 m/sec and insertion loss 29 dB.

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Study on the Thin-film Transistors Based on TiO2 Active-channel Using Atomic Layer Deposition Technique (원자층 증착 기술을 이용한 TiO2 활성층 기반 TFT 연구)

  • Kim, Sung-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.7
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    • pp.415-418
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    • 2015
  • In this paper, $TiO_2$ based thin-film transistors (TFTs) were fabricated using by an atomic layer deposition with high aspect ratio and excellent step coverage. $TiO_2$ semiconducting layer was deposited showing a rutile phase through the rapid thermal annealing process, and exhibited TFT characteristics with a $200{\mu}m$ channel length of low-leakage currents (none of current flow during off-state), stable threshold voltages (-10 V ~ 0 V), and a much higher on/off current ratio (<$10^5$), respectively.

A study on the etching properties of (Ba,Sr)$TiO_3$ film by high density plasma (고밀도 플라즈마에 의한 (Ba,Sr)$TiO_3$막의 식각특성 연구)

  • Kim, Seung-Bum;Kim, Chang-Il;Chang, Eui-Goo
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.798-800
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    • 1998
  • (Ba,Sr)$TiO_3$ thin films were etched with $Cl_2$/Ar gas mixing ratio in an inductively coupled plasma (ICP) by varying the etching parameter such as f power, do bias voltage, and chamber pressure. The etch rate was $560{\AA}/min$ under Cl_2/(Cl_2+Ar)$ gas mixing ratio of 0.2, rf power of 600 W, do bias voltage of 250 V, and chamber pressure of 5 mTorr, At this time, the selectivity of BST to Pt, $SiO_2$ was respectively 0.52, 0.43. The surface reaction of the etched (Ba,Sr)$TiO_3$ thin films was investigated with X-ray photoelectron spectroscopy (XPS).

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