• Title/Summary/Keyword: O$_2$ concentration

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Sterilization Test of Microorganisms of Slow-released ClO2 Gas Gel-Pack (서방출형 이산화염소 가스 젤팩의 미생물 살균 시험)

  • Lee, Kyung-Haeng;Kim, Hong-Gil
    • The Korean Journal of Food And Nutrition
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    • v.31 no.2
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    • pp.308-312
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    • 2018
  • Even though chlorine dioxide ($ClO_2$) is utilized in a pre-treatment due to its effective sterilizing activity for microorganisms and its safety for food, it has a limitation in maintaining freshness of the food product. In this study, a low-concentration $ClO_2$ gas was produced in a packaging form of air-permeable gel pack so that it could be released continuously over several days. The amount of $ClO_2$ gas emission and microbial inactivation effect against foodborne pathogens were measured during the release of $ClO_2$ gas. As a result of measuring the change of color in order to confirm whether the chlorine dioxide gas was eluted in the form of a sustained release, the yellowness was significantly higher at higher gel pack concentration and higher value during storage periods. The slow-released $ClO_2$ gel-pack showed clear inactivation effect against Escherichia coli and Staphylococcus aureus with 99.9% inactivation efficiency. As a result of measuring the sterilization effect of Listeria monocytogenes by the concentration of chlorine dioxide gas, the sterilization effect was increased as the concentration was increased. Therefore, the slow-released $ClO_2$ gel-pack is feasible to apply for industry usages.

Degradation of Phenol by "TiO2 Ceramic Membrane+UV+H2O2" AOP ("TiO2 촉매막+UV+H2O2" 고도산화법(AOP)을 이용한 페놀 분해)

  • Choung, Youn Kyoo;Kim, Jin Wook
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.3
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    • pp.645-654
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    • 1994
  • Photocatalytic oxidation conditions of reactant recirculation flow rate 275 mL/min, aeration rate 2 LPM and $UV+TiO_2+H_2O_2$(500 mg/L) proved to be appropriate for water including organic materials treatment. With increasing turbidity and suspended solids concentration, at turbidity 10 NTU-suspended solids concentration 29 mg/L the phenol degradation efficiency increased, which in turn decreased at turbidity 50 NTU-suspended solids concentration 170 mg/L, however no significant differences were observed, demonstrating similar results with those obtained at zero turbidity and suspended solids concentration. The degradation efficiency of phenol decreased with increasing influent phenol concentrations. The $UV+TiO_2+H_2O_2$ photocatalytic advanced oxidation process conducted is considered to be possibly applied to the drinking water treatment, and the post-treatment process of biological wastewater treatment.

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Effect of Soil Salinity on Growth, Yield and Nutrients Uptake of Whole Crop Barley in Newly Reclaimed Land (신간척지에서 토양 염농도가 청보리 생육, 수량 및 양분 흡수에 미치는 영향)

  • Lee, Sang-Bok;Cho, Kwang-Min;Shin, Pyung;Yang, Chang-Hyu;Back, Nam-Hyun;Lee, Kyeong-Bo;Baek, Seung-Hwa;Chung, Doug-Young
    • Korean Journal of Environmental Agriculture
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    • v.32 no.4
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    • pp.332-337
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    • 2013
  • BACKGROUND: Newly reclaimed land has poor soil environment for crop growth since it is high in salt concentration but low in organic content compared with ordinary soil. It is known that whole-crop-barley can grow better in the soil of relatively high salt concentration than other crops but, the growth is poor at the concentration if higher than certain amount and it is a difficulty to secure productivity. Hence, the level of soil salt concentration suitable for the production of bulky feed in newly reclaimed land has been investigated. METHODS AND RESULTS: At Saemanguem reclaimed land, the land for the soil salt concentration electrical conductivity (EC) 0.8, 3.1, 6.5, 11.0 dS/m was selected; and chemical fertilizer $N-P_2O_5-K_2O$ (150-100-100kg/ha) was tested; and forage barley 220kg/ha were sown. The soil salt concentration during the cultivation period decreased in the order of harvest season>earing season>sowing season>wintering season, and the salt concentration in harvest season is 1.4-4.2 times higher than that of the sowing season. The higher the salt concentration, the poorer the over ground growth due to poor rooting; especially at EC 11.0 ds/m there was emergence but, it blighted after wintering. The Yield from the soil salt concentration 3.1dS/m and 6.5 dS/m was 68% and 35% from that of the soil salt concentration 0.8 dS/m (8.8 MT/ha) respectively. The proline content in early life stage was more than that of the harvest season, and it increased with salt concentration. The higher salt concentration, the more $Na_2O$ and MgO content in harvest season; but the higher the salt concentration, the less the content of N, $P_2O_5$, $K_2O$ and CaO. CONCLUSION(S): When the soil salt concentration becomes higher than 3.1 dS/m, the yield becomes poor because there is serious growth inhibition of forage barley both in root part and above aerial part that results in unbalanced absorption of nutrients. Therefore, it is recommended that the salt concentration should be lowered below 3.1 dS/m by underground drainage facilities or irrigating water for the stable production of whole-crop-barley.

A Study of Nitrous Oxide Thermal Decomposition and Reaction Rate in High Temperature Inert Gas (고온 불활성 기체 분위기에서 아산화질소 열분해 및 반응속도에 관한 연구)

  • Lee, Han Min;Yun, Jae Geun;Hong, Jung Goo
    • Journal of ILASS-Korea
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    • v.25 no.3
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    • pp.132-138
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    • 2020
  • N2O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N2O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N2O emission from industrial machines. In this study, the thermal decomposition experiment of N2O gas mixture is conducted by using cylindrical reactor to figure out N2O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N2O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N2O gas decreases with N2O emitted concentration. At 800℃ and 900℃, N2O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N2O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.

The Effect of Cerium Reduction on Light Emission in Cerium-containing 20Y2O3-25Al2O3-55SiO2 Glass

  • Maeng, Jee-Hun;Choi, Sung-Churl
    • Journal of the Optical Society of Korea
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    • v.16 no.4
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    • pp.414-417
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    • 2012
  • The effect of cerium concentration and the addition of $Sb_2O_3$ on the light emission of cerium-contained glass were investigated. The glass matrix composition was $20Y_2O_3-25Al_2O_3-55SiO_2$, the $CeO_2$ concentration ranged from 0.05 to 0.5 mol%, and $Sb_2O_3$ was added at concentrations of 0.02 to 0.1 mol%. The $Ce^{3+}$ and $Ce^{4+}$ absorption bands were observed at approximately 330 nm and 240 nm, respectively. A broad emission band at 400 nm, due to the 4f-5d transition of the $Ce^{3+}$ ion, was observed under illumination by a UV light at 330 nm. The photoluminescence intensity of $Ce^{3+}$ had a maximum value at a $CeO_2$ concentration of 0.1 mol%. Adding $Sb_2O_3$ decreased the $Ce^{4+}$ absorption intensity and enhanced the light emission intensity of $Ce^{3+}$ by about 45%.

Airborne Measurements of Ozone and Its Precursors over Yeosu-Gwangyang Industrial Areas in the Southern Coast of Korea

  • Kim, So-Young;Seo, Seok-Jun;Park, Hyun-Ju;Son, Jung-Seok;Park, Ji-Hoon;Kim, Jong-Choon
    • Asian Journal of Atmospheric Environment
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    • v.7 no.3
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    • pp.139-151
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    • 2013
  • The purpose of this study is to understand distributional characteristics in the atmospheric concentrations of $O_3$ and its precursors based on data taken at the southern Korean coast. The average $O_3$ concentration in the high altitude was found to range from 32.3 to 90.8 ppb with a maximum concentration of 132 ppb. The ambient $O_3$ concentration was high at altitudes of 1000 m and 500 m above the southern sea near Gwangyang Bay and an industrial area containing emission sources. The daily mean concentrations of $NO_y$ and CO were 6.7-24.2 ppb and 0.152-0.487 ppm, respectively. During the aerial measurement period, the highest mean concentration of $O_3$ was observed on June 1. The aerial measurement results showed that the maximum ozone concentration was observed to be 132 ppb in the high altitude the southernmost part of Yeosu. The measurement of vertical wind fields in the air indicated that $O_3$ formed in the southernmost part of Yeosu was transported by strong southwesterly winds to the northeast of Gwangyang Bay. This led to a ground $O_3$ concentration of over 100 ppb in Jinju, the northeastern part of Gwangyang Bay. On August 9, when the maximum $O_3$ concentration was 50 ppb, the measurement results showed that $O_3$ concentrations were relatively low compared to other days. In particular, low $NO_2$ and TVOC concentrations were observed, both of which serve to form $O_3$ in photochemical reactions.

Bench-scale Experiment on Catalytic Decomposition of 1,2 Dichlorobenzene by Vanadia-Titania Catalyst

  • Jeong, Ju-Young;Chin, Sung-Min;Jurng, Jong-Soo
    • Journal of Environmental Science International
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    • v.18 no.7
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    • pp.709-714
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    • 2009
  • Catalytic activities of $V_2O_5/TiO_2$ catalyst were investigated under reaction conditions such as reaction temperature, catalyst size, inlet concentration and space velocity. A 1,2-dichlorobenzene(1,2-DCB) concentrations were measured in front and after of the heated $V_2O_5/TiO_2$ catalyst bed, and conversion efficiency of 1,2-DCB was determined from it's concentration difference. The conversion of 1,2-DCB using a pellet type catalyst in the bench-scale reactor was lower than that with the powder type used in the micro flow-scale reactor. However, when the pellet size was halved, the conversion was similar to that with the powder type catalyst. The highest conversion was shown with an inlet concentration of 100 ppmv, but when the concentration was higher or lower than 100 ppmv, the conversion was found to decrease. Complete conversion was obtained when the GHSV was maintained at below 10,000 $h^{-1}$, even at the relatively low temperature of $250^{\circ}C$. Water vapor inhibited the conversion of 1,2-DCB, which was suspected to be due to the competitive adsorption between the reactant and water for active sites.

Theoretical Calculation and Experimental Verification of the Hf/Al Concentration Ratio in Nano-mixed $Hf_xAl_yO_z$ Films Prepared by Atomic Layer Deposition

  • Kil, Deok-Sin;Yeom, Seung-Jin;Hong, Kwon;Roh, Jae-Sung;Sohn, Hyun-Cheol;Kim, Jin-Woong;Park, Sung-Wook
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.2
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    • pp.120-126
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    • 2005
  • We have proposed a characteristic method to estimate real composition when multi component oxide films are deposited by ALD. Final atomic concentration ratio was theoretically calculated from the film densities and growth rates for $HfO_2$ and $Al_2O_3$ using ALD processed HfxAhOz mms.W e have transformed initial source feeding ratio during deposition to fins] atomic ratio in $Hf_xAl_yO_z$ films through thickness factors ($R_{HFO_2}$ ami $R_{Al_2O_3}$) ami concentration factor(C) defined in our experiments. Initial source feeding ratio could be transformed into the thickness ratio by each thickness factor. Final atomic ratio was calculated from thickness ratio by concentration factor. It has been successfully confirmed that the predicted atomic ratio was in good agreement with the actual measured value by ICP-MS analysis.

Effect of KHCO3 Concentration Using CuO Nanowire for Electrochemical CO2 Reduction Reaction

  • Kanase, Rohini Subhash;Kang, Soon Hyung
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.11-17
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    • 2020
  • Copper has been proved to be the best catalyst for electrochemical CO2 reduction reaction, however, for optimal efficiency and selectivity, its performance requires improvements. Electrochemical CO2 reduction reaction (RR) using CuO nanowire electrode was performed with different concentrations of KHCO3 electrolyte (0.1 M, 0.5 M, and 1 M). Cu(OH)2 was formed on Cu foil, followed by thermal-treatment at 200℃ under the air atmosphere for 2 hrs to transform it to the crystalline phase of CuO. We evaluated the effects of different KHCO3 electrolyte concentrations on electrochemical CO2 reduction reaction (RR) using the CuO nanowire electrode. At a constant current (5mA), low concentrated bicarbonate exhibited a more negative potential -0.77 V vs. Reversible Hydrogen Electrode (RHE) (briefly abbreviated as VRHE), while the negative potential reduced to -0.33 VRHE in the high concentration of bicarbonate solution. Production of H2 and CH4 increased with an increased concentration of electrolyte (KHCO3). CH4 production efficiency was high at low negative potential whereas HCOOH was not influenced by bicarbonate concentration. Our study provides insights into efficient, economically viable, and sustainable methods of mitigating the harmful environmental effects of CO2 emission.

A Study on the Degradation Characteristics of 1,4-dioxane at Different Initial $H_2O_2$ Concentration with Advanced Oxidation Process using Ozone and Hydrogen Peroxide ($O_3/H_2O_2$를 이용한 고급산화공정에서 초기 $H_2O_2$ 농도에 따른 1,4-dioxane의 제거 특성 연구)

  • Park, Jin-Do;Suh, Jung-Ho;Lee, Hak-Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1108-1113
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    • 2005
  • Advanced oxidation process involving $O_3/H_2O_2$ was used to eliminate 1,4-dioxane and to enhance the biodegradability of dioxane-contaminated water. Oxidation process was carried out in a bubble column reactor under different pH and $H_2O_2$ concentrations. The removal efficiencies of 1,4-dioxane were investigated at hydrogen peroxide concentration between 40 and 120 mg/L. At the same pH, removal efficiencies of 1,4-dioxane increased with increasing initial $H_2O_2$ concentration. There was a linear relationship between initial concentration of $H_2O_2$ and the amount of consumed $O_3$. It was observed that the high $H_2O_2$ concentration accelerated the generation of hydroperoxy ions(${HO_2}^-$) and hydroxyl radicals($OH{\cdot}$). Hydrogen peroxide enhanced the decomposition of 1,4-dioxane and the biodegradability of the solution.