• 한국응용과학기술학회지
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• 제28권4호
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• pp.402-409
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• 2011

Compatibility and properties of PP/N66 blends with or without PP-g-MAH as a compatibilizer were investigated by DSC, SEM and universal testing machine. Morphological studies revealed that PP and N66 were incompatible and addition of PP-g-MAH was very effective to enhance the compatibility between PP and N66. The compatibilization effect between N66 and PP-g-MAH was based on the reaction between the amine end group of N66 and anhydride group in PP-g-MAH. The crystallization and melting behavior of PP/N66 blends were investigated and the results of analyses for enthalpy changed were discussed. The Izod impact strength could be improved by optimizing the compatibilizer concentration. Tensile strength, elongation at break, notched Izod impact strength were increased with using compatibilizer, however, both the compatibilized and the noncompatibilizer blends did not show any big difference in the flexural modulus.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2354-2358
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• 2007

MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2359-2362
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• 2007

MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

• 한국산학기술학회논문지
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• 제15권6호
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• pp.3990-3996
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• 2014

나일론66/유리섬유 복합체의 경우 $300^{\circ}C$ 이상의 고온에서 사출가공 될 때 물성 저하가 일어날 수 있어, 재이용시 열이력에 대한 체계적인 연구가 필요하다. $305/290/273/268/265/260^{\circ}C$ 온도조건의 이축압출기(twin screw extruder)를 이용하여 나일론66/유리섬유 복합체의 압출시료를 압출횟수에 따라 제조하였다. 압출횟수에 따른 화학구조, 열적특성, 용융지수, 결정구조, 아이조드 충격강도 및 유변학적 특성을 FT-IR, 용융지수 측정기, DSC, TGA, XRD, Izod 시험기, 그리고 유변물성 측정기를 이용하여 분석하였다. 적외선분광 스펙트럼을 이용하여 확인한 결과 압출횟수에 따른 압출시편에서의 화학구조 변화는 확인되지 않았다. 압출횟수에 따라 분자량이 감소하는 것을 용융지수와 복소점도를 이용하여 확인하였다. 나일론66/유리섬유 복합체의 용융온도는 큰 변화가 없으나, 압출횟수 증가에 따라 분해온도가 $20^{\circ}C$ 정도까지 감소하는 것을 DSC와 TGA를 이용하여 확인하였다. 압출시편의 아이조드 충격강도는 압출횟수가 증가함에 따라 감소하였다. 또한 나일론66/유리섬유 복합체 압출시편의 G'-G" 곡선의 기울기나 형태가 변하지 않는 것으로부터 압출시편에 가교와 같은 구조변화가 크게 나타나지 않음을 알 수 있었다.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1997년도 춘계학술발표회 논문집
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• pp.235-239
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• 1997

• 한국가스학회지
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• 제11권1호
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• pp.34-39
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• 2007

본 본문에서는 LPG 용기용 밸브의 개폐과정에서 발생하는 밸브패킹과 밸브시트의 상대접촉 마찰작용에 따른 밀봉성에 대한 FEM 해석결과를 제시하고 있다. 개폐용 밸브의 밀봉작용은 나일론-66으로 제조한 디스크 형상의 밸브패킹이 원형 파이프의 밸브시트 단면을 막아 LP 가스의 외부 송출을 차단하면서 완료된다. 밸브패킹은 밸브시트에 대하여 평면으로 접촉밀봉을 하는 경우와 원형홈의 둥근접촉 형상에 대한 밀봉 압착력을 확보하는 두 가지가 있다. FEM 해석 및 실험적 연구결과에 의하면, 밸브패킹을 사용하기 이전의 평면접촉 밀봉 작용력은 4.9 MPa로 높지만, 밸브를 사용한 이후의 원형홈 접촉 밀봉력은 4.4 MPa로 약간 낮게 나타났다. 그러나 이들 최대응력은 나일론 소재의 항복응력 83 MPa에 비하여 대단히 낮은 값이기 때문에 현재의 개폐밸브용 패킹은 과도하게 설계되었다 할 수 있다.

• 한국의류산업학회지
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• 제5권3호
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• pp.267-272
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• 2003

Tactel(Nylon66) union fabrics were woven with the specification of 70d/34f nylon as warp for sport wear jacket. Weft yarn has three types; 100% cotton yarn, nylon core-spun yarn and nylon-polyurethane covering yarn as weft. Fabric structers were plain, twill and satin weave structure with the air jet loom. The mechanical properties of 8 fabrics were measured with KES-F and primary Hand Values and Total Hand Values were calculated. The results of the study were as follows: 1) There was little difference among LTs of N/CM fabric groups. RT of the fabrics with CM100's was bigger than that of fabrics with CM80's, resulting that the fabrics with CM100's have better formability. In terms of weaving structure, twill fabrics have shape deformation. 2) In comparison of RTs with weft yarn type, RT of N-PU covering yarn was the highest, followed by Nylon core-spun yarn and cotton yarn. Thus, the fabric with N-PU covering yarn has better stability of shape deformation. 3) Stretch yarn could express an excellent silhouette formation and twill and satin structures were better structure to make curvature on human form. 4) 2HG/G value of nylon core-spun fabrics was larger than that of N/C fabrics, but the silhouette formation of N/C fabrics was excellent. 5) The RC of N/PU was the highest, followed by N/P, and N/CM. 6) Koski of N/PU fabrics was the highest, Numeri of N/PU and N/Co-I were relatively higher than the others. THVs of N/CM-IV and N/CO-II were lower than the others, resulting that, twill structure was better than plain structure for a sport wear uses.

• Membrane and Water Treatment
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• 제10권6호
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• pp.441-449
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• 2019

In this study, cellulose acetate (CA) / nylon66 (NYL66) (95/5) blend membranes with different thicknesses were prepared by a solvent evaporation method. The effects of membrane thickness (almost $7-25{\mu}m$), feed concentration (70-95 wt.% isopropanol), and feed temperature ($30-60^{\circ}C$) were investigated on the performance of membrane in the separation of isopropanol-water mixtures. With regard to the results of sorption experiments, it was found that the increase of feed temperature enhanced the overall sorption while by increasing feed concentration, the overall sorption passed through a maximum value at 70 wt. % isopropanol (IPA). The best separation factor 3080.51 was gained at high isopropanol concentration 95 wt.%, low feed temperature $30^{\circ}C$, and high membrane thickness $24.62{\mu}m$. Regarding the pervaporation separation index, the obtained results showed that proper values for the thickness of membrane, feed temperature, and isopropanol concentration in feed were $24.62{\mu}m$, $40^{\circ}C$, and 70 wt.%, respectively.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2008년도 제38차 학술발표대회
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• pp.159-161
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• 2008

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2005년도 추계학술발표회 및 workshop
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• pp.147-148
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• 2005