• Title/Summary/Keyword: Nylon6,6

Search Result 507, Processing Time 0.023 seconds

Natural Dyeing Properties and Antibacterial Activity of Nylon Fabric Dyed with Cochineal (코치닐에 의한 나일론직물의 천연 염색성과 항균성)

  • Bae, Jung-Sook;Huh, Man-Woo
    • Fashion & Textile Research Journal
    • /
    • v.8 no.6
    • /
    • pp.702-708
    • /
    • 2006
  • The purpose of this study was to investigate the dyeing-property and antibacterial activity on nylon fabric dyed with cochineal at variable dyeing conditions. Al, Cr, Fe, Cu and Sn were used as mordants and adsorption was compared with different mordanting methods. The maximum UV-visible absorption band of cochineal extract was 495 nm. The dyeability on nylon fabric was good because of having a amine group. The optimum dyeing conditions of nylon fabrics are dyeing concentration 1.5%(o.w.s), dyeing temperature $60^{\circ}C$, pH 3 and dyeing time 30 minutes. The pre-mordanting method is preferred for Al and Cr, and the post-mordanting one is preferred for Cu, Sn and Fe to achieve better dyeing. The optimum mordanting conditions of wool fabrics dyed with cochineal are mordanting concentration of 0.5%(o.w.s), mordanting temperature $60^{\circ}C$, and dyeing time 30 minutes. Nylon fabrics dyed with cochineal show a little antibacterial activity, but it was increased by Sn mordanting. MIC test results in antibacterial activities revealed that the antibacterial activity of Cu was the highest among mordants, but Sn mordant was the most effective in antibacterial activities after mordanting treatment of nylon fabric. The fastness properties of dyed nylon fabric showd a little worse or a similar level and there was no significant difference between a mordanted and non-mordanted fabric.

Performance Test and Finite Element Analysis of Pneumatic Muscle Actuator (공기압 근육 구동기의 유한요소 해석 및 성능시험)

  • Huh Shin;Bae Sang-Kyu;Kim Dong-Soo;Kim Wan-Doo;Hong Sung-In
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.30 no.6 s.249
    • /
    • pp.662-669
    • /
    • 2006
  • The pneumatic muscle actuator consists of an air bellows tube with two end-flanges. The air bellows tube is made from rubber layers and flexible sheathing formed from nylon 6 fibers. This structure can be stretched or compressed to convert the radial expansive forces into contractile forces. We performed the finite element analysis and the performance test of pneumatic muscle actuator. Also, the pneumatic muscle actuator was manufactured and tested by home-made tester. The results of FEA was similar with performance test below the maximum error of 42 %.

Changes in Mechanical Properties, Hand, and Appearance according to Dyeing of Cotton, PET, Nylon, and Cotton Mixture Fabrics (면, 폴리에스테르, 나일론, 면 교직물의 염색후 역학특성, 태 그리고 봉제성 변화)

  • Jo, Gil-Su;Lee, Eun-Ju;Im, Ji-Yeong
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.20 no.6
    • /
    • pp.1138-1150
    • /
    • 1996
  • This study was carried out to investigate the effects of dyeing on the mechanical properties, primary hand, total hand value (THV), and total appearance value (TAV) of woven fabrics. Cotton, PET, nylon, cotton/PET, and cotton/nylon woven fabrics were used as test specimens. Each of fabric was dyed under the same conditions as the fabrics for sportswear which consumers have selected as best. Mechanical properties of specimens were measured by KES-FB system and primary hand and THV were calculated by equation KN -201-MDY and KN-301-WINTER respectively. TAV was calculated by KN (eq. 10). The results were as follows: 1. In mechanical properties. tensile energy increased when cotton and two cotton mixture fabrics were dyed and decreased when polyester and nylon fabrics were dyed. Bending rigidity and shear rigidity decreased after all fabrics were dyed except nylon and cotton/ nylon mixture fabrics showing higher rigidities. Cotton fabrics showed higher surface roughness while other fabrics did lower values after dyeing. 2. In evaluation of primary hand and total hand , four primary hands of cotton fabrics so decreased after dyeing that THV were lowered. Numeri, Fukurami, and Sofutosa in primary hand of polyester, cotton/polyester, and cotton/nylon fabrics and Koshi and Numeri of nylon fabrics increased after dyeing and therefore THV of four fabrics were improved. 3. Cotton and polyester fabrics showed higher TAV due to their lower bending and shear rigidity, while nylon and cotton/nylon fabrics did lower values due to their higher shear rigidity. 4. It was proposed that the method of dyeing or treatment for minimizing the decrease of THV of cotton fabrics and TAV of nylon fabrics should be developed.

  • PDF

Comparison of Shelf-life of Vienna Sausage Packed with Polyvinylidene Chloride and Nylon Laminated Film (PVDC와 Nylon 적층필름으로 포장한 비엔나소시지의 Shelf-life 비교)

  • Park, Hyung-Woo;Kim, Byeong-Sam;Park, Moo-Hyun
    • Korean Journal of Food Science and Technology
    • /
    • v.21 no.2
    • /
    • pp.252-257
    • /
    • 1989
  • Nylon laminated low density polyethylene(LDPE) film is mostly used for package of Vienna sausage in Korea. The water vapor permeability and gas transmission rate of Nylon laminated LDPE film is higher than that of Oriented polypropylene/polyvinylidene chloride coated LDPE film. Comparision of shelf-life of Vienna sausage packed with both film was as follows. The water vapor permeability and gas transmission rate of PVDC coated film were 2.5 times lower and 20.7 to 30 times lower than those of Nylon laminated film, respectively. Shelf-lives of Vienna sausage packed with Nylon laminated film and PVDC coated films were 25 days and 31 days at $15^{\circ}C$, 32 days and 41 days at $5^{\circ}C$, respectively.

  • PDF

Characterization of Synthetic Polyamides by MALDI-TOF Mass Spectrometry

  • Choi, Hae-Young;Choe, Eun-Kyung;Yang, Eun-Kyung;Jang, Sung-Woo;Park, Chan-Ryang
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.12
    • /
    • pp.2354-2358
    • /
    • 2007
  • MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

Highly Dispersed CuO Nanoparticles on SBA-16 Type Mesoporous Silica with Cyclam SBA-16 as a Precursor

  • Prasetyanto, Eko Adi;Sujandi, Sujandi;Lee, Seung-Cheol;Park, Sang-Eon
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.12
    • /
    • pp.2359-2362
    • /
    • 2007
  • MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

Natural Dyeing of Fabrics with a Dyebath Extracted from C. Umshiu Mandarin Peel (온주밀감 과피 추출액을 이용한 직물의 천연염색)

  • 임은숙;이혜선
    • Journal of the Korean Society of Costume
    • /
    • v.54 no.6
    • /
    • pp.141-148
    • /
    • 2004
  • This study examines the dyeability of fabrics in relation to dyeing temperature, time, concentration, and the number of repeated dyeings. For this study, at first we extracted natural dyes from the peel of C.umshiu mandarin, which is fast as a dye and considered as recycling agricultural wastes. Additionally, it represents the image of Jeju Island. Then, we dyed cotton, wool, silk and nylon fabrics with the extracted dyes. The findings of this study are as follows. 1) Dyed cotton, wool, silk and nylon fabrics with the extract of C.umshiu mandarin peel are generally yellow. 2) Wool, nylon, silk, and cotton, in this order, are of good dyeability; Wool fabrics have the highest dyeability and cotton fabrics have the lowest. The dyeabilty of cotton fabrics was not improved even after dyeing in different conditions. 3) Colorfastness with washing, rubbing and perspiration are all good, while colorfastness with light is poor. 4) Higher dyeing concentration makes better dyeability. 5) Dyeability is enhanced as the dyeing temperature increases, while the dyeability of silk and nylon is relatively good even at low temperatures. 6) Looking at dyeability according to dyeing time, the longer the dyeing time, the better the dyeablility. Sixty minutes of dyeing time is appropriate to dye fabrics. 7) With an increase in the number of repeated dyeings, increased dyeability is obtaihed.

Degradation Behavior of Nylon 4 in the Presence of Newly Synthesized Thermal Stabilizers (합성 열안정제에 의한 나일론 4의 분해거동)

  • Jang, Geunseok;Kim, Jongho;Kim, Daigeun;Kim, Young Jun;Lee, Taek Seung
    • Polymer(Korea)
    • /
    • v.38 no.3
    • /
    • pp.314-319
    • /
    • 2014
  • Three kinds of thermal stabilizers for nylon 4 were synthesized to incorporate both hindered amine groups and methylene units with various lengths. It is expected that the hindered amine groups play a role in the capture of degradation-triggering species. Considering sequence rules, hydrogen bonding formed between nylon 4 and the stabilizers is optimized to alter the lengths of the methylene units in the stabilizers. As a result, it was found that a tetramethylene unit in the stabilizer is an optimal length for hydrogen bonding in terms of isothermal thermogravimetric analysis (TGA). Considering the slight and often negligible improvement of thermal stability of nylon 4 containing commercially-available nylon 6 stabilizers, retardation of thermal degradation has been substantially improved upon.

EFFECT OF TEFLON MEMBRANE AND NYLON MEMBRANE ON GUIDED BONE REGENERATON IN RABBIT TIBIA (가토 경골 골결손부에서 Nylon Membrane과 Teflon Membrane의 골유도 재생 효과)

  • Kim, Kwan-Shik;Cho, Byoung-Ouck;Lee, Young-Chan
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
    • /
    • v.26 no.2
    • /
    • pp.146-153
    • /
    • 2000
  • The purpose of present study is comparing the effect of Teflon Membrane and Nylon Membrane on bone regeneration in rabbit tibia. The 6 defects of $8{\times}8{\times}5mm$ size were drilled with dental handpiece in rabbit tibia, which on left side as an order of Control group(no coverage), Group 1(Nylon $5{\mu}m$ size), Group 3(Nylon $10{\mu}m$ size), and on right side Control group, Group 2($5{\mu}m$ Teflon), Group 4($10{\mu}m$ Teflon). Animals were killed at 7, 10, 14, 42 days to make specimens and observed the difference of healing potentials with light microscopy. The results were as follows ; 1. New bone formation has taken place at 14 days in Guided Bone Regeneration (GBR) group comparing to the Control group of massive inflammatory status. 2. Larger pore membrane allows more favorable healing potentials. Bone formation started earlier in larger membrane pore groups than smaller groups, until 14 days. 3. Bone forming potentials of Teflon membrane group was higher than Nylon membrane groups, Control group has the lowest bone forming potentials. 4. New bone formation was almost ended in 42 days, and there was no difference of bone formation between Nylon and Teflon membrane group of different size. There was no difference of bone formation at final stage(42 days) between Nylon membrane and Teflon membrane of same pore size. So nylon membrane may be clinically usable in guided bone regeneration case with further studies.

  • PDF

Structural Characteristics of Nylon 6 Grafted with Polyacrylamide (아크릴아미드로 그라프트 공중합시킨 나일론6의 구조적 특성)

  • Lee, Yang Hun;Park, Chan Hun;Shin, Eun Joo;Choi, Suk Chul
    • Textile Coloration and Finishing
    • /
    • v.9 no.1
    • /
    • pp.1-14
    • /
    • 1997
  • Nylon 6 grafted with polyacrylamide(PAAm) was synthesized by a dispersion polymerization method at 6$0^{\circ}C$ for 2 hours, and a cresol-soluble graft polymer(CSGP) and water-dispersable graft polymer (WI)GP) were separated. Infra-red(IR) spectrum analysis, differential scanning calorimetery(DSC), thermogravimetery(TG), and X-ray diffraction analysis were carried out to research their structural characteristics.

  • PDF