• 제목/요약/키워드: Nylon6,6

검색결과 507건 처리시간 0.025초

Sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate를 이용한 나일론/면 복합소재의 단일 산성염료 일욕염색 (Dyeing of Nylon/Cotton Blend with Acid Dyes Using Sodium 2-(2,3- dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate)

  • 김미경;윤남식;김태경
    • 한국염색가공학회지
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    • 제24권1호
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    • pp.8-17
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    • 2012
  • In order to dye nylon/cotton blended fabrics in solid colors with only acid dyes, a hetero-bifunctional bridge compound (DBDCBS) was examined. The bridge compound was designed to react only onto cotton fabrics first, on which amino-containing acid dyes react later by covalent bonding. By the effect of DBDCBS, amino-containing acid dyes exhibited high affinity toward the cotton fabrics. From the dyeing properties examined at various conditions, the optimum dyeing was decided at pH 4 and $100^{\circ}C$. Consequently, the solid color was obtained on nylon/cotton blended fabrics in one bath dyeing process using only acid dyes. The DBDCBS did not show any negative effect on nylon side in terms of dyeing and physical properties.

Mechanical and thermal properties of polyamide versus reinforced PMMA denture base materials

  • Soygun, Koray;Bolayir, Giray;Boztug, Ali
    • The Journal of Advanced Prosthodontics
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    • 제5권2호
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    • pp.153-160
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    • 2013
  • PURPOSE. This in vitro study intended to investigate the mechanical and thermal characteristics of Valplast, and of polymethyl methacrylate denture base resin in which different esthetic fibers (E-glass, nylon 6 or nylon 6.6) were added. MATERIALS AND METHODS. Five groups were formed: control (PMMA), PMMA-E glass, PMMA-nylon 6, PMMA-nylon 6.6 and Valplast resin. For the transverse strength test the specimens were prepared in accordance with ANSI/ADA specification No.12, and for the impact test ASTM D-256 standard were used. With the intent to evaluate the properties of transverse strength, the three-point bending (n=7) test instrument (Lloyd NK5, Lloyd Instruments Ltd, Fareham Hampshire, UK) was used at 5 mm/min. A Dynatup 9250 HV (Instron, UK) device was employed for the impact strength (n=7). All of the resin samples were tested by using thermo-mechanical analysis (Shimadzu TMA 50, Shimadzu, Japan). The data were analyzed by Kruskal-Wallis and Tukey tests for pairwise comparisons of the groups at the 0.05 level of significance. RESULTS. In all mechanical tests, the highest values were observed in Valplast group (transverse strength: $117.22{\pm}37.80$ MPa, maximum deflection: $27.55{\pm}1.48$ mm, impact strength: $0.76{\pm}0.03$ kN). Upon examining the thermo-mechanical analysis data, it was seen that the E value of the control sample was 8.08 MPa, higher than that of the all other samples. CONCLUSION. Although Valplast denture material has good mechanical strength, its elastic modulus is not high enough to meet the standard of PMMA materials.

왁스와 오일 또는 흑연의 함침에 의한 나일론의 마찰특성 향상에 관한 연구 (A Study on the Improvement of Frictional Properties of Nylon Impregnated with Wax and Oil or Graphite)

  • 강석춘;정대원
    • 한국자동차공학회논문집
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    • 제10권6호
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    • pp.142-149
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    • 2002
  • The frictional properties of nylon can be improved by the impregnation of lubricants like wax, oil or graphite. The inclusion of these lubricants, on the other hand, decreases the mechanical properties of nylon, such as tensile strength, hardness and impact strength. As an attempt to maximize frictional properties, while minimizing a decrease in the mechanical properties, various kinds of nylon containing 3 wt% wax and varying contents of oil or graphite were prepared. It was found that the synergy effects to improve both friction and anti-wear properties is evidenced by impregnating a combination of wax/oil or wax/graphite. The wear rate of a nylon containing 3 wt% of wax and 1.5 wt% of oil turned out to be 1/4 of that of nylon impregnated with 8 wt% wax or 8 wt% oil. The latter showed the lowest wear rate among the nylons prepared with a single lubricant. In addition, the friction coefficient of the developed nylon was found to be very similar to the nylon with 8 wt% wax only.

Effect of Washing and Subsequent Heat Treatment on Water Repellency and Mechanical Properties of Nylon 6, Triacetate and Silk Fabrics Treated with Hydrocarbon Resins

  • Park, Hyei-Ran;Lee, Mun-Cheul;Nishi, Kenji;Wakida, Tomiji
    • 한국염색가공학회지
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    • 제20권6호
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    • pp.87-91
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    • 2008
  • It is commonly known that water repellency of the fabric treated with fluorocarbon resin brings about a decrease by the washing and recovers by the subsequent heat treatment. In this article, effect of the water repellency was investigated on the nylon 6, triacetate and silk fabrics treated with hydrocarbon and silicon resins. Hydrocarbon and silicon resins have been widely used in the textile finishing as the softening and water proofing agents. The fabrics were treated with hydrocarbon resins, Paragium JQ and RC (Ohara Paragium Chemical Co.) and a silicon resin, Poron MR (Shinetsu Chemical Co.), and then washed and subsequently heat treated. Although the water repellency increased by the resin treatment, it decreased by the washing apparently and recovered a little by the heat treatment. The effect of the heat treatment was small comparing with that of the fluorocarbon resin. Furthermore, as a mechanical property of the treated fabric, KES shearing and bending hysteresis parameters, modulus and hysteresis width of the hydrocarbon resin-treated nylon 6, triacetate and silk fabrics decreased by the heat treatment after washing. Therefore, the treatment is effective at improving the softening of the fabric in water repellent finish.

마찰하전형(摩擦荷電型) 정전선별(靜電選別)에 의한 폐플라스틱 맥주병 재질분리(材質分離)에 관한 연구(硏究) (A Study on Material Separation of Waste Plastics Beer Bottle by Triboelectrostatic Separation)

  • 전호석;;백상호;박철현;최우진
    • 자원리싸이클링
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    • 제17권1호
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    • pp.43-50
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    • 2008
  • 본 연구에서는 마찰하전형정전선별법을 적용하여 폐플라스틱 맥주병(PET, Nylon)의 재활용을 위한 재질분리 연구를 수행하였다. 하전재질 선정을 위한 하전특성 연구결과, PMMA가 폐플라스틱 맥주병(PET, Nylon)의 재질분리에 가장 효과적인 하전재질로 확인되어, PMMA를 사용한 pipe line와 cyclone 하전장치를 개발하였다. 본 연구에서 개발된 pipe line과cyclone 하전장치를 이용한 재질분리 실험결과, 최적 실험조건에서 PET의 품위와 회수율이 각각 99.6%와 88.2%인 결과를 얻어, 폐플라스틱 맥주병(PET, Nylon) 재활용을 위한 재질분리 기술을 확립하였다.

Nylon6 / AgO복합섬유의 연신 및 열처리에 따른 미세구조와 물성 (The fine structure and physical properties of Nylon6/AgO bicomponent fiber on drawing and annealing)

  • 김동환;이선희;정호규;조현혹
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 봄 학술발표회 논문집
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    • pp.239-242
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    • 2003
  • 고분자 물질은 여러 가지 물질과 복합체를 형성하여 물리적 성질을 향상시켜왔다. 특히 유ㆍ무기물질의 복합체는 의류용, 산업용 차원에서 관심이 증대되고 있으며, 유ㆍ무기 입자가 첨가된 고분자 복합소재는 고분자 매트릭스에 기계적, 열적 특성을 향상시킬 뿐만 아니라 이들의 다양한 기능성을 부여할 수 있다.[1] 최근 수 십 년 동안 자연 오염문제로 인하여 섬유분야에서도 항균 처리가 관심이 증대되고 있다. (중략)

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폴리우레탄 함량과 블렌드 시간이 Nylon 6/pu 블렌드의 결정구조 및 기계적 특성에 미치는 영향 (Effects of the Polyurethane Contents and Blend Time on the Crystalline Structure and Mechanical Properties of Nylon 6/PU Blend)

  • 윤철수;지동선
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2002년도 봄 학술발표회 논문집
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    • pp.474-477
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    • 2002
  • 열가소성 폴리우레탄(PU)은 우수한 탄성을 갖는 유용한 고분자중의 하나로 섬유나 플라스틱에 널리 사용되고 있다. PU는 상온보다 높은 유리전이 온도(T$_{g}$)를 갖는 유리상의 hard segment와 상온보다 낮은 유리전이 온도(T$_{g}$)를 갖는 고무상의 soft segment로 구성되어 있으며 열역학적으론 비상용성으로 인하여 미세 상분리 구조를 가지게 되어 고무보다 높은 탄성률과 우수한 인장 회복거동을 갖게 된다[1-3]. (중략)

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장섬유강화 Nylon6/PPS 복합재료에 관한연구 (A study on the Long Fiber Reinforced Nylon6/PPS Composites)

  • 윤병선
    • 유변학
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    • 제8권2호
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    • pp.69-77
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    • 1996
  • 장섬유강화 열가소성 고분자 복합재료 (FRTP)의 난연성과 개선을 위하여 polyhenylene sulfide(PPS)를 첨가한 polyamide 6(PA6)/glass fiber (GF)의 FRTR를 제조하 였다. 고점성수지내에 보강섬유를 균일하게 분산시키고 함침성을 높임과 동시에 보강섬유의 손상을 방지하기 위하여 섬유상 수지와 보강섬유를 분섬비동장치에서 직접혼방시키고 이를 압축성형하는 독특한 공정을 도입하였다. 제조된 복합재료의 유변학적 특성 형태학적특성 인장 및 충격특성 열적특성, 난연성, 내약품성에 관한연구를 수행한 결과 복합재료와 기계적 특성을 약화시키지 않으면서도 난연성가 내약품성을 현격히 향상시킬수 있는 FRTP의 제조 가 가능함을 확인하였다.

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그래핀/탄소나노튜브(FCN) 첨가에 따른 Polyamide-Nylon 6의 기계적 특성에 미치는 영향 (Effect of Adding Graphene/Carbon Nanotubes (FCN) on the Mechanical Properties of Polyamide-Nylon 6)

  • 여승준;신해름;노우승;김만태
    • 한국산업융합학회 논문집
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    • 제26권6_3호
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    • pp.1297-1303
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    • 2023
  • Research on enhancing the mechanical strength, lightweight properties, electrical conductivity, and thermal conductivity of composite materials by incorporating nano-materials is actively underway. Thermoplastic resins can change their form under heat, making them highly processable and recyclable. In this study, Polyamide-Nylon 6 (PA6), a thermoplastic resin, was utilized, and as reinforcing agents, fused carbon nano-materials (FCN) formed by structurally combining Carbon Nanotube(CNT) and Graphene were employed. Nano-materials often face challenges related to cohesion and dispersion. To address this issue, Silane functional groups were introduced to enhance the dispersion of FCN in PA6. The manufacturing conditions for the composite materials involved determining the use of a dispersant and varying FCN content at 0.05 wt%, 0.1 wt%, and 0.2 wt%. Tensile strength measurements were conducted, and FE-SEM analysis was performed on fracture surfaces. As a result of the tensile strength test, it was confirmed that compared to pure PA6, the strength of the polymer composite with a content of 0.05 wt% was improved by about 60%, for 0.1 wt%, about 65%, and for 0.2 wt%, the strength was improved by 50%. Also, when compared according to the content of FCN, the best strength value was shown when 0.1 wt% was added. The elastic modulus also showed an improvement of about 15% in the case of surface treatment compared to the case without surface treatment, and an improvement of about 70% compared to pure PA6. Through FE-SEM, it was confirmed that the matrix material and silane-modified nanomaterial improved the dispersibility and bonding strength of the interface, helping to support the load evenly and enabling effective stress transfer.