• 한국자기공명학회논문지
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• 제14권1호
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• pp.18-27
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• 2010

The NMR spectrum and spin-lattice relaxation times, $T_1$, of the $^{1}H$ nuclei in $(NH_{4})_{2}Cd_{2}(SO_{4})_{3}$ single crystals were obtained. The two minima in $T_1$ in the paraelectric phase are attributed to the reorientational motions of the $NH_{4}^{+}$ groups. The $^{1}H\;T_1$ of the $(NH_{4})_{2}Cd_{2}(SO_{4})_{3}$ crystals can be described with Bloembergen- Purcell-Pound (BPP) theory. The experimental value of $T_1$ can be expressed in terms of an isotropic correlation time ${\tau}_H$ for molecular motions by using the BPP theory, and determine the role of protons in these processes.

• Journal of Magnetics
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• 제5권3호
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• pp.73-75
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• 2000

Undoped and Cr-doped samples of electrooptic material KTiOPO$_4$ were studied by $^{31}$P nuclear magnetic resonance (NMR). Spin-lattice relaxation time ($T_1$) measurements manifested phase transition behaviors that are attributed to changes in the dominant charge carriers in different temperature ranges.

• Current Optics and Photonics
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• 제4권6호
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• pp.466-471
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• 2020

We analyze the transverse nuclear magnetizations of 129Xe and 131Xe in a vapor cell containing natural Xe, 87Rb, and buffer gases. Th e Xe atoms are polarized th rough spin-exch ange optical pumping (SEOP) with Rb atoms under low-magnetic-field conditions. From the free-induction-decay (FID) signal, we measure the nuclear magnetization of the Xe atoms in the Xe-Rb vapor cell. Furthermore, we measure the dependence of the gyromagnetic ratio on the magnetization of 129Xe and 131Xe by examining the amplitude of the FID signal of each isotope, and we evaluate the relationship between the magnetic field gradient and transverse relaxation rate for both of the 129Xe and 131Xe isotopes.

• 한국자기공명학회논문지
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• 제22권4호
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• pp.76-81
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• 2018

Investigation of the protein-protein interaction mode at atomic resolution is essential for understanding on the underlying functional mechanisms of proteins as well as for discovering druggable compounds blocking deleteriou interprotein interactions. Solution NMR spectroscopy provides accurate and precise information on intermolecular interactions even for weak and transient interactions, and it is also markedly useful for examining the change in the conformation and dynamics of target proteins upon binding events. In this mini-review, we comprehensively describe three unique and powerful methods of solution NMR spectroscopy, paramagnetic relaxation enhancement (PRE), pseudo-contact shift (PCS), and residual dipolar coupling (RDC), for the study on protein-protein interactions.

• 지구물리와물리탐사
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• 제16권2호
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• pp.97-105
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• 2013

자기공명검층은 수소와 자기장의 상호작용을 측정, 분석하는 물리검층 방법으로 이는 저류층 평가를 위한 중요한 물리검층 방법 중 하나이다. 측정된 감쇠 신호 즉, 이완은 측정지역 내 수소의 밀도에 대한 정보와 유체의 종류에 따른 감쇠속도에 대한 정보를 포함하고 있으며, 이를 바탕으로 공극률, 투과도와 습윤도 등을 예측할 수 있다. 1950년대 초반 랜덤워크로 자기공명의 이완감쇠를 시뮬레이션한 것을 시작으로 자기공명반응에 대한 연구가 급격히 발전되었다. 이 논문에서는 자기공명 시뮬레이션의 연구 동향을 먼저 살펴 보고, 자기공명반응인 이완을 발생시키는 이완메커니즘에 대해 간단히 알아본다. 이에 기초하여 자기공명검층에서 주로 측정하는 횡축이완곡선을 자기장구배를 고려하는 경우와 고려하지 않는 시뮬레이션 방법에 대해 비교분석하고 자기장구배가 이완메커니즘 및 횡축이완곡선에 미치는 영향에 대해 분석한다.

• 한국자기학회지
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• 제25권6호
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• pp.185-188
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• 2015

본 연구에서는 FT-NMR 분광기를 사용하여 $NaMgCl_3$ 단결정의 구성 원자인 $^{23}Na$ 원자핵에 대한 핵 자기 공명 실험을 하였다. 이로부터 $^{23}Na$ 원자핵이 모결정 내에서 입방정계 대칭성 내에 존재한다는 것을 알았고, 200 K~410 K 온도 범위에서 $^{23}Na$ 원자핵에 대한 스핀-격자 완화 시간 $T_1$을 온도 변화에 따라 계산하였다. 온도가 증가함에 따라서 $^{23}Na$ 원자핵의 $T_1$ 값이 점차적으로 감소하였다. 스핀-격자 완화율 $1/T_1$ 이 온도 T에 선형적으로 비례하였고, $^{23}Na$ 원자핵의 스핀-격자 완화 메커니즘을 $^{23}Na$ 원자핵 스핀과 단일 포논이 직접적으로 작용하는 직접과정(direct process)으로 설명하였다. 또한 $^{23}Na$ 원자핵의 활성화 에너지를 계산하여 $E_a=4.82J/mol$를 얻었다.

• 한국자기공명학회논문지
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• 제15권2호
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• pp.146-156
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• 2011

The line widths and spin-lattice relaxation times of protons in $[N(C_2H_5)_4]_2CoCl_4$ and $[N(CH_3)_4]_2CoCl_4$ single crystals were investigated in the temperature range 160-400 K. The temperature dependences of the spin-lattice relaxation times are attributed to the molecular motions of the ethyl and methyl groups in the $[N(C_2H_5)_4]^+$ and $[N(CH_3)_4]^+$ ions respectively. The NMR line widths indicate that the ethyl groups in $[N(C_2H_5)_4]_2CoCl_4$ have one more degree of freedom than the methyl groups in $[N(CH_3)_4]_2CoCl_4$. The experimental results are interpreted in terms of the reorientations of the methyl and ethyl groups.

• 한국자기공명학회논문지
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• 제17권1호
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• pp.24-29
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• 2013

The structural characteristics of 4-coordinate $BO_4$ [B(1)] and 3-coordinate $BO_3$ [B(2)] groups in $BiB_3O_6$ were studied by $^{11}B$ magic angle spinning (MAS) and single-crystal nuclear magnetic resonance (NMR) spectroscopy. The spin-lattice relaxation time in the laboratory frame, $T_1$, for $^{11}B$ decreased slowly with increasing temperature, whereas the spin-lattice relaxation times in the rotating frame, $T_{1{\rho}}$, for B(1) and B(2), which differed from $T_1$, were nearly constant. Further, $T_{1{\rho}}$ for B(1) and B(2) showed very similar trends, although the $T_{1{\rho}}$ value of B(2) was shorter than that of B(1). The 3-coordinate $BO_3$ and 4-coordinate $BO_4$ were distinguished by $^{11}B$ MAS NMR spectrum and $T_{1{\rho}}$.

• 한국자기공명학회논문지
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• 제18권1호
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• pp.41-46
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• 2014

In order to obtain information on the structural geometry of $NH_4HSeO_4$ near the phase transition temperature, the spectrum and spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for the ammonium and hydrogen-bond protons were investigated through $^1H$ MAS NMR. $T_{1{\rho}}$ for the hydrogen-bond protons abruptly decreased at high temperature and it is associated with the change in the structural geometry in $O-H{\cdots}O$ bonds. This mobility of the hydrogen-bond protons may be the main reason for the high conductivity.

• 한국자기공명학회논문지
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• 제19권3호
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• pp.119-123
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• 2015

The thermodynamic properties and structural geometry of $KMgCl_3{\cdot}6H_2O$ were investigated using thermogravimetric analysis, differential scanning calorimetry, and nuclear magnetic resonance. The initial mass loss occurs around 351 K ($=T_d$), which is interpreted as the onset of partial thermal decomposition. Phase transition temperatures were found at 435 K ($=T_{C1}$) and 481 K ($=T_{C2}$). The temperature dependences of the spin-lattice relaxation time $T_1$ for the $^1H$ nucleus changes abruptly near $T_{C1}$. These changes are associated with changes in the geometry of the arrangement of octahedral water molecules.