• 한국재료학회지
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• 제32권11호
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• pp.496-507
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• 2022

For the selective catalytic reduction of NOx with ammonia (NH₃-SCR), a V₂O₅WO₃/TiO₂ (VW/nTi) catalyst was prepared using V₂O₅ and WO₃ on a nanodispersed TiO₂ (nTi) support by simple impregnation process. The nTi support was dispersed for 0~3 hrs under controlled bead-milling in ethanol. The average particle size (D₅₀) of nTi was reduced from 582 nm to 93 nm depending on the milling time. The NOx activity of these catalysts with maximum temperature shift was influenced by the dispersion of the TiO₂. For the V_0.5W₂/nTi-0h catalyst, prepared with 582 nm nTi-0h before milling, the decomposition temperature with over 94 % NOx conversion had a narrow temperature window, within the range of 365-391 ℃. Similarly, the V_0.5W₂/nTi-2h catalyst, prepared with 107 nm nTi-2h bead-milled for 2hrs, showed a broad temperature window in the range of 358~450 ℃. However, the V_0.5W₂/Ti catalyst (D₅₀ = 2.4 ㎛, aqueous, without milling) was observed at 325-385 ℃. Our results could pave the way for the production of effective NOx decomposition catalysts with a higher temperature range. This approach is also better at facilitating the dispersion on the support material. NH₃-TPD, H₂-TPR, FT-IR, and XPS were used to investigate the role of nTi in the DeNOx catalyst.

• International Journal of Automotive Technology
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• 제4권1호
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• pp.47-55
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• 2003

The Center for Transportation Research at the Argonne National Laboratory (ANL) supports the DOE by evaluating advanced automotive technologies in a systems context. ha has developed a unique set of compatible simulation tools and test equipment to perform an integrated systems analysis project from modeling through hardware testing and validation. This project utilized these capabilities to demonstrate the trade-off in fuel economy and Oxides of Nitrogen (NOx) emissions in a so-called ‘pre-transmission’ parallel hybrid powertrain. The powertrain configuration (in simulation and on the dynamometer) consists of a Compression Ignition Direct Ignition (CIDI) engine, a Continuously Variable Transmission (CVT) and an electric drive motor coupled to the CVT input shaft. The trade-off is studied in a simulated environment using PSAT with different controllers (fuzzy logic and rule based) and engine models (neural network and steady state models developed from ANL data).

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2003년도 춘계학술대회 논문집
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• pp.362-363
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• 2003

Photochemical ozone is formed from nitrogen oxides (NOx) and volatile organic compounds(VOCs) through non-linear interactions between chemical reactions and meteorology, and the relationship between precursors and photochemical ozone will be changed to match the emission distribution and meteorological fields. It is generally known that for some conditions the process of ozone formation is controlled almost entirely by NOx and is largely independent of VOC, while for other conditions ozone production increases with increasing VOC and does not increase(or sometimes even decreases) with increasing NOx (omitted)

• 한국연소학회지
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• 제4권1호
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• pp.85-93
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• 1999

Experimental study on a porous ceramic liquid fuel combustor is performed. Compact burner with low pollutant emission and high combustion efficiency is realized through the use of porous ceramic materials of high porosities. The use of porous ceramic materials in burner material results in rapid vaporization of liquid fuel and enhancement in mixing process, and thus nearly premixed combustion of liquid fuel is achieved instead of diffusion and partially premixed combustion method, which is often used and apt to produce high pollutant emissions such as CO, NOx and soot. With this enhanced vaporization and premixing method of liquid fuel vapor and air, it is found that enhanced combustion process with intense radiation output and better emission characteristics in NOx, CO and soot emission, compared to other conventional liquid fuel burning method, are possible.

• 한국연소학회지
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• 제4권1호
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• pp.67-83
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• 1999

The objective of this study is development of low emission pulverized coal combustor for reducing pollutant emission generated from coal combustion. Low emission combustion technology for reducing NOx and fly ash was investigated by using 2 stage coaxial cyclone combustor. Staged combustion was employed for NOx reduction and high temperature slagging combustion was also studied for fly ash removal in the combustor. The result of this study shows that the low emission combustion system can reduce the amount of atmospheric pollutions with improved boiler efficiency and performance.

• 한국연소학회지
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• 제4권1호
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• pp.95-103
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• 1999

Experimental study on combustion characteristics of a regenerative combustor has performed. High-temperature air combustion in the regenerative combustor is obtained through heat recovery from exhaust gas flow by porous ceramic materials and through alternation of air flow direction through the combustor. Temperature field, CO and NOx emission with respect to the frequency of alternation are measured. It is found that at initial stage of the alternation, temperature of inlet section of main combustion chamber is increased sharply since both high temperature air preheated by the ceramics and prompt fuel injection results in rapid combustion. Following this initial stage, combustion temperature is reduced as the preheated air temperature is reduced. However peak temperature in the chamber and exhaust gas temperature are decreased as the alternation period is reduced, increased temperature of ceramic is observed. CO and NOx emission with respect to the alternation period is also examined. It is found that there exists a range of optimum alternating period for CO and NOx emission characteristics.

• 한국안전학회지
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• 제17권3호
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• pp.43-49
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• 2002

The NOx emission characteristics of double-concentric diffusion flames and normal diffusion flames fueled with CH$_4$ were studied. Experimental and numerical investigations were carried out for double-concentric diffusion flame with varying central air flow rate and normal diffusion flame. The Emission indices of NOx(EINOx) were measured by chemiluminescent method and calculated by numerical model based on detailed chemistry. From the comparison between double-concentric diffusion flames and normal diffusion flames, the results show that EINOx of double-concentric diffusion flames are lower than normal diffusion flame, because of Prompt EINOx was decreased. EINOx of double-concentric diffusion flames increase with central air flow rate increasing.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 E
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• pp.1806-1808
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• 1998

Tests of pilot-scale plasma DeSOx-DeNOx system using pulsed streamer corona were carried out. The system consists of the reactor with wire-plate electrodes the $30kW_{max}$. MPC type pulse generator, and $1MW_{th}$ pulverized coal combustor as a flue gas source. $NH_3$ and $C_2H_4$ were used to enhance the removal rate. The experimental result on the removal efficiency of SOx/NOx and on the effect of the additives was presented in this paper.

• 한국자동차공학회논문집
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• 제10권4호
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• pp.60-68
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• 2002

Experiments have been conducted to investigate the effects of emulsified fuels on the spray characteristics and exhaust emissions in a diesel engine. Four different fuels were examined : diesel, emulsified fuels with water contents which were varied with 13, 15, and l7wt%. Characteristics of fuel spray were measured by an optical method, PLLIF(planar liquid laser induced fluorescence). Compared to diesel fuel, emulsified fuels which had relatively high kinematic viscosity showed smaller spray angle and longer spray tip penetration. The qualitative droplet distributions of emulsified fuels showed worse atomization process than that of diesel fuel. As the water contents were increased, PM and NOx could be reduced simultaneously. It was specially noted that the emulsified fuel with l7wt% water content was found to be the best in reducing rates, NOx 30% and PM 40%.

• 동력기계공학회지
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• 제11권4호
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• pp.12-17
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• 2007

Recently, many small and medium size diesel vehicles have been equipped with turbocharger and EGR system to get high performance and reduce $NO_x$ emissions but its application to heavy-duty diesel engine is not common yet. In this work, the simulation model for EURO-3 engine was developed using WAVE and then its performance and emission level were verified by comparing with experimental results. The possibility of current EURO-3 engine equipped with LPL EGR system which would be satisfied the EURO-5 regulation are examined. ESC 13 mode was chosen as the primary engine test mode, and the injection timing and fuel quantity were changed to compensate the lost engine performance caused by EGR. The system developed in this study shows that the current EURO-3 engine could satisfy EURO-5 $NO_x$ regulation by applying LPL EGR.