• Title/Summary/Keyword: Normal values

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Kinetics and Mechanism of the Anilinolysis of Diethyl Thiophosphinic Chloride in Acetonitrile

  • Hoque, Md. Ehtesham Ul;Lee, Hai-Whang
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2306-2310
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    • 2011
  • The nucleophilic substitution reactions of diethyl thiophosphinic chloride with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at 55.0 $^{\circ}C$. The values of deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) invariably increase from secondary inverse ($k_H/k_D$ < 1) to primary normal (kH/kD > 1) as the nucleophiles change from the strongly basic to weakly basic anilines. The secondary inverse with the strongly basic anilines and primary normal DKIEs with the weakly basic anilines are rationalized by the gradual transition state (TS) variation from a predominant backside attack, via invariably increasing the fraction of a frontside attack, to a predominant frontside attack, in which the reaction mechanism is a concerted $S_N2$ pathway. A frontside attack involving a hydrogen bonded, four-center-type TS is substantiated by the primary normal DKIEs.

Work-rate Estimation for Predicting Fretting-wear in SG Tubes due to Turbulence Excitation (난류 가진에 의한 증기발생기 전열관의 마모 일률 평가)

  • 조봉호;유기완;박치용
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2004.05a
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    • pp.115-118
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    • 2004
  • In this study, amplitudes of turbulence excitation are obtained for selected tubes inside the KSNP SG and their normal work-rates are investigated to estimate the magnitude of fretting-wear. From the results of numerical calculation, row 40&41 tubes show the maximum work-rates. Up to this row number, the work-rates inside the row 41 have much larger values than those of outside tubes. This phenomenon reveals the particular central one which has larger normal work-rate than that of outside zone. It turns out that both of the higher local mode at the U-bend region and the larger value of effective mass in the central region Increase the normal work-rate enormously.

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Ultrasonic Tissue Characterization by Digital Spectrum Analysis Technique (Digital Spectrum 분석방법을 이용한 조직특성 변수에 관한 연구)

  • 곽철은;민병구
    • Journal of Biomedical Engineering Research
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    • v.5 no.1
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    • pp.55-62
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    • 1984
  • A digital spectrum analysis technique was used to estimate the tissue characteristic parameters (transmission velocity and attenuation coefficient) in the phantom study and the human liver's ultrasound scanning. The soft tissue equivalent phantom was made with the combination materials of agar, water, powdered graphite, and n-propyl alcohol. In the human study, twenty five normal subjects and three patients with liver diseases were studied using the ultrasonic reflection signals and the spectrum analysis method The following results were obtained; 1. The soft tissue-equivalent materical could be produced with various acoustic parameters by changing the composition amount of the powdered graphite and n-propyl alcohol. 2. Attenuation coefficients of normal human liver tissue were estimated to be 0. 36 dB/cm MHz$\pm$0.11. In patients with liver disese, tile attenuation coefficients were shown to be different from the above normal values.

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Shear Strength and Deformation Behavior of Rock Joint with Roughness (절리면의 거칠기에 따른 암석 절리의 전단강도 및 변형거동에 관한 연구)

  • 이상돈;강준호;이정인
    • Tunnel and Underground Space
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    • v.4 no.3
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    • pp.261-273
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    • 1994
  • Direct shear tests were carried out on the rock joints and artificial discontinuities to investigate the influence of joint roughness on the shear strength and deformation behaviour. Single direct shear testing apparatus used in experiment was designed and manufactured. Its capacity is 200 tons of shear load, 20 tons of normal load and 50$\textrm{cm}^2$ of maximum shear area. Test samples were cement mortar with artificial discontinuity and sandstone with natural joint. Peak shear strength was increased as joint roughness or normal stress was increased, especially, linearly increased with roughness angle in cement mortar. If joint roughness angle was constant at low normal stress, shear strength was not affected by width and height of joint roughness in cement mortar. Peak shear strengths obtained from tests were larger than the values calculated by Barton's equation, and shear stiffness was increased with joint roughness coefficient.

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Dynamic MOE and Internal Friction of Compression Woods in Pinus densiflora (소나무 압축응력재(壓縮應力材)의 동(動) 탄성율(彈性率)과 내부마찰(內部摩擦))

  • Hong, Byung-Wha;Byeon, Hee-Seop
    • Journal of the Korean Wood Science and Technology
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    • v.23 no.2
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    • pp.32-36
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    • 1995
  • A study was conducted to evaluate the dynamic mechanical properties (modulus of elasticity, resonant frequency and interanal friction) of compression wood in Pinus densiflora. Vibration method was used for estimation of dynamic modulus of elasticity and the values were compared to those of static bending modulus of elasticity. The results obtained are as follows: 1. The dynamic modulus of elasticity of compression wood decreased, whereas that of normal wood increased, with increasing specific gravity. 2. The resonant frequency of compression wood decreased, whereas that of normal wood increased, with increasing specific gravity. 3. The internal friction of compression wood increased with increasing specific gravity. 4. The correlation coefficients between dynamic and static moduli of elasticity in compression and normal woods were high.

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A rice-lognormal channel model for nongeostationary land mobile satellite system

  • 황승훈;한규진;안재영;서종수;황금찬
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.23 no.4
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    • pp.1113-1120
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    • 1998
  • This paper introduces a channel model that is a combination of Rice and log-normal statistics, with independent shadowing affectingeach direct and diffuse component, repectively. This model extends the channel model of a combined Rice and Log-normal, proposed by Corazza, to include the independent shadowing. The validity of model is confirmed by comparisons with the data collectedin the literature, the analytical model, and the computer model in terms of probability distribution of the evvelope of each model. The model turns out to be one of many well-known narrowband models in limiting cases, e.g. Rayleigh, Rice, log-normal, Suzuki, Loo, and Corazza. Finally, the examples of bit error probability evaluations for several values of the elevation angle in the channel are provided.

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The static thrust and normal force calculation of a Hybrid type LPM as a servo actuator (서보 액튜레이터용 Hybrid형 LPM의 정추력 및 수직력 계산)

  • Cho, Yun-Hyou;Koo, Dae-Hyon;Lee, Jae-Bong
    • Proceedings of the KIEE Conference
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    • 1994.07a
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    • pp.43-45
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    • 1994
  • This paper proposes the new method to calculate the static thrust and normal force of a hybrid type double-sided linear pulse motor by the coenergy which considered the magnetic nonlinealities. In the process of the computation, the nonlinear characteristics of the magnetic material were interpolated by the cubic spline method. And, to investigate the characteristics of the hybrid type DLPM, the static thrust and the normal force is shown as a function of displacement, input current and air airgap length. Also the simulation values are compared with the experimental ones obtained from a hybrid type DLPM.

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Effects of Chitosan on the Normal and Cyclophosphamide-suppressed Primary Humoral Immune Response in Mice (Chitosan이 마우스의 정상 및 cyclophosphamide로 억제된 일차 체액성 면역반응에 미치는 영향)

  • 표명윤;곽영희
    • YAKHAK HOEJI
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    • v.46 no.2
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    • pp.120-123
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    • 2002
  • In order to investigate the effects of chitosan on the normal and cyclophosphamide (CY)-suppressed primary humoral immune response in mice, chitosan was orally administered alone (single dose of 62.5, 250 mg/kg) or with CY (20 mg/kg, i.p.) to female ICR mice on the 2nd day before or after immunization with SRBC-antigen. When chitosan alone was administered before antigenic challenge, splenic IgM plaque forming cells (PFC) and splenic cellularity were slightly increased and serum IgM was not changed when compared with control group. However, chitosan significantly enhanced PFC, serum IgM and splenic cellularity when administered after antigenic challenge. The PFC numbers, serum IgM and splenic cellularity were significantly decreased by the treatment of CY, whereas those values were slightly increased by the concomitant treament of CY and chitosan when compared with CY alone-administration. These results indicate that chitosan is able to increase normal humoral immunity (HI) and to slightly inhibit the suppressive effects of CY on HI.

Developing Noninformative Priors for the Common Mean of Several Normal Populations

  • Kim, Yeong-Hwa;Sohn, Eun-Seon
    • Journal of the Korean Data and Information Science Society
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    • v.15 no.1
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    • pp.59-74
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    • 2004
  • The paper considers the Bayesian interval estimation for the common mean of several normal populations. A Bayesian procedure is proposed based on the idea of matching asymptotically the coverage probabilities of Bayesian credible intervals with their frequentist counterparts. Several frequentist procedures based on pivots and P-values are introduced and compared with Bayesian procedure through simulation study. Both simulation results demonstrate that the Bayesian procedure performs as well or better than any available frequentist procedure even from a frequentist perspective.

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Design and Analysis of Eddy-Current Braker for High-Speed Train (고속전철 와전류 제동장치 설계와 특성해석 및 실험)

  • 정수진;강도현;김동희
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.51 no.12
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    • pp.659-663
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    • 2002
  • The brake systems of high-speed train are to be equipped with three different brake systems, such as regenerative brake with regenerative feedback in driving car, a pneumatic disc brake, and non-contact linear eddy-current brake(ECB). The regenerative brake and the pneumatic disc brake are acting on the wheels. Their achievable braking force depends on the adhesive coefficient, which is influenced by the weather condition and speed, between the wheel and The linear eddy current brake gets an economical solution in the high-speed train because of the independence of the adhesive coefficient, no maintenance needed. and the good control characteristics. The braking force and the normal force of ECB for korean high-speed train are analysed by the 2D FEM(Finite Element Method). Finally the normal force is compared with the experiential values to verify the analysis.