• 한국광학회지
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• 제11권1호
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• pp.25-32
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• 2000

순수 N-(4-nitrophenyl)-(L)-prolinol (NPP)와 NPP를 곁가지로 갖는 poly(methyl metharcrylate) (PMMA) 및 poly(p-phenlene terephthalates) (PPT) 고분자계의 제 1차 초편극도 $\beta$를 전기장 인가 제 2고조파 발생(EFISHG)방법과 hyper-Rayleigh 산란(HRS) 방법으로 측정하여 비교하였다. 1,1,2,2,-tetrachloroethane 용액속의 순수 NPP와 NPP-PMMA 경우, 두 방법으로 구한 $\beta$측정값은 실험오차 이내에서 유사하였다. 그러나 1,1,2,2,-tetrachloroethane 용액속의 HNPP-PPT 고분자 경우 $\beta$측정 결과는 순수 NPP에 비하여 EFISHG에서는 9.7배 증대되고 HRS에서는 2.4배 증대되었다. 이 결과는 견고한 고분자 주사슬에 비선형 광 발색단을 곁가지로 갖는 고분자계에서는 직류 전기장속에서 발색단들이 고분자 2차 비선형 특성에 상호 보강적으로 기여하여 극성 고분자 사슬에서와 같이 증대된 것으로 해석하였다.

• 공업화학
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• 제9권5호
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• pp.704-709
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• 1998

${\alpha}$-Methyl styrene과 maleic anhydride를 공단량체로 사용하여 유리전이온도가 높고 내열성이 우수한 poly (${\alpha}$-methylstyrene-co-maleic anhydride) (MSMA) 기재 고분자 (substrate polymer)를 합성하고 여기에 니트로기를 가진 발색단을 고분자반응을 이용하여 도입하는 반응 및 생성된 비선형 광학 고분자의 전기 광학 특성에 대해 조사하였다. MSMA 기재 고분자에 hydroxyl기를 가지는 azo계 발색단 (chromophore) 2-[4-(4-nitrophenylazo)-N-ethylphenylamino]ethanol (DR1)을 고분자 반응 (polymer reaction)으로 maleic anhydride에 ester 결합으로 도입할 때 4-dimethylaminopyridine (DMAP) 촉매만을 쓴 것 (MSMA-D)보다 DMAP와 3-dicyclohexyl carbodiimid (DCC)를 동시에 사용한 경우 (MSMA-DC)가 DR1 발색단의 도입율이 높게 나타났다. 비선형 광학 고분자 (MSMA-DC)의 전기광학계수 ($r_{33}$)는 파장이 632.8 nm인 광원에서 18 pm/V의 값을 나타냈으며 열적 안정성도 유리전이 온도 ($T_g$)가 $175^{\circ}C$ 이상으로 우수하게 나타났다.

• 한국광학회:학술대회논문집
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• 한국광학회 2003년도 하계학술발표회
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• pp.168-169
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• 2003

We have determined the orientational distribution functions (OBFs) at both air and substrate isotropic interfaces of a chiral chitosan bio-polymer film by the measurements of surface second-harmonic generation (SHG). It was shown that the simultaneous SHG analysis of both interfaces, based on the macroscopic and microscopic relations, provides all the informations on the nonlinear optical (NLO) activity. (omitted)

• Journal of the Optical Society of Korea
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• 제3권2호
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• pp.47-50
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• 1999

Nonlinear optical properties of an unsaturated polymer (poly trifluroethy dipropargy malonate) are investigated by using a passive Q-switched Nd:YAG laser. Double-peaked structure of phase conjugate signals due to the two-photon-absorption induced thermal effect is clearly is clearly observed and a simple method to remove the thermal effect from the overall phase-conjugate signals is demonstrated.

• 한국광학회:학술대회논문집
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• 한국광학회 2001년도 제12회 정기총회 및 01년도 동계학술발표회
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• pp.228-229
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• 2001

Electroluminescent polymers have attracted considerable attention due to possible applications as large-area light-emitting displays. There have been many efforts to improve the electroluminescent efficiency. To design the polymer with high efficiency, it is necessary to understand the luminescent mechanism. In this report, we have investigated two-photon absorption(2PA) characteristics of highly efficient electroluminescent polymer using various techniques such as nonlinear transmission, 2PA-induced photoluminescence(2PA-PL) and 2PA-induced photoconductivity(2PA-PC). (omitted)

• Bulletin of the Korean Chemical Society
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• 제31권6호
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• pp.1509-1514
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• 2010

Methyl 3,4-di-(2'-hydroxyethoxy)benzylidenecyanoacetate (3) was prepared and condensed with terephthaloyl chloride to yield novel Y-type polyester (4) containing 3,4-dioxybenzylidenecyanoacetate groups as NLO-chromophores, which constituted parts of the polymer main chains. The resulting polymer 4 is soluble in common organic solvents such as acetone and N,N-dimethylformamide. Polymer 4 shows thermal stability up to $280^{\circ}C$ in thermogravimetric analysis with glass-transition temperature obtained from differential scanning calorimetry near $105^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer films at the 1064 nm fundamental wavelength is around 2.42 pm/V. The dipole alignment exhibits high thermal stability up to near $T_g$, and there is no SHG decay below $100^{\circ}C$ due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.

• Bulletin of the Korean Chemical Society
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• 제30권5호
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• pp.1080-1084
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• 2009

Methyl 2,4-di-(2'-hydroxyethoxy)benzylidenecyanoacetate (3) was prepared and polymerized with terephthaloyl chloride to yield a novel Y-type polyester 4 containing 2,4-dioxybenzylidenecyanoacetate groups as NLOchromophores, which constituted parts of the polymer backbone. The resulting polymer 4 is soluble in common organic solvents such as acetone and N,N-dimethylformamide. Polymer 4 showed thermal stability up to 280 ${^{\circ}C}$ in thermogravimetric analysis with glass-transition temperature obtained from differential scanning calorimetry near 108 ${^{\circ}C}$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer films at the 1064 nm fundamental wavelength was around $3.54\;{\time}\;10^{-9}$ esu. The dipole alignment exhibited a thermal stability up to near $T_g$ and no significant SHG decay was observed below 100 ${^{\circ}C}$ due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.

• Macromolecular Research
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• 제12권5호
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• pp.484-489
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• 2004

We have prepared a phenothiazine-based nonlinear optical (NLO) chromophore that displays a fairly high microscopic nonlinearity through intramolecular charge transfer. The phenothiazine unit plays important roles of contributing its high electron donating ability and connecting the resonance pathway through a conjugative effect in the cyclized ring adjacent to the aromatic ring. Theoretical calculations and an absorption spectroscopic study provided useful information concerning the microscopic nonlinearity of the chromophores. We investigated the electro-optic (EO) properties of the guest-host systems in amorphous polycarbonate containing the synthesized chromophores at different concentrations under different poling temperatures. A real-time pole and probe method provided a much greater amount of information regarding how the EO properties can arise and how they can be optimized.

• Macromolecular Research
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• 제16권8호
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• pp.741-744
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• 2008

• 한국광학회지
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• 제10권3호
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• pp.188-194
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• 1999

Mitsunobu 반응을 이용하여 전기광학계수 $\gamma_{33}$크고 열적 .시간적으로 안정적인 폴리이미드(polyimide)계고분자 용액인 PI-SOT(폴리이미드계 4-[N,N-bis(hydroxyethyl)amino­4'­($\beta$­cyano-$\beta$­methylsulfonyl)vinyl]azobenzene)고분자를 합성하였다. C.C. Teng의 단순반사법을 이용하여 코로나 폴링으로 극성 배향시킨 PI-SOT 박막의 전기광학계수 $\gamma_{33}$의 열안정성 및 시간안정성을 파장 632.8 nm와 852nm에서 측정하였다. 그 결과 상온에서 전기광학계수$\gamma_{33}$은 파장 632.8nm서 25.12 pm/V이고, 852 nmsns 5.40pm/V였다. 이 값들은 상온에서 60일 이상 장기간 안정적으로 유지되었으며, $100^{\circ}C$의 고온에서도 10시간내에서 6% 이내로 안정된 값을 유지하였다.