• Bulletin of the Korean Chemical Society
• /
• v.23 no.1
• /
• pp.98-102
• /
• 2002

The structure of a single crystal, grown by a slow cooling a melt of $Ca_{1.29}Bi_{0.14}VO_4$ composition, was analyzed. The crystals belong to the rhombohedral space group R3c and the dimensions of the unit cells are a = 10.848(1)${\AA}$, c = 38.048(6)${\AA}$, V = 3877.6(8)${\AA}^3$ for the pale yellow crystal, and a = 10.857(1), c = 38.063(6)${\AA}$, V = 3885.6(8)${\AA}^3$ for the yellow crystal, respectively. Unit cell dimensions of the crystal were larger than those of the host crystal, $Ca_3(VO_4)_2$, owing to the Bi that replaced Ca in the unit cell. Ca in the unit cell formed six, eight and nine coordinated polyhedra with O atoms and Bi replacing Ca entered the eight or nine coordinated Ca sites with different crystallographic environments in the unit cell. All the V in the unit cell formed four coordinated tetrahedra with O atoms, however V-O bond lengths in the tetrahedra were different from one another.

• Journal of the Optical Society of Korea
• /
• v.3 no.2
• /
• pp.41-46
• /
• 1999

Spatial and temporal dynamics arising in a photorefractive crystal(BaTiO3) during the process of double phase conjugation was studied experimentally. We studied the dynamical effects caused by the buildup of the diffraction grating and turn on of phase conjugated beams, as well as the spatial effects caused by the finite transverse coupling of beams and the propagation direction of beams. We observed conical emission in DPCM. We believe that various temporal and spatial instabilities are due to movement of the nonlinear grating. For a real beam coupling and constructive interaction of interference fringes in the crystal, we observed steady, periodic, irregular temporal behavior. And, by the calculation of the correlation index, we found that the spatial correlation decreased as the transverse interaction region was increased.

• Proceedings of the Korea Crystallographic Association Conference
• /
• 2002.11a
• /
• pp.18-18
• /
• 2002

Although it was suggested in 1962 that an efficient wavelength conversion could be achieved using ferroelectric crystals of periodic 180° domains, it was not until 1990's that quasi-phase-matching (QPM) became realized, as technology for periodic poling of LiNbO₃ crystals was readily available. Since ferroelectric domain inversion brings about change of the sign of second-order nonlinear susceptibility, periodically poled ferroelectric structures provide an ideal way of achieving QPM for second-harmonic generation and optical parametric oscillation. Periodically poled ferroelectric domains can also be utilized for optical devices, such as Brags electrooptic modulators. fabrication of stable periodic domain structures depends on a number of poling parameters of a ferroelectric crystal, such as coercive field, internal field and electrical conductivity. We present poling kinetics of KNbO₃ crystals, which involve domain nucleation and growth, backswitching, relaxation of internal field. Optimum poling conditions were established by designing a proper wave shape of external field. We demonstrate an efficient second-harmonic generation using QPM in a periodically poled KNbO₃ crystal.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.7 no.3
• /
• pp.384-392
• /
• 1997

Potassium lithium niobate(KLN) single crystal for a nonlinear-optic material, which changes the wavelength of lasers, has a ferroelectric tetragonal tungsten bronze structure at room temperature. It has been very hard to get single crystals of good quality due to the cracks during cooling process. In order to investigate the composition change due to the evaporation of solution during the growth, the thermogravimetric analysis was carried out. In atmospheric condition at $1000^{\circ}C$ which is about $10^{\circ}C$ higher than the crystal growing temperature, the weight change was negligible amount of $1.46{\times}10^{-5}$g/($\textrm{cm}^2$hr). By using both the Pt plate as the nucleation site and the slow cooling method with temperature fluctuation, KLN single crystal of good quality of size 1 cm could be obtained. The phase transition temperature was $490^{\circ}C$, which was higher than that reported by other researchers of the other composition. The optical anisotropy due to the absorption of OH-band exists in the range of IR.

• Journal of the Korean Ceramic Society
• /
• v.35 no.5
• /
• pp.493-498
• /
• 1998

ZnS doped borosilicate glass for nonlinear optical application was prepared by melting and precipitation process. The optical band gap of the precipitated ZnS particles ranged from 3.83 to 3.96 eV compared with the bulk ZnS energy gap of 3.53 eV. This result was interpreted in terms of a quantum confinement effect due to small crystal size. ZnS partilcle size estimated by effective mass approximation ranged from about 39 to 83 $\AA$ It increased wtih the increase of heat tratment time and temperature.

• Korean Journal of Optics and Photonics
• /
• v.18 no.1
• /
• pp.14-18
• /
• 2007

Photonic crystal fibers(PCFs) with silica cores within an away of air holes have unique properties. Broad band single-mode and the octave-spanning supercontinuum generation, impossible to achieve in classical fibers, can be realized. The design of PCFs is very flexible. There are two parameters to manipulate: air hole diameter, and lattice pitch. We introduced a fabrication process for control of the parameters to obtain endlessly single mode PCF, which is single mode in a large wavelength range, and highly nonlinear PCF. The numerical analysis and experiments are included.

• Journal of the Optical Society of Korea
• /
• v.3 no.1
• /
• pp.15-19
• /
• 1999

The formation of spontaneous transverse optical patterns was investigated in a single feedback mirror system using nematic liquid crystals as nonlinear optical media. By varying the size of an input beam and the feedback distance, we obtained various interesting transverse optical patterns as well as the hexagonal pattern which are predicted theoretically assuming plane wave input. We can explain theoretically these characteristics of various pattern by introducing a ratio of the beam half width and spatial wavelength of the patterns. We have observed that as this ratio increased, the number of spot constituting the patterns also increased. Finally the patte군 evolved into the sucessive hexagon in the transverse plane.

• Korean Journal of Optics and Photonics
• /
• v.16 no.6
• /
• pp.490-493
• /
• 2005

We have experimentally studied supercontinuum generation in a photonic crystal fiber as a function of pump wavelength and intensity with 100 fs pulsewidth. A supercontinuum over 750 nm spectral width with amplitude variation less than 10 dB has been achieved. It was generated by coupling femtosecond pulses from a mode-locked Ti:Sapphire laser into a 2 m long photonic crystal fiber. Adjusting the parameters of the pump source, it was also possible to control different spectral features of the supercontinuum radiation.

• Korean Journal of Optics and Photonics
• /
• v.13 no.5
• /
• pp.400-407
• /
• 2002

Two dimensional solitary waves are stably propagated in a saturable medium which has a saturable nonlinear index as input intensity. However, in the case of low intensity. a negative fifth-order nonlinear medium has properties of a saturable medium. So a Gaussian beam travels stably. The propagation process into the fifth order nonlinear medium of the Gaussian beam with a weak intensity is investigated by using the computer simulation of the two-dimensional nonlinear Schrodinger equation. As a result, it is confirmed that the two-dimensional spatial solitary waves are stably propagated in this medium when the incident powers are self-trapping powers. In the condition of the phase difference and collisional angle between two input beams of 180 degree and 0.05 degree, respectively, we can confirm that all optical switching is as simple as controlling the incident power of one input beam.

• Korean Journal of Optics and Photonics
• /
• v.9 no.2
• /
• pp.76-85
• /
• 1998

Organic single crystal of p-toluene sulfonate(PTS) bulks and thin films were fabricated using a slow solution evaporation method. Third and fifth order nonlinear refractive indices, $n_2$and $n_3$, of PTS crystals at 1600 nm were determined by the Z-scan method and the multimode output of the PTS thin film waveguide was observed at 1350 nm. When the beam intensity is in 2-5 GW/$cm^2$, the nonlinear refractive indices are $n_{2}=6{\times}10^{-4}cm^{2}$/GW and $n_{3}=-7{\times}10^{-5}cm^{4}/GW^{2}$ and the two and three photon absorption coefficients are zero. When the beam intensity is in 5~16 GW/$cm^2$, the split-step fast Fourier transform beam propagation method simulation shows that the beam propagation in the PTS is distorted from the gaussian shape.