• Title/Summary/Keyword: Non-structure

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Degradation of the Pd catalytic layer electrolyte in dye sensitized solar cells (염료감응태양전지에서 Pd 촉매층의 전해질과의 반응에 따른 특성 저하)

  • Noh, Yunyoung;Song, Ohsung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.4
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    • pp.2037-2042
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    • 2013
  • A TCO-less palladium (Pd) catalytic layer on the glass substrate was assessed as the counter electrode (CE) in a dye sensitized solar cell (DSSC) to confirm the stability of Pd with the $I^-/I_3{^-}$electrolyte on the DSSC performance. A 90nm-thick Pd film was deposited by a thermal evaporator. Finally, DSSC devices of $0.45cm^2$ with glass/FTO/blocking layer/$TiO_2$/dye/electrolyte(10 mM LiI + 1 mM $I_2$ + 0.1 M $LiClO_4$ in acetonitrile solution)/Pd/glass structure was prepared. We investigated the microstructure and photovoltaic property at 1 and 12 hours after the sample preparation. The optical microscopy, field emission scanning electron microscopy (FESEM), cyclic voltammetry measurement (C-V), and current voltage (I-V) were employed to measure the microstructure and photovoltaic property evolution. Microstructure analysis showed that the corrosion by reaction between the Pd layer and the electrolyte occurred as time went by, which led the decrease of the catalytic activity and the efficiency. I-V result revealed that the energy conversion efficiency after 1 and 12 hours was 0.34% and 0.15%, respectively. Our results implied that we might employ the other non-$I^-/I_3{^-}$electrolyte or the other catalytic metal layers to guarantee the long term stability of the DSSC devices.

Experimental Study of Small Vertical Axis Wind Turbine according to Type of Blades (블레이드 형태에 따른 소형 수직축 풍력발전기의 실험적 연구)

  • Lee, Min-Gu;Oh, Hun;Park, Wal-Seo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.12
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    • pp.88-92
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    • 2017
  • Owing to the depletion of fossil energy, wind power is attracting attention as a promising environmentally friendly alternative energy source, because it is abundant, renewable, and non-polluting. Wind turbines are divided into horizontal axis wind turbines (HAWTs) and vertical axis wind turbines (VAWTs) according to the direction of the rotating shaft. VAWTs have a low power generation efficiency, but are not affected by the wind direction and, thus, no yaw system is required and their structure is simple. Small VAWTs are attracting much attention because they can generate power even at low wind speeds. In this study, the output voltages and output currents of small VAWTs with gyromill type, hinge type and double door type blades capable of generating power even at low wind speeds were analyzed at variable wind speeds in the range of 1~11 m/s. At the maximum wind speed of 11m/s, the application of the double door type blades achieved 67% and 9% higher wind turbine output voltages than that of the gyromill type and hinge type blades, respectively. As regards the wind turbine output currents, the application of the double door type blades gave rise to 93% and 5% higher results than that of the gyromill type and hinge type blades, respectively. Through this study, the excellent output characteristics and commercialization potential of the double door type blades, which can generate power both at low and high wind speeds, were confirmed.

The Implication of Bandura's Vicarious Reinforcement in Observational Learning for Christian Education (관찰학습에서의 반두라 대리강화에 대한 기독교교육적 함의)

  • Lee, Jongmin
    • Journal of Christian Education in Korea
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    • v.61
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    • pp.81-107
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    • 2020
  • This study reviews Bandura's vicarious reinforcement in observational learning process and implies this concept into Christian education in terms of spiritual role modeling. The first part of this study answers three questions: "what is vicarious reinforcement?" "how does vicarious reinforcement take place in observational learning?" and "how does vicarious reinforcement affect observer's behavior change?" Bandura conceptualizes the learning process with observational learning and imitative or non-imitative performance. Based on this concept, Bandura define the roles of vicarious reinforcement in the four steps of observational learning process: attention, retention, motor reproduction, and motivational process. Also, the three effects of vicarious reinforcements are explained in the following categories: the observational learning effect, inhibitory or disinhibitory effects, and eliciting effect. Adapting the structure of observational learning theory in terms of the effect of vicarious reinforcement and the function of role models, the second part of this study examines the biblical concept of imitation of Christ and the modeling strategy of discipleship. Especially Paul's spiritual role model serves as positive vicarious reinforcement for the Christian believers to perform the desired behaviors. Also, Paul's condemnation serves as explicit negative vicarious reinforcement. Then, the last part of this study covers the implication of these findings from observational learning and empirical studies in terms of spiritual role modeling to Christian education.

A Study on Preparation of Colloidal Gas Aphrons and Stability (Colloidal Gas Aphrons의 제조와 안정성에 대한 연구)

  • Yoon, Mi-Hae;Cho, Dae-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.6
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    • pp.670-677
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    • 2007
  • The stability of CGAs(colloidal gas aphrons) prepared from non-ionic and ionic surfactants was investigated. Those surfactants were sodium dodecyl sulfate(SDS), Triton X-100, Tween 80 and Quillaja Saponin. The stability of CGAs prepared from single surfactants or mixed surfactants(two components) using a CGA generate. was investigated as functions of temperature, surfactant concentration and stirring time. Saponin among the single surfactants has shown the longest duration time(143 min) and then, Triton X-100, SDS, and Tween 80 were followed by at room temperature. In case of CGAs heated up to $70^{\circ}C$, SDS endured for 116 min but Saponin lasted for only 105 mit which was a considerable reduction of the duration time of CGAs at room temperature. For mixed surfactant pairs, stability of any one pairs stood between the two. That meant no synergic effect for surfactant blending. At the higher temperature, Saponin+Triton X-100 was disclosed to be the lowest, 53 min meanwhile Saponin+SDS was the highest at ambient temperature. The CGAs, initially about 140 ${\mu}m$ in diameter, began to grow right after the agitation to be about 190 ${\mu}m$ owing to coalescence of the bubbles and then became to collapse. When heated, CGAs including Saponin tended to be smaller while the others to be larger. In summary, we found that the stability of CGAs or the duration time was greater for single surfactants and at room temperature rather than for mixed surfactants that caused substantial intermolecular interactions in the CGA structure and at the higher temperature.

A Basic Study on the Differential Diagnostic System of Laryngeal Diseases using Hierarchical Neural Networks (다단계 신경회로망을 이용한 후두질환 감별진단 시스템의 개발)

  • 전계록;김기련;권순복;예수영;이승진;왕수건
    • Journal of Biomedical Engineering Research
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    • v.23 no.3
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    • pp.197-205
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    • 2002
  • The objectives of this Paper is to implement a diagnostic classifier of differential laryngeal diseases from acoustic signals acquired in a noisy room. For this Purpose, the voice signals of the vowel /a/ were collected from Patients in a soundproof chamber and got mixed with noise. Then, the acoustic Parameters were analyzed, and hierarchical neural networks were applied to the data classification. The classifier had a structure of five-step hierarchical neural networks. The first neural network classified the group into normal and benign or malign laryngeal disease cases. The second network classified the group into normal or benign laryngeal disease cases The following network distinguished polyp. nodule. Palsy from the benign laryngeal cases. Glottic cancer cases were discriminated into T1, T2. T3, T4 by the fourth and fifth networks All the neural networks were based on multilayer perceptron model which classified non-linear Patterns effectively and learned by an error back-propagation algorithm. We chose some acoustic Parameters for classification by investigating the distribution of laryngeal diseases and Pilot classification results of those Parameters derived from MDVP. The classifier was tested by using the chosen parameters to find the optimum ones. Then the networks were improved by including such Pre-Processing steps as linear and z-score transformation. Results showed that 90% of T1, 100% of T2-4 were correctly distinguished. On the other hand. 88.23% of vocal Polyps, 100% of normal cases. vocal nodules. and vocal cord Paralysis were classified from the data collected in a noisy room.

Development and Evaluation of Natural Hydroxyapatite Ceramics Produced by the Heat Treatment of Pig Bones

  • Lim, Ki-Taek;Kim, Jin-Woo;Kim, Jangho;Chung, Jong Hoon
    • Journal of Biosystems Engineering
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    • v.39 no.3
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    • pp.227-234
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    • 2014
  • Purpose: The aim of this research was to develop and evaluate natural hydroxyapatite (HA) ceramics produced from the heat treatment of pig bones. Methods: The properties of natural HA ceramics produced from pig bones were assessed in two parts. Firstly, the raw materials were characterized. A temperature of $1,200^{\circ}C$ was chosen as the calcination temperature. Fine bone powders (BPs) were produced via calcinations and a milling process. Sintered BPs were then characterized using field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), energy dispersive X-ray spectroscopy (EDX), Fourier transform infrared (FTIR) spectroscopy, and a 2-year in vitro degradability test. Secondly, an indirect cytotoxicity test was conducted on human osteoblast-like cells, MG63, treated with the BPs. Results: The average particle size of the BPs was $20{\pm}5{\mu}m$. FE-SEM showed a non-uniform distribution of the particle size. The phase obtained from XRD analysis confirmed the structure of HA. Elemental analysis using XRF detected phosphorus (P) and calcium (Ca) with the Ca/P ratio of 1.6. Functional groups examined by FTIR detected phosphate ($PO{_4}^{3-}$), hydroxyl ($OH^-$), and carbonate ($CO{_3}^{2-}$). The EDX, XRF, and FTIR analysis of BPs indicated the absence of organic compounds, which were completely removed after annealing at $1,200^{\circ}C$. The BPs were mostly stable in a simulated body fluid (SBF) solution for 2 years. An indirect cytotoxicity test on natural HA ceramics showed no threat to the cells. Conclusions: In conclusion, the sintering temperature of $1,200^{\circ}C$ affected the microstructure, phase, and biological characteristics of natural HA ceramics consisting of calcium phosphate. The Ca-P-based natural ceramics are bioactive materials with good biocompatibility; our results indicate that the prepared HA ceramics have great potential for agricultural and biological applications.

Comparative Molecular Field Analyses on the Fungicidal Activities of N-phenylthionocarbamate Derivatives based on Different Alignment Approaches (상이한 정렬에 따른 N-phenylthionocarbamate 유도체들의 살균활성에 관한 비교 분자장 분석)

  • Sung, Nack-Do;Soung, Min-Gyu;You, Jae-Won;Jang, Seok-Chan
    • The Korean Journal of Pesticide Science
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    • v.10 no.3
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    • pp.157-164
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    • 2006
  • Three dimensional quantitative structure-activity relationships (3D-QSARs) for the fungicidal activities against Rhizoctonia solani (RS) and Phytophthora capsici (PC) by N-phenyl substituents(X) of N-phenylthionocarbamate derivatives were studied quantitatively using comparative molecular field analysis (CoMFA) methodology based on different alignment approaches. Statistical quality of CoMFA models with field fit alignment were slightly higher than that of atom based fit alignment. The optimized CoMFA models (RS: RF2 & PC: PF2) were derived from field fit alignment and combination of CoMFA fields. And the statistical results of the two models showed the best predictability of the fungicidal activities based on the cross-validated value $q^2$ ($r^2_{cv.}$ =RS: 0.557 & PC: 0.676) and non-cross-validated value ($r^2_{ncv.}$ =RS: 0.954 & PC: 0.968), respectively. The selective fungicidal activities between two fungi were dependence upon the electrostatic field of substrate molecule. Therefore, the fungicidal activities from CoMFA contour maps showed that the fungicidal activity will be able to increased according to the modification of X-substituents on the substrate molecules.

A Study on Elasto-Plastic Behavior of Column-to-Beam Welded Connection with 600MPa Class High Performance Steel (600MPa급(SM 570 TMC) 고성능강 기둥-보 용접접합부의 탄소성 거동에 관한 연구)

  • Kim, Jong Rak;Oh, Young Suk;Baek, Ki Youl;Chang, Sung Yun
    • Journal of Korean Society of Steel Construction
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    • v.20 no.6
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    • pp.783-792
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    • 2008
  • While the recent high demand for mega-tall buildings has led to the development of high-performance and high-strength steels, the requirements for architectural-structure-performance steel have been raised as engineers recognize the potential damage that an earthquake can wreak on a tall building. A 600MPa-class steel has emerged to meet such need, and many studies are currently exploring its practical applications on civil engineering works and mega-tall buildings. The available data on the horizontal-force behaviors of structures built with such new steel, however, are still insufficient. There is an urgent need to look into its design data, especially its toughness, and to compare the plastic strain ratios of column-to-beam connections using high-strength steel and regular steel. One of the first studies on the behavior of a column-to-beam connection using 600MPa-class steel (SM570 TMC), this thesis analyzes such steel's structural performance by conducting a structural test on seismic resistance on a full-scale column-to-beam welded connection with non-scallop and recommended-scallop details. Compared with the previous studies on SM490, this thesis evaluates the weldability of SM570 TMC and presents the latter's seismic design data for use in testing its practical application.

E-cadherin Expression in Colonic Epithelium of Various Colitis in Children (소아에서 발생한 대장의 염증성 질환에서 E-cadherin의 발현)

  • Lee, Na-Young;Park, Do-Youn;Park, Jae-Hong
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.12 no.2
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    • pp.177-182
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    • 2009
  • Purpose: Colitis is a condition associated with a spectrum of altered morphologic changes and cellular adhesion. E-cadherin plays a key role in the establishment and maintenance of epithelial tissue structure and cell-cell adhesion. The purpose of this study is to evaluate E-cadherin expression in colonic epithelium of various colitis in children. Methods: The expressions of E-cadherin were examined in 39 cases of colonic mucosal biopsy specimen using immunohistochemical staining. When more than 50 percent of cells exhibited uniformly the same intensity and pattern of immunostaining as the adjacent normal mucosa, the antigen expression was considered normal. Abnormal expression was defined when less than 50 percent of cells stained, when cells showed a heterogeneously weak or altered distribution, or when complete absence of staining was observed. Results: Fifteen cases with non-specific colitis (38.5%), 7 cases of with Crohn's disease (17.9%), 5 cases of infectious colitis and milk protein sensitive proctocolitis (12.8%), 3 cases of ulcerative colitis (7.7%), 2 cases of Henoch-Schonlein purpura colitis (5.1%), one case of Behcet's disease and ischemic colitis (2.6%) were included in this study. E-cadherin expression was decreased in all kinds of colitis. Reduced expression of E-cadherin was observed in 77 percent of cases. E-cadherin was weaker or no expression in reparative epithelium and "ulcer associated cell lineage". Conclusion: Altered expression of E-cadherin occurs during mucosal inflammation in any kinds of colitis. These changes may be involved in promoting cell migration during epithelial restitution of the gastrointestinal mucosa.

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Development of Portable X-ray CT System II - CT Image Reconstruction of Wood using Density Distribution - (현장 적용이 가능한 X선 CT 시스템 개발 II- 밀도분포를 이용한 목재의 CT영상 구성 -)

  • Kim, Kwang-Mo;Lee, Sang-Joon;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.1
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    • pp.23-31
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    • 2006
  • X-ray transit materials with straight path and the its intensity is proportional to the density of materials. Therefore, X-ray has been extensively used as a nondestructive evaluation (NDE) method in various fields. This study was carried out for development of a portable X-ray CT (computed-tomography) system to detect deteriorations of wood members in buildings. Based on the results of our previous study, a procedure of CT image reconstruction was established In order to verify the applicability of developed system, CT images of three wood disks were reconstructed by newly developed procedure and compared with the prototypes. From the results of this study, it was shown that the newly developed system could be used not only to determine the shape, size, and position of defects, but also to find the density distribution in cross section of wood structure members. The density distribution may be utilized to clarify the reason of wood deterioration and to provide the preventive method on how to treat or repair wood buildings. Because it was initial stage of system development, there were some limitations concerned with measuring equipment and image reconstruction algorithm. Especially, measuring time including equipment setup time was longer and measuring accuracy was lower than we expected. Therefore, we planned some additional studies on improvement of equipment and algorithm to enhance the capability of X-ray CT system.