• Title/Summary/Keyword: Non-solvent

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The Optimum Cleaning Process of Non-aqueous Alternative Solvents for 1,1,1-TCE (1,1,1-TCE에 대한 비수계성 대체세정제의 최적 세정공정)

  • Jung, Duck-Chae;Lee, Ki-Chang;Kong, Seung-Dae;Mok, Gab-Young;Lee, Seok-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.3
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    • pp.237-240
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    • 1999
  • This study showed that the optimized cleaning process using non-aqueous cleaning solvents is adaptable in the industrial field for existing 1.1.1-TCE cleaning solvents which is an ozone depleting sustance. Alternative cleaning solvent system substituted for existing cleaning solvent against non-aqueous pollutants(cutting & flux oil), was evaluated for the cleaning efficiency using gravimetric analysis method and surface change of sample by Image analyzer. The results showed that alternative solvents and process had excellent cleaning efficiency.

THE INVESTIGATION FOR THE EFFECT 01 THE SOLUBILITY PARAMETER BETWEEN OIL BINDER AND SOLVENT TO THE PRODUCT QUALITY IN THE WET TYPE BACK INJECTION PRESS PROCESS.

  • Y, Tae-Young;K, Jong-Kuy;L, Joo-Wan
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.105-110
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    • 1998
  • In the make-up product, Eye-shadow products have several purposes of enhancing product quality such as providing the beauty (variation of shape, clean appearance), feeling, continuity and adhesion. In this paper, newly developed wet type back injection press process is introduced so as to increase higher value products which providing various the beauty. The solvent takes an essential role to provide the fluidity of the powder bulk during the pressed-process of wet type pressed product. In this study, the effect of solvent in the oil binder was investigated, And the higher quality condition of the wet type pressed product was built to apply cosmetic preparation. Firstly, the system was designed powder phase as non treated pigment. The oil binder phase is categorized as hydrocarbons(Mineral oil, Squalane), Silicones(Methicone, Dimethicone ), esters (Octyldodecanol, Octyl Dodecyl Myristate). The solvent phase used was C 7-8 isoparaffin and Isopropyl Alcohol. The interaction of oil binder and solvent is investigated by measuring mass of final oil binder and the each solubility parameter. It was found that the higher the solubility the higher the degree of change in the final composition of the oil binder. In order to maintain the quality of the final product, the solvent used in pressed-process should be hydrophobic with oil binder.

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The Influence of Dielectric Constant on Ionic and Non-polar Interactions

  • Hwang, Kae-Jung;Nam, Ky-Youb;Kim, Jung-Sup;Cho, Kwang-Hwi;Kong, Seong-Gon;No, Kyoung-Tai
    • Bulletin of the Korean Chemical Society
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    • v.24 no.1
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    • pp.55-59
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    • 2003
  • This work is focused on analyzing ion-pair interactions and showing the effect of solvent induced inter-atomic attractions in various dielectric environments. To estimate the stability of ion-pairs, SCI-PCM ab initio MO calculations were carried out. We show that the solvent-induced attraction or ‘cavitation' energy of the ion-pair interactions in solution that arises mainly from the stabilization of the water molecules by the generation of an electrostatic field. In fact, even the strong electrostatic interaction characteristic of ion-pair interactions in the gas phase cannot overcome the destabilization or reorganization of the water molecules around solute cavities that arise from cancellation of the electrostatic field. The solvent environment, possibly supplemented by some specific solvent molecules, may help place the solute molecule in a cavity whose surroundings are characterized by an infinite polarizable dielectric medium. This behavior suggests that hydrophobic residues at a protein surface could easily contact the side chains of other nearby residues through the solvent environment, instead of by direct intra-molecular interactions.

Composite copper powder from Kelex 100 (Kelex100로부터 구리입자 분말 합성)

  • ;P.R Taylor
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.131-137
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    • 1998
  • A composite copper coated powder was generated by pressure hydrogen stripping copper from Kelex 100 solvent extractant in the presence of silica powder. Within the limitation of solvent extraction under constant conditions, both loading level and stripping rate were reproducible. The stripping copper kinetics are reduced from a divalent state to a metallic state and then deposited on the surface of the silica powder. Copper nucleates heterogeneously on the seed particles. They are giving an agglomerated and non - uniform powder.

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Effect of Solvent Extraction on the Anti-complementary Activities of Green and Ripe Cucurbita moschata Duch

  • Yang, Jin-Ok;Kim, Chang-Jin;Song, Kyung-Bin
    • Preventive Nutrition and Food Science
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    • v.6 no.2
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    • pp.133-135
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    • 2001
  • The edible part of cucurbita moschata Duch, which is commonly used as a Korean traditional medicine as well as a popular food source, was studied to isolate anti-complementary substance. Extracts of Cucurbita moschata Duch showed significant anti-complementary activities on the classical pathway of the complement system. Especially, the ripe Cucurbita moschata Duch had more activity than that of the complement system. Especially, the ripe Cucurbita moschata Duch had more activity than that of the green one in terms of the overall anti-complementary activity. Among the extracts of various organic solvents of the ripe Cucurbita moschata Duch, chloroform and ethyl-acetate extracts, which are non-polar solvent extracts, showed the strongest activities. These results suggest that the major difference in the solvent extraction for the anti-complementary substances depends on the change in the chemical composition such as the fatty acid with the degree of ripening.

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Dispersions of partially reduced graphene oxide in various organic solvents and polymers

  • Kim, Hye Min;Kim, Seo Gyun;Lee, Heon Sang
    • Carbon letters
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    • v.23
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    • pp.55-62
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    • 2017
  • We report on the dispersion state of partially reduced graphene oxide (PRGO) in organic solvents, namely methyl ethyl ketone, ethyl acetate, methylene chloride, toluene, and xylene, by controlling the carbon to oxygen (C/O) atomic ratio of the PRGOs. A two-phase solvent exchange method is also proposed to transfer PRGO from water to an aprotic solvent, such as methyl ethyl ketone. We achieve relatively good dispersion in aprotic and non-polar solvents by controlling the C/O atomic ratio of the PRGOs and applying the two-phase solvent exchange method. There is an increase in the glass transition temperatures with the dispersion of PRGOs into amorphous polymers, in particular a $4.4^{\circ}C$ increase for poly(methyl methacrylate) and $3.0^{\circ}C$ increase for polycarbonate. Good dispersion of PRGO in a nonpolar polymer, such as linear low density polyethylene, is also obtained.

Simultaneous Extraction and Separation of Oil and Azadirachtin from Seeds and Leaves of Azadirachta indica using Binary Solvent Extraction

  • Subramanian, Sheela;Salleh, Aiza Syuhaniz;Bachmann, Robert Thomas;Hossain, Md. Sohrab
    • Natural Product Sciences
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    • v.25 no.2
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    • pp.150-156
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    • 2019
  • Conventional extraction of oil and azadirachtin, a botanical insecticide, from Azadirachta indica involves defatting the seeds and leaves using hexane followed by azadirachtin extraction with a polar solvent. In order to simplify the process while maintaining the yield we explored a binary extraction approach using Soxhlet extraction device and hexane and ethanol as non-polar and polar solvents at various ratios and extraction times. The highest oil and azadirachtin yields were obtained at 6 h extraction time using a 50:50 solvent mixture for both neem leaves (44.7 wt%, $720mg_{Aza}/kg_{leaves}$) and seeds (53.5 wt%, $1045mg_{Aza}/kg_{leaves}$), respectively.

Fabrication of Block Copolymer Membranes via SNIPS Process (SNIPS 공정을 이용한 블록공중합체 분리막의 구조 형성에 관한 연구)

  • Woo, Sanghoon;Kim, Jinhee;Lee, Junghyun;Bang, Joona
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.214-219
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    • 2017
  • In this work, we fabricated PS-b-P4VP block copolymer membranes from self-assembly and non-solvent induced phase separation (SNIPS), which combines the block copolymer self-assembly and conventional NIPS process. While previous studies mostly focused on the fabrication of well-defined structures, we systematically examined various processing parameters such as polymer concentration, solvent evaporation duration, solvent composition, and humidity, to optimized the membrane structures. As a result, the morphology of PS-b-P4VP membranes was optimized at a certain polymer concentration in solution and composition of volatile solvent at low humidity conditions, resulting in SNIPS separation membranes with well-defined nanopores on the surface, 75% of membrane porosity, and 18% of surface porosity.

Fabrication and Characteristics of Non-Solvent Silica-Acryl Monomer Hybrid Sol for Optical Device (광학용 무용제 실리카-아크릴 모노머 하이브리드 졸 기반의 코팅액 제조 및 특성 평가)

  • Kang, Woo Kyu;Jang, Gun Eik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.3
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    • pp.246-251
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    • 2019
  • A solvent free, highly concentrated silica-acryl monomer hybrid sol was synthesized using aqueous colloidal silica as a precursor. The effects of the silica particle size, type of surface treatment agent employed, and silica content on the formation of the hybrid sol were systematically studied. The optical and physical properties of the coating solution prepared using the hybrid sol were also characterized. The viscosity of the hybrid sol tended to decrease as the particle size of the silica and the molecular weight of the surface treatment agent increased. The PET substrate coated with MPTMS-Mix (mixture, 70 wt%) solution showed the highest surface hardness (6 H) and low surface roughness ($Ra=0.044{\mu}m$), which could be attributed to an increase in packing density caused by the infiltration of small particles into the pores formed between larger particles.

Removal of Organic Pollutants from Aqueous Solution by Hollow Fiber Module (중공사모듈에 의한 수용액으로부터 유기오염물의 제거)

  • 유홍진
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.2
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    • pp.114-119
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    • 2003
  • This study is to remove several organic pollutants from wastewater by non-dispersive membrane solvent extraction technique. The distribution coefficients of several solvents were determined and the experimental system was operated counter-currently and cocurrently with respect to the aqueous phase and solvent. In these experiments, as the flow rate of aqueous solution inclosed, due to being shortened contact time to solvent, the rate of removal of organic pollutants decreased and as the flow rate of solvent increased, the rate of removal increased. Meanwhile, the rate of removal of organic pollutants for the countercurrent flow system was higher than that for the occurrent flow system.

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