• Title/Summary/Keyword: Non-mixture

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Emulsification of the Mixture of Catalytic Pyrolysis Oil Obtained under Methane and Nitrogen Environment in Diesel Using Span 80 and Atlox 4916 as Surfactants

  • Farooq, Abid;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.357-360
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    • 2021
  • Emulsions were prepared using a mixture of bio-oil obtained from the pyrolysis of sawdust in an N2 environment and Quercus mongolica in a CH4 environment for both non-catalytic and catalytic cases. Both prepared emulsions were examined by measuring the physical stability and Fourier transform infrared spectroscopy. The emulsion with HLB 5.8 (Span 80 and Atlox 4916) for the ratio of bio-oil (B-oil and C-oil): surfactant: diesel = 10% : 3% : 87% showed stability for 15 days. Combining oils produced in N2 and CH4 environments could be a potential solution for generating high-quality emulsions with a high heating value.

Control Efficacy of Sodium Bicarbonate alone and in mixture with Polyoxyethylene sorbitanmonolaurate to Powdery Mildew of Strawberry.

  • M.H. Nam;S.K. Jung;S.W. Ra;Kim, H.G.
    • Proceedings of the Korean Society of Plant Pathology Conference
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    • 2003.10a
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    • pp.87.1-87
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    • 2003
  • Powdery mildew on strawberry plants, caused by Spherotheca aphanis (Wallr.) U. Braun var. aphanis, is the most serious disease for strawberry production. There is a demand to develop the substitutes for chemicals which are more environment friendly materials. Control of powdery mildew was evaluated on Akihime, Sachinoka, Dochiodome, Noyho and Redpearl varieties grown in the greenhouse. Applications of 1%, 0.5%, and 0.25% of sodium bicarbonate (NaHCO3Nyoho in greenhouse experiments. Non-phytotoxicity was revealed on the leaves and fruits of strawberry at these concentrations. This$.$result indicates that a mixture of sodium bicarbonate and tween 20 is a useful substitute for fungicides to control powdery mildew of strawberry.

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Optimal Thresholds from Mixture Distributions (혼합분포에서 최적분류점)

  • Hong, Chong-Sun;Joo, Jae-Seon;Choi, Jin-Soo
    • The Korean Journal of Applied Statistics
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    • v.23 no.1
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    • pp.13-28
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    • 2010
  • Assuming a mixture distribution for credit evaluation studies, we discuss estimating threshold methods to minimize errors that default borrowers are predicted as non defaults or non defaults are regarded as defaults. A method by using statistical hypotheses tests, the most powerful test and generalized likelihood ratio test, for the probability density functions which are defined with the score random variable and the parameter space consisted of only two elements such as the default and non default states is proposed to estimate a threshold. And anther optimal thresholds to maximize classification accuracy measures of the accuracy and the true rate for ROC and CAP curves are estimated as equations related with these probability density functions. Three kinds of optimal thresholds in terms of the hypotheses testing, the accuracy and the true rate are obtained from normal random samples with various means and variances. The sums of the type I and type II errors corresponding to each optimal threshold are obtained and compared. Finally we discuss about their efficiency and derive conclusions.

Characterization of Heterogeneous Interaction Behaviour in Ternary Mixtures by Dielectric Analysis: The H-Bonded Binary Polar Mixture in Non-Polar Solvent

  • Sengwa, R.J.;Madhvi;Sankhla, Sonu;Sharma, Shobha
    • Bulletin of the Korean Chemical Society
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    • v.27 no.5
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    • pp.718-724
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    • 2006
  • The heterogeneous association behaviour of various concentration binary mixtures of mono alkyl ethers of ethylene glycol with ethyl alcohol were investigated by dielectric measurement in benzene solutions over the entire concentration range at 25 ${^{\circ}C}$. The values of static dielectric constant $\epsilon_0$ of the mixtures were measured at 1 MHz using a four terminal dielectric liquid test fixture and precision LCR meter. The high frequency limiting dielectric constant $\epsilon_\infty$ values were determined by measurement of refractive index $n_D$ ($\epsilon_\infty\;=\;n_D\;^2$). The measured values of $\epsilon_0$ and $\epsilon_\infty$ were used to evaluate the values of excess dielectric constant $\epsilon^E$, effective Kirkwood correlation factor $g^{eff}$ and corrective correlation factor $g_f$ of the binary polar mixtures to obtain qualitative and quantitative information about the H-bond complex formation. The non-linear behaviour of the observed $\epsilon_0$ values of the polar molecules and their mixtures in benzene solvent confirms the variation in the associated structures with change in polar mixture constituents concentration and also by dilution in non-polar solvents. Appearance of the maximum in $\epsilon^E$ values at different concentration of the polar mixtures suggest the formation of stable adduct complex, which depends on the molecular size of the mono alkyl ethers of ethylene glycol. Further, the observed $\epsilon^E$ < 0 also confirms the heterogeneous H-bond complex formation reduces the effective number of dipoles in these polar binary mixtures. In benzene solutions these polar molecules shows the maximum reduce in effective number of dipoles at 50 percent dilutions. But ethyl alcohol rich binary polar mixtures in benzene solvent show the maximum reduce in effective number of dipoles in benzene rich solutions.

AC Breakdown Voltage Simulation of SF6/N2 Mixture in Non-Uniform Field and Its Comparison with Experimental Values (불평등 전계에서 SF6/N2 혼합가스의 AC 절연파괴전압 시뮬레이션 및 실험값와의 비교)

  • Lee, Byung-Taek;Hwang, Cheong-Ho;Lee, Tae-Ho;Huh, Chang-Su;Chang, Yong-Moo;Lee, Ki-Taek
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.8
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    • pp.1416-1422
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    • 2010
  • $SF_6$ is the most commonly used insulating gas in electrical systems. But In these days $SF_6$ mixtures and alternative gas has been studied because of global warming. so although many studies have been carried out about binary gas mixtures with $SF_6$, few studies were presented about breakdown characteristics of $SF_6/N_2$ mixtures. At present study the breakdown characteristics of $SF_6/N_2$ mixtures in Non-uniform field was performed. In this paper, The simulation value are compared with experiment values. Streamer breakdown criterion was used for predicting breakdown voltage. For accurate simulation this simulation apply utilization factor using CST(computer simulation technology) EM $studio^{tm}$ program. AC breakdown experiments in non-uniform field was performed to compare with the breakdown simulation values. The pressure range of gas mixtures was 0.4 MPa to 0.7 MPa. The rod-plane was used and mixture ratio is $SF_6$ 20% : $N_2$ 80%. The gap lengths are 10mm to 70mm. As the pressure increase, this simulation value does not correspond to the experiment value. So this simulation need surface roughness factor. As a result of applying surface roughness factor this simulation decrease a relative error (|experiment value - simulation value| /simulation value).

Predicting Unknown Composition of a Mixture Using Independent Component Analysis (독립성분분석을 이용한 혼합물의 미지성분비율 예측)

  • Lee Hye-Seon;Song Jae-Kee;Park Hae-Sang;Jun Chi-Hyuck
    • The Korean Journal of Applied Statistics
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    • v.19 no.1
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    • pp.135-148
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    • 2006
  • Independent component analysis (ICA) is a statistical method for transforming an observed high-dimensional multivariate data into statistically independent components. ICA has been applied increasingly in wide fields of spectrum application since ICA is able to extract unknown components of a mixture from spectra. We focus on application of ICA for separating independent sources and predicting each composition using extracted components. The theory of ICA is introduced and an application to a metal surface spectra data will be described, where subsequent analysis using non-negative least square method is performed to predict composition ratio of each sample. Furthermore, some simulation experiments are performed to demonstrate the performance of the proposed approach.

Non-monotonic Size Dependence of Electron Mobility in Indium Oxide Nanocrystals Thin Film Transistor

  • Pham, Hien Thu;Jeong, Hyun-Dam
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2505-2511
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    • 2014
  • Indium oxide nanocrystals ($In_2O_3$ NCs) with sizes of 5.5 nm-10 nm were synthesized by hot injection of the mixture precursors, indium acetate and oleic acid, into alcohol solution (1-octadecanol and 1-octadecence mixture). Field emission transmission electron microscopy (FE-TEM), High resolution X-Ray diffraction (X-ray), Nuclear magnetic resonance (NMR), and Fourier transform infrared spectroscopy (FT-IR) were employed to investigate the size, surface molecular structure, and crystallinity of the synthesized $In_2O_3$ NCs. When covered by oleic acid as a capping group, the $In_2O_3$ NCs had a high crystallinity with a cubic structure, demonstrating a narrow size distribution. A high mobility of $2.51cm^2/V{\cdot}s$ and an on/off current ratio of about $1.0{\times}10^3$ were observed with an $In_2O_3$ NCs thin film transistor (TFT) device, where the channel layer of $In_2O_3$ NCs thin films were formed by a solution process of spin coating, cured at a relatively low temperature, $350^{\circ}C$. A size-dependent, non-monotonic trend on electron mobility was distinctly observed: the electron mobility increased from $0.43cm^2/V{\cdot}s$ for NCs with a 5.5 nm diameter to $2.51cm^2/V{\cdot}s$ for NCs with a diameter of 7.1 nm, and then decreased for NCs larger than 7.1 nm. This phenomenon is clearly explained by the combination of a smaller number of hops, a decrease in charging energy, and a decrease in electronic coupling with the increasing NC size, where the crossover diameter is estimated to be 7.1 nm. The decrease in electronic coupling proved to be the decisive factor giving rise to the decrease in the mobility associated with increasing size in the larger NCs above the crossover diameter.

Optimum Formulation of Starch and Non-muscle Protein for Alkali Surimi Gel from Jack Mackerel (전갱이의 알칼리 수리미 겔 제조를 위한 전분 및 비근육 단백질의 최적화)

  • 최종덕;최영준
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.7
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    • pp.1032-1038
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    • 2003
  • The two-level full factorial and mixture design were used to screen ingredient type and to investigate the effects of ingredients on properties of surimi gel from jack mackerel using measurements of breaking forces, deformation values and color. The addition of starch decreased breaking force significantly (p<0.05), but did not affect deformation. The bovine plasma protein (BPP) among non-muscle proteins increased a breaking force and deformation value. However, the dried egg white increased slightly a breaking force, and decreased greatly a deformation value. The breaking force of gel was increased, but deformation value did not change significantly (p<0.05) with adding BPP. The whiteness of gel was slightly improved with the addition of corn starch and BPP. At 78% moisture, the optimum ratios of ingredients were 89.5∼90.0% for alkali surimi, 4.6∼6.0% for corn starch and 4.3∼5.4% for BPP to obtain above 110g for a breaking force, 4.2 mm for a deformation, and 22.5 for a whiteness.

Studies on the Estimation of Theromodynamic Properties for the Non-Azeotropic Refrigerant Mixtures (혼합냉매의 열역학적 물성치 추산에 관한 연구)

  • 김민수;김동섭;노승탁;김욱중;윤재호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.5
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    • pp.1337-1348
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    • 1990
  • Estimations of the thermodynamic properties are made for the selected binary non-azeotropic refrigerant mixtures including R13B1/R114, R22/R114, R12/R114, R152a/R114, R13B1/R152a and R13B1/R12 using the Peng-Robinson equation of state and mixing rules. In this study, we find that the binary interaction coefficients for the above mixtures have an effect upon the vapor-liquid equilibria and the thermodynamic properties. As the binary interaction coefficient becomes larger, the deviation from the idealized model, say, Raoult`s rule, is obvious. A correlation is proposed to relate the binary interaction coefficient to the difference between the dipole moments op each pure refrigerant. Vapor-liquid equilibrium are also accurately estimated using the binary interaction coefficient. Pressure-enthalpy and temperature-entropy relations are plotted for a certain composition ratio of each refrigerant mixture. Results show that the estimating method in this study can be applied to the investigation of the thermodynamic properties for the binary non-azeotropic refrigerant mixtures.

Sheet Modeling and Transformation of Sheet into Solid Based on Non-manifold Topological Representation (바다양체 위상 표현을 바탕으로 한 박판 형상 모델링 및 솔리드로의 변환)

  • Lee, S.H.;Lee, K.W.
    • Journal of the Korean Society for Precision Engineering
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    • v.13 no.7
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    • pp.100-114
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    • 1996
  • In order to create a solid model more efficiently for a plastic or sheet metal product with a thin and constant thickness, various methods have been proposed up to now. One of the most typical approaches is to create a sheet model initially and then transform it into a solid model automatically for a given thickness. The sheet model as well as the transitive model in sheet modeling procedure is a non-manifold model. However, the previous methods adopted the boundary representations for a solid model as their topological framework. Thus, it is difficult to represent the exact adjacency relationship between topological entities and to implement the topological operations for sheet modeling and the transformation procedure of a sheet into a solid. In this paper, we proposed a sheet modeling system based on a non-manifold topological representation which can represent solids, sheets, wireframes, and their mixture. A set of generalized Euler operators for non-manifold topology as well as the sheet modeling capabilities including adding, bending, and punching functions are provided for easy modeling of sheet objects, and they are perfomed interactively with a two dimensional curve editor. Once a sheet model is completed, it can be transformed into a solid automatically. The transformation procedure is composed of the offset functions and the Boolean operations of sheet models, and it is even more comprehensive and easier to be implemented than the precious methods.

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