• 제목/요약/키워드: Non-homogeneous material

검색결과 107건 처리시간 0.022초

고휘도 휴대용 디스플레이를 위한 액정소자의 폴리스타일렌 배향막에 관한 연구 (Chemically modulated polystyrene surface using various ion beam exposure time for liquid crystal alignment of high brightness mobile display)

  • 조명현;이호영
    • 한국위성정보통신학회논문지
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    • 제9권3호
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    • pp.22-26
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    • 2014
  • 본 연구에서는 액정의 수직배향을 달성하기 위해서 특별히 제조된 폴리스타일렌 박막에 다양한 이온빔을 조사하는 방법을 사용하였다. 일반적으로 폴리스타일렌 수지는 통상의 폴리이미드 계열의 수지에 비해서 박막코팅을 하였을 때 보다 우수한 투과율을 나타내므로, 투과형 디스플레이로 사용되는 LCD의 배향막 재료로 더 적합하다고 생각되었다. 특히 고휘도이면서 저전력 사양을 달성하여야 하는 휴대용 디스플레이에서의 응용가능성이 기대되었다. 그러나, 일반적인 러빙법에 의한 배향처리에 대해서는 액정분자의 배향성이 폴리이미드 계열의 재료에 비해서 열등하여 사용되지 못하였다. 본 연구에서는 폴리스타일렌 계열의 박막재료를 배향막으로 가공함에 있어서 새로운 이온빔 조사법에 의한 비접촉식 배향법을 사용하였으며, 배향성과 액정분자의 프리틸트각 특성에 대해서 정량적인 결과를 얻을 수 있었다. 실험에서는 폴리스타일렌 수지에 이온빔의 조사시간을 15초까지 변화시키면서 액정분자의 배향성 및 프리틸트각의 특성을 측정하였다. 측정결과 스마트폰 및 휴대용 정보단말기 등의 디스플레이에 적합한 고투과율 액정표시소자의 구현이 가능하였다.

Performance of carbon fiber added to anodes of conductive cement-graphite pastes used in electrochemical chloride extraction in concretes

  • Pellegrini-Cervantes, M.J.;Barrios-Durstewitz, C.P.;Nunez-Jaquez, R.E.;Baldenebro-Lopez, F.J.;Corral-Higuera, R.;Arredondo-Rea, S.P.;Rodriguez-Rodriguez, M.;Llanes-Cardenas, O.;Beltran-Chacon, R.
    • Carbon letters
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    • 제26권
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    • pp.18-24
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    • 2018
  • Pollution of chloride ion-reinforced concrete can trigger active corrosion processes that reduce the useful life of structures. Multifunctional materials used as a counter-electrode by electrochemical techniques have been used to rehabilitate contaminated concrete. Cement-based pastes added to carbonaceous material, fibers or dust, have been used as an anode in the non-destructive Electrochemical Chloride Extraction (ECE) technique. We studied the performance of the addition of Carbon Fiber (CF) in a cement-graphite powder base paste used as an anode in ECE of concretes contaminated with chlorides from the preparation of the mixture. The experimental parameters were: 2.3% of free chlorides, 21 days of ECE application, a Carbon Fiber Volume Fraction (CFVF) of 0.1, 0.3, 0.6, 0.9%, a lithium borate alkaline electrolyte, a current density of $4.0A/m^2$ and a cement/graphite ratio of 1.0 for the paste. The efficiency of the ECE in the traditional technique using metal mesh as an anode was 77.6% and for CFVF of 0.9% it was 90.4%, with a tendency to increase to higher percentages of the CFVF in the conductive cement-graphite paste, keeping the pH stable and achieving a homogeneous ECE in the mass of the concrete contaminated with chlorides.

Ni를 첨가한 ZnO-Bi2O3-Sb2O3계의 소결과 전기적 특성 (Sintering and Electrical Properties of Ni-doped ZnO-Bi2O3-Sb2O3)

  • 홍연우;신효순;여동훈;김종희;김진호
    • 한국전기전자재료학회논문지
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    • 제22권11호
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    • pp.941-948
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    • 2009
  • The present study aims at the examination of the effects of 1 mol% NiO addition on the reaction, microstructure development, resultant electrical properties, and especially the bulk trap and interface state levels of $ZnO-Bi_2O_3-Sb_2O_3$ (Sb/Bi=0.5, 1.0, and 2.0) systems (ZBS). The samples were prepared by conventional ceramic process, and characterized by density, XRD, SEM, I-V, impedance and modulus spectroscopy (IS & MS) measurement. The sintering and electrical properties of Ni-doped ZBS (ZBSN) systems were controlled by Sb/Bi ratio. Pyrochlore ($Zn_2Bi_3Sb_3O_{14}$) was decomposed more than $100^{\circ}C$ lowered in ZBS (Sb/Bi=1.0) by Ni doping. The reproduction of pyrochlore was suppressed by the addition of Ni in ZBS. Between two polymorphs of $Zn_7Sb_2O_{12}$ spinel ($\alpha$ and $\beta$), microstructure of ZBSN (Sb/Bi=0.5) composed of a-spinel was more homogeneous than $Sb/Bi{\geq}1.0$ composed of $\beta$-spinel phase. In ZBSN, the varistor characteristics were not improved drastically (non-linear coefficient $\alpha\;=\;6{\sim}11$) and independent on microstructure according to Sb/Bi ratio. Doping of Ni to ZBS seemed to form ${V_0}^{\cdot}$ (0.33 eV) as dominant bulk defect. From IS & MS, especially the grain boundaries of Sb/Bi=0.5 systems were divided into two types, i.e. sensitive to oxygen and thus electrically active one and electrically inactive intergranular one with temperature.

Pectin from Passion Fruit Fiber and Its Modification by Pectinmethylesterase

  • Contreras-Esquivel, Juan Carlos;Aguilar, Cristobal N.;Montanez, Julio C.;Brandelli, Adriano;Espinoza-Perez, Judith D.;Renard, Catherine M.G.C.
    • Preventive Nutrition and Food Science
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    • 제15권1호
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    • pp.57-66
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    • 2010
  • Passion fruit fiber pectin gels represent a new alternative pectin source with potential for food and non-food applications on a commercial scale. Pectic polysaccharides were extracted from passion fruit (Passiflora edulis) fiber using citric acid as a clean catalyst and autoclaved for 20 to 60 min at $121^{\circ}C$. The best condition of pectin yield with the highest molecular weight was obtained with 1.0% of citric acid (250 mg/g dry passion fruit fiber pectin) for 20 min of autoclaving. Spectroscopic analyses by Fourier transform infrared, enzymatic degradation reactions, and ion-exchange chromatography assays showed that passion fruit pectin extracted for 20 min was homogeneous high methoxylated pectin (70%). Gel permeation analysis confirmed that the pectin extract obtained by autoclaving by 20 min showed higher molecular weights than those autoclaved for 40 and 60 min. Passion fruit pectin extracted for 20 min was enzymatically modified with fungal pectinmethylesterase to create restructured gels. Short autoclave treatment (20 min) with citric acid as extractant resulted in a significant increase of gel strength, improving pectin extraction in terms of functionality. The treatment of solubilized material (pectic polysaccharides) in the presence of insoluble material (cellulose and hemicellulose) with pectinmethylesterase and calcium led to the creation of a stiffer passion fruit fiber pectin gel, while syneresis was not observed.

탄성파 기법을 이용한 콘크리트궤도의 구조강성 및 충전상태 평가에 관한 연구 (Evaluation on Structural Stiffness and Grouting Efficiency of Concrete Track using Elastic Wave Tests)

  • 이일화;조성호;장승엽
    • 한국철도학회논문집
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    • 제12권1호
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    • pp.55-64
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    • 2009
  • 콘크리트궤도는 유지보수상의 장점으로 인하여 자갈궤도를 급속히 대체하고 있다. 반면에 보수보강이 어렵기 때문에 매우 엄격한 설계와 시공기술이 필요하며 이러한 기술을 만족하기 위해서는 평가기술 또한 뒷받침이 되어야 한다. 본 논문에서는 이와 같이 시공 및 유지보수의 핀 평가기술을 확보하기 위한 방안으로서 탄성파를 이용하는 비파괴조사기법을 다양하게 적용하였다. 사용된 기법은 SASW시험, 임팩트에코시험, 연속임팩트에코시험이다. 시험은 49개의 프리캐스트 판넬의 강성구조와 충진성능을 평가하는 목적으로 총 5,353회에 걸쳐 수행되었다. 적용 결과, 콘크리트재료 자체의 비균질성으로 인하여 탄성파시험의 적용 및 분석이 제한적이지만 본 논문에서 목적하는 슬래브의 강성구조과 충전성(공극)에 대한 신뢰성 있는 조사 결과를 얻을 수 있을 것으로 나타났다.

XFINAS 계면요소와 고체요소를 이용한 콘크리트-강재 합성구조물의 비선형 거동해석 (Nonlinear Analysis of Steel-Concrete Composite Structures using XFINAS Interface and Solid Elements)

  • 김기두;수타스트라디트 송삭;박종화;박재균
    • 한국전산구조공학회논문집
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    • 제23권3호
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    • pp.267-274
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    • 2010
  • 합성구조는 전체가 동일한 재료 특성을 가지는 구조와는 달리 서로 다른 특성 즉 강재와 콘크리트의 구조로 결합되어 있다. 따라서 실제 모델링 시 이러한 재료 특성을 반영하지 않으면 실제 거동을 예측할 수 없으므로 콘크리트와 강재 사이에 인터페이스 요소를 연결하여 강재와 콘크리트의 슬립을 예측할 수 있게 한다. 인터페이스 요소는 일반적으로 사용되는 구성방정식은 적합하지 않고 실제 부착 및 슬립을 고려한 비선형 구성 방정식을 사용하여야만 적절히 사용할 수 있다. 이 계면요소를 이용하여 판형 강재 박스와 콘크리트의 접촉면을 묘사하였다. 그리고 강재 박스의 휨-좌굴 거동을 묘사하기 위해서는 일반적인 8절점 적합 요소의 사용은 부적절하므로 판형 강재 박스는 보강 변형도(Enhanced Assumed Strain) 고체요소를 사용하여 휨거동을 묘사할 수 있게 하였다.

Static impedance functions for monopiles supporting offshore wind turbines in nonhomogeneous soils-emphasis on soil/monopile interface characteristics

  • Abed, Younes;Bouzid, Djillali Amar;Bhattacharya, Subhamoy;Aissa, Mohammed H.
    • Earthquakes and Structures
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    • 제10권5호
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    • pp.1143-1179
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    • 2016
  • Offshore wind turbines are considered as a fundamental part to develop substantial, alternative energy sources. In this highly flexible structures, monopiles are usually used as support foundations. Since the monopiles are large diameter (3.5 to 7 m) deep foundations, they result in extremely stiff short monopiles where the slenderness (length to diameter) may range between 5 and 10. Consequently, their elastic deformation patterns under lateral loading differ from those of small diameter monopiles usually employed for supporting structures in offshore oil and gas industry. For this reason, design recommendations (API and DNV) are not appropriate for designing foundations for offshore wind turbine structures as they have been established on the basis of full-scale load tests on long, slender and flexible piles. Furthermore, as these facilities are very sensitive to rotations and dynamic changes in the soil-pile system, the accurate prediction of monopile head displacement and rotation constitutes a design criterion of paramount importance. In this paper, the Fourier Series Aided Finite Element Method (FSAFEM) is employed for the determination of static impedance functions of monopiles for OWT subjected to horizontal force and/or to an overturning moment, where a non-homogeneous soil profile has been considered. On the basis of an extensive parametric study, and in order to address the problem of head stiffness of short monopiles, approximate analytical formulae are obtained for lateral stiffness $K_L$, rotational stiffness $K_R$ and cross coupling stiffness $K_{LR}$ for both rough and smooth interfaces. Theses expressions which depend only on the values of the monopile slenderness $L/D_p$ rather than the relative soil/monopile rigidity $E_p/E_s$ usually found in the offshore platforms designing codes (DNV code for example) have been incorporated in the expressions of the OWT natural frequency of four wind farm sites. Excellent agreement has been found between the computed and the measured natural frequencies.

SnO2-(1-x)P2O5-xB2O3 유리의 열적, 구조적 특성 (Structure and Thermal Properties of SnO2-(1-x)P2O5-xB2O3 Glasses)

  • 안용태;최병현;지미정;장우석;배현;황해진
    • 한국세라믹학회지
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    • 제47권2호
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    • pp.117-121
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    • 2010
  • $SnO_2-(1-x)P_2O_5-xB_2O_3$ glass system were prepared by melt-quenching technique in the compositional series containing 50, 55 and 60 mol% of $SnO_2$. Local structure of the glasses was investigated by Raman and FT-IR measurements. A large glass-forming region was found at the phosphate side of the ternary system with homogeneous glasses containing up to 5~25 mol% of $B_2O_3$. According as content of $B_2O_3$ increases, theraml expansion coefficient of glass decreased but transition temperature and softening temperature increased. Because these phenomenon changed local structure of glass. According as content of $B_2O_3$ increases, quantity of bridging oxygen increased. Also, according as content of $SnO_2$ increases, confirmed that quantity of non-bridging oxygen increases.

자활직업훈련 사업의 임금 효과 분석 - Propensity Score Matching 방법으로 - (An analysis of the income impact of Self-Sufficiency training Program - by using Propensity Score Matching -)

  • 안서연
    • 사회복지연구
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    • 제37호
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    • pp.171-197
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    • 2008
  • 본 연구는 국민기초생활보장법 하의 조건부 수급자가 자활직업훈련 프로그램의 참여로 인해 임금이 향상되었는지에 관해 실증적으로 분석 하였다. 분석 자료로는 한국노동연구원에서의 자활사업 참여자를 대상으로 한 '자활대상자 직업훈련 실태'조사와 한국보건사회연구원에서 실시하는 2004년 '자활패널'조사 자료를 결합하여 '자활직업훈련 실태'조사의 응답자를 실험그룹으로'자활패널'을 비교그룹으로 구성하여 분석하였으며, 기존 연구의 통계적 취약점을 극복하기 위해 Propensity Score Matching 방법을 이용하여 자활직업훈련의 임금효과를 분석하였다. 분석 결과 자활직업훈련 참가자들이 그와 비슷한 특성을 가진 비교그룹에 비해서 약 12만원 정도 소득이 낮음을 확인함으로써, 이러한 부정적인 효과가 나타난 원인과 의미에 대해서 논의하였다.

Two-dimensional curved panel vibration and flutter analysis in the frequency and time domain under thermal and in-plane load

  • Moosazadeh, Hamid;Mohammadi, Mohammad M.
    • Advances in aircraft and spacecraft science
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    • 제8권4호
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    • pp.345-372
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    • 2021
  • The analysis of nonlinear vibrations, buckling, post-buckling, flutter boundary determination and post-flutter behavior of a homogeneous curved plate assuming cylindrical bending is conducted in this article. Other assumptions include simply-supported boundary conditions, supersonic aerodynamic flow at the top of the plate, constant pressure conditions below the plate, non-viscous flow model (using first- and third-order piston theory), nonlinear structural model with large deformations, and application of mechanical and thermal loads on the curved plate. The analysis is performed with constant environmental indicators (flow density, heat, Reynolds number and Mach number). The material properties (i.e., coefficient of thermal expansion and modulus of elasticity) are temperature-dependent. The equations are derived using the principle of virtual displacement. Furthermore, based on the definitions of virtual work, the potential and kinetic energy of the final relations in the integral form, and the governing nonlinear differential equations are obtained after fractional integration. This problem is solved using two approaches. The frequency analysis and flutter are studied in the first approach by transferring the handle of ordinary differential equations to the state space, calculating the system Jacobin matrix and analyzing the eigenvalue to determine the instability conditions. The second approach discusses the nonlinear frequency analysis and nonlinear flutter using the semi-analytical solution of governing differential equations based on the weighted residual method. The partial differential equations are converted to ordinary differential equations, after which they are solved based on the Runge-Kutta fourth- and fifth-order methods. The comparison between the results of frequency and flutter analysis of curved plate is linearly and nonlinearly performed for the first time. The results show that the plate curvature has a profound impact on the instability boundary of the plate under supersonic aerodynamic loading. The flutter boundary decreases with growing thermal load and increases with growing curvature.