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The Stabilizing Role of Cyclodextrins on Keggin Phosphotungstic Acid by Complexation Unveiled by Electrospray Mass Spectrometry

  • Fan, YanXuan;Zhang, Yan;Jia, QiaoDi;Cao, Jie;Wu, WenJie
    • Mass Spectrometry Letters
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    • v.6 no.1
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    • pp.13-16
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    • 2015
  • This study demonstrated the stabilizing role of a cyclodextrin on Keggin $[PW_{12}O_{40}]^{3-}$ via hydrogen bonding complexation unveiled by ESI-MS. The distinctive fragmentation pathways of the $\{PW_{12}\}/{\gamma}$-CD complexes from that of discrete $[PW_{12}O_{40}]^{3-}$ showed that the so-called "weak" non-covalent interactions can effectively change the dissociation chemistry of POM in the gas phase. The influence of different types of solvents and organic additives such as ${\gamma}$-CD on the stability of Keggin $[PW_{12}O_{40}]^{3-}$ was also addressed firstly by ESI-MS.

Fast, Upward, Long-Lasting, Transit Echoes as an Evidence of New-Type of Meteor-Trail Leader Discharge in the Summer Polar Upper Mesosphere

  • Lee, Young-Sook;Kirkwood, Sheila;Kwak, Young-Sil
    • Journal of Astronomy and Space Sciences
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    • v.35 no.2
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    • pp.93-103
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    • 2018
  • Non-specular, vertically upward transit, fast-moving radar echoes are observed in the summer polar upper mesosphere near 90 km using 52 MHz VHF radar at Esrange, Sweden. By resolving maximum echo power movement, the unusual meteor trails propagate vertically upward with taking horizontal displacements at an initial speed of 10 km/s exponentially decreasing with increasing height from 85-89 km, lasting for 3.5 sec. Another upward transit is observed as following a downward transit echo target in about ~1 sec, lasting over 5 sec. The upward motion cannot be explained with the dynamics of penetrating meteors or by atmospheric dynamics. The observation proposes that secondary produced plasma jets occurring from meteor trail are possibly responsible for upward fast moving echoes. The long-lasting (3-5 sec), ascending meteor trails at speeds of a few $10^4m/s$ are distinctive from any previous occurrences of meteors or upper atmospheric electrical discharges in the aspect of long-lasting upward/downward motions. This result possibly suggests a new type of meteor-trail leader discharge occurring in the summer polar upper mesosphere and lower thermosphere.

Narrative Structure in "World of Warcraft" ("World of Warcraft"의 서사 연구)

  • Lee, Jae-Hong
    • Journal of Korea Game Society
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    • v.8 no.4
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    • pp.45-53
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    • 2008
  • This paper analyzed the narrative construction of ‘World of Warcraft’ which is very popular worldwide. Narratology and ludology should be interrelated in the larger area of art, rather than existing as separate fields. Dramatic narrative constructions of game would be made when the rules of game emerge with the circumstances of play. This paper reviews how 'World of Warcraft' generates its tremendous popularity through analyzing the overall narratives of 'World of Warcraft' and sub-narratives such as quest, PvP and hunting systems. The distinctive feature of this game is its well-designed story flow which is emerged by both underlying linear original story and non-linear multi-scenario that offers rich interactivities to the game users.

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Study on NDT Fault Diagnosis of the Ball Bearing under Stage of Abrasion by Infrared Thermography (마모 단계의 볼 베어링에 대한 적외선 열화상 비파괴 결함 진단 연구)

  • Seo, Jin-Ju;Hong, Dong-Pyo;Kim, Won-Tae
    • Journal of the Korean Society for Nondestructive Testing
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    • v.32 no.1
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    • pp.7-11
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    • 2012
  • For fault detection about the abrasion stage of rotational machineries under the dynamic loading conditions unlike the traditional diagnosis method used in the past decade, the infrared thermographic method with its distinctive advantages in non-contact, non-destructive, and visible aspects is proposed. In this paper, by applying a rotating deep-grooved ball bearing, passive thermographic experiments were conducted as an alternative way to proceeding the traditional fault monitoring on spectrum analyzer. As results, the thermographic experiment was compared with the traditional vibration spectrum analysis to evaluate the efficiency of the proposed method. Based on the results obtained as NDT, the temperature characteristics and abnormal fault detections of the ball bearing according to the abrasion stage were analyzed.

Crisis Management System in Hospitals (병원의 위기관리 시스템)

  • Kim, Hyeongjin
    • Korea Journal of Hospital Management
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    • no.spc
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    • pp.85-95
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    • 2016
  • This study is to introduce a comprehensive framework of a crisis management system developed at a prominent hospital in South Korea. Throughout recent decades, especially in the recent years, the way in which to cope with both internal and external challenges has been one of the most critical issues. Since the incident management system in the U.S. is acknowledged as the most advanced crisis management model in the world, a portion of this study refers to the Hospital Incident Command System(HICS) provided by the California Emergency Medical Services Authority(EMSA). Nevertheless, the framework suggested in this article was designed based on a distinctive Korean hospital setting. The main contents of this study are as follows; categorization of each type of crisis, organization of a crisis management team in a non-crisis or crisis state, crisis assessment by life cycle stage, and establishment of crisis management protocol. Even though many types of crises are unspecified, those can be categorized into external crisis, medical crisis, and utility & activity failure. A crisis management organization should be operated and consisted differently- depending on a crisis or non-crisis situation. From a life-cycle perspective, the range by which the crisis should be managed extends from pre-stage to post-stage of the crisis. It is important to set proper scenarios and manuals by crisis type to develop a crisis management framework of high quality. With continuous efforts, hospitals can prepare for the uncertainty to better concentrate on core business operations.

Comic-Book Style Rendering for Game (게임을 위한 코믹북 스타일 렌더링)

  • Kim, Tae-Gyu;Oh, Gyu-Hwan;Lee, Chang-Shin
    • Journal of Korea Game Society
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    • v.7 no.4
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    • pp.81-92
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    • 2007
  • Nowadays, many computer games based on NPR(Non-photorealistic Rendering) techniques have been developed due to their distinctive visual properties. However, only limited methods of NPR techniques have been exploited in producing computer games and amongst them cartoon-style rendering techniques especially has had the special interest. In the paper, we suggest an effective rendering method of comic-book style that will be applicable to computer game. In order to do, we first characterize the properties of comic-book from comparing two visuals: celluloid animation and comic-book. We then suggest a real-time rendering method of comic-book style represented by outline sketch, tone, and hatching. We finally examine its effectiveness by observing the game developed using the method.

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Feasibility study of a resistive-type sodium aerosol detector with ZnO nanowires for sodium-cooled fast reactors

  • Jewhan Lee;Da-Young Gam;Ki Ean Nam;Seong J. Cho;Hyungmo Kim
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2373-2379
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    • 2023
  • In sodium systems, leakage is one of the safety concerns; it can cause chemical reactions, which may result in fires. There are contact and non-contact types of leak detectors, and the conventional method of non-contact type detection is by gas sampling. Because of the complexity of this method, there has always been a need for a simple gas sensor, and the resistive-type nanostructure ZnO sensor is a promising option with various advantages. In this study, a ZnO sensor was fabricated, and the concept was tested as a leak detector using a dedicated experiment facility. The experiment results showed distinctive changes in resistance with the presence of sodium aerosol under various conditions. Replacing the conventional gas sampling with the ZnO sensors is expected to enable identification of the leakage location if used as a point-wise instrumentation and to greatly reduce the total cost, making the system simple, light, and effective. For further study, more tests will be performed to evaluate the sensitivity of key parameters under various conditions.

Analysis of Online Behavior and Prediction of Learning Performance in Blended Learning Environments

  • JO, Il-Hyun;PARK, Yeonjeong;KIM, Jeonghyun;SONG, Jongwoo
    • Educational Technology International
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    • v.15 no.2
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    • pp.71-88
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    • 2014
  • A variety of studies to predict students' performance have been conducted since educational data such as web-log files traced from Learning Management System (LMS) are increasingly used to analyze students' learning behaviors. However, it is still challenging to predict students' learning achievement in blended learning environment where online and offline learning are combined. In higher education, diverse cases of blended learning can be formed from simple use of LMS for administrative purposes to full usages of functions in LMS for online distance learning class. As a result, a generalized model to predict students' academic success does not fulfill diverse cases of blended learning. This study compares two blended learning classes with each prediction model. The first blended class which involves online discussion-based learning revealed a linear regression model, which explained 70% of the variance in total score through six variables including total log-in time, log-in frequencies, log-in regularities, visits on boards, visits on repositories, and the number of postings. However, the second case, a lecture-based class providing regular basis online lecture notes in Moodle show weaker results from the same linear regression model mainly due to non-linearity of variables. To investigate the non-linear relations between online activities and total score, RF (Random Forest) was utilized. The results indicate that there are different set of important variables for the two distinctive types of blended learning cases. Results suggest that the prediction models and data-mining technique should be based on the considerations of diverse pedagogical characteristics of blended learning classes.

Sclerosing Meningioma : Radiological and Clinical Characteristics of 21 Cases

  • Kang, Ho;Kim, Jin Wook;Se, Young-Bem;Dho, Yun-Sik;Choi, Seung Hong;Park, Sung-Hye
    • Journal of Korean Neurosurgical Society
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    • v.59 no.6
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    • pp.584-589
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    • 2016
  • Objective : A rare subtype of meningioma, sclerosing meningioma is not included in the current World Health Organization classification of meningiomas and is classified into the category of other morphological variation subtypes. Sclerosing meningioma is often misdiagnosed to other non-benign meningioma or malignant neoplasm, so it is important to diagnose sclerosing type correctly. We analyzed the radiological and clinical characteristics of a series of sclerosing meningiomas. Methods : Twenty-one patients who underwent surgery in one institute with a histopathologically proven sclerosing meningioma were included from 2006 to 2014. Eighteen tumors were diagnosed as a pure sclerosing-type meningioma, and 3 as mixed type. Magnetic resonance image was taken for all patients including contrast enhancement image. Computed tomography (CT) scan was taken for 16 patients. One neuroradiologist and 1 neurosurgeon reviewed all images retrospectively. Results : In the all 16 patients with preoperative CT images, higher attenuation was observed in the meningioma than in the brain parenchyma, and calcification was observed in 11 (69%). In 15 of the 21 patients (71%), a distinctive very low signal intensity appeared as a dark color in T2-weighted images. Nine of these 15 tumors (60%) exhibited heterogeneous enhancement, and 6 (40%) exhibited homogeneous enhancement that was unlike the homogeneous enhancing pattern shown by conventional meningiomas. Ten patients had a clear tumor margin without peritumoral edema. Conclusion : Although these peculiar radiological characteristics are not unique to sclerosing meningioma, we believe that they are distinctive features that may be helpful for distinguishing sclerosing meningioma from other subtypes.

Major Element Changes in the Upper Quaternary Sediment of the East Sea (Sea of Japan): Their Implications for the Onset of Holocene

  • Hyun, Sang-Min;Han, Sang-Joon;Bahk, Jang-Jun
    • Journal of the korean society of oceanography
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    • v.33 no.4
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    • pp.185-195
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    • 1998
  • Two piston cores (94PC-2 and 95PC-4) taken from the East Sea (Sea of Japan) are studied to evaluate the paleoceanographic changes and its interaction with climatic variation. The bulk geochemistry of the non-biogenic fractions of 54 sediment samples is determined using X-ray fluorescence. Four geochemical stratigraphic units at both core sediments are recognized based on the variations in major element concentration. These chemical stratigraphic units correspond well with the sedimentological and paleontological facies. Source materials are considered as basic and/or intermediate rocks judging from silica content. A distinctive boundary around 11 kyr may correspond to Younger Dryas event. The switch of most major elements at this level and the distinctive changes in concentration of typical terrigenous elements (TiO$_2$ and Al$_2$O$_3$) are the strong evidence for the difference in sources of terrigenous materials. The weathering indices exhibit high degree in Core 94PC-2 and low degree in Core 95PC-4. The changes in weathering degree can be distinguished by the lowest value occurred at 11 kyr in Core 94PC-2 and by a gradual decrease from top to bottom in Core 95PC-4. The profiles of potassium and sodium exhibit specific excursions between the Holocene and the late Pleistocene. This implies that sediments of the two cores originating from different sources with different weathering degrees. The distinct two-group distributions in K$_2$O/CaO vs. Na$_2$O/K$_2$O also support the difference in provenance of aluminosilicate materials at the boundary of 11 kyr. Thus, supply patterns of terrigenous materials are stable in Holocene and more complicated in the last glacial period.

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