• Bulletin of the Korean Chemical Society
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• v.27 no.11
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• pp.1769-1774
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• 2006

A new liquid chromatographic chiral stationary phase based on (2S,3S)-O,O'-bis-(10-undecenoyl)-N,N'-bis-(3,5-dinitrobenzoyl)-2,3-diamino-1,4-butandiol was prepared starting from (2R,3R)-1,4-bis(benzyloxy)-2,3-butanediol. The new chiral stationary phase was applied to the resolution of racemic anilide derivatives of N-acetyl-a-amino acids, 1,1'-bi-2-naphthol and 3,3'-diaryl-1,1'-bi-2-naphthols. The CSP was also applied to the resolution of some chiral drugs including a diuretic, bendroflumethiazide, and non-steroidal anti-inflammatory agents such naproxen and alminoprofen. In every case, the chiral recognition efficiency of the new CSP was quite excellent.

• Journal of the Korea Society for Simulation
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• v.19 no.3
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• pp.109-117
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• 2010

In this study, we consider stationary waiting times in a simple fork-and-join type queue which consists of three single-server machines, Machine 1, Machine 2, and Assembly Machine. We assume that the queue has a renewal arrival process and that independent service times at each node are either deterministic or non-overlapping. We also assume that the Machines 1 and 2 have an infinite buffer capacity whereas the Assembly Machine has two finite buffers, one for each machine. Services at each machine are given by FIFO service discipline and a communication blocking policy. We derive the explicit expressions for stationary waiting times at all nodes as a function of finite buffer capacities by using (max,+)-algebra. Various characteristics of stationary waiting times such as mean, higher moments, and tail probability can be computed from these expressions.

• Ocean Systems Engineering
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• v.4 no.4
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• pp.293-308
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• 2014

Unlike the traditional displacement type vessels, the high speed planing crafts are supported by the lift forces which are highly non-linear. This non-linear phenomenon causes their motions in an irregular seaway to be non-Gaussian. In general, it may not be possible to express the probability distribution of such processes by an analytical formula. Also the process might not be stationary or ergodic in which case the statistical behavior of the motion to be constantly changing with time. Therefore the extreme values of such a process can no longer be calculated using the analytical formulae applicable to Gaussian processes. Since closed form analytical solutions do not exist, recourse is taken to fitting a distribution to the data and estimating the statistical properties of the process from this fitted probability distribution. The peaks over threshold analysis and fitting of the Generalized Pareto Distribution are explored in this paper as an alternative to Weibull, Generalized Gamma and Rayleigh distributions in predicting the short term extreme value of a random process.

• Journal of Korea Multimedia Society
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• v.12 no.1
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• pp.26-30
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• 2009

We propose an adaptive Recursive Least Rank(RLR) L-filter which uses an L-estimator in order statistics and is based on rank estimate in robust statistics. The proposed RLR L-filter is a non-linear adaptive filter using non-linear adaptive algorithm and adapts itself to optimal filter in the sense of least dispersion measure of errors with non-homogeneous step size. Therefore the filter may be suitable for applications when the transmission channel is nonlinear channels such as Gaussian noise or impulsive noise, or when the signal is non-stationary such as image signal.

• Structural Engineering and Mechanics
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• v.2 no.3
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• pp.285-294
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• 1994

Based on a fast and accurate method for the stationary random seismic response analysis for discretized structures(Lin 1992, Lin et al. 1992), a Ritz method for dealing with such responses of continuous systems in developed. This method is studied quantitatively, using cantilever shear beams for simplicity and clarity. The process can be naturally extended to deal with various boundary conditions as well as non-uniform Bernoulli-Euler beams, or even Timoshenko beams. Algorithms for both proportionally and non-proportionally damped responses are described. For all of such damping cases, it is not necessary to solve for the natural vibrations of the beams. The solution procedure is very simple, and equally efficient for a white or a non-white ground excitation spectrum. Two examples are given where various power spectral density functions, variances, covariances and second spectral moments of displacement, internal force response, and their derivatives are calculated and analyses. Some Ritz solutions are compared with "exact" CQC solutions.

• Smart Structures and Systems
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• v.2 no.1
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• pp.47-60
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• 2006

Bi-spectrum is a tool in the signal processing for identification of non-linear dynamic behvaiour in systems, and well-known for stationary system where components are non-linearly interacting. Breathing of a crack during shaft rotation is also exhibits a non-linear behaviour. The crack is known to generate 2X (twice the machine RPM) and higher harmonics in addition to 1X component in the shaft response during its rotation. Misaligned shaft also shows similar such feature as a crack in a shaft. The bi-spectrum method has now been applied on a small rotating rig to observe its features. The bi-spectrum results are found to be encouraging to distinguish these faults based on few experiments conducted on a small rig. The results are presented here.

• Journal of Navigation and Port Research
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• v.44 no.1
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• pp.44-52
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• 2020

More accurate forecasting of port cargo in the global long-term recession is critical for the implementation of port policy. In this study, the Busan Port container volume (export cargo and transshipment cargo) was estimated using the Vector Autoregressive (VAR) model and the vector error correction (VEC) model considering the causal relationship between the economic scale (GDP) of Korea, China, and the U.S. as well as ARIMA, a single volume model. The measurement data was the monthly volume of container shipments at the Busan port J anuary 2014-August 2019. According to the analysis, the time series of import and export volume was estimated by VAR because it was relatively stable, and transshipment cargo was non-stationary, but it has cointegration relationship (long-term equilibrium) with economic scale, interest rate, and economic fluctuation, so estimated by the VEC model. The estimation results show that ARIMA is superior in the stationary time-series data (local cargo) and transshipment cargo with a trend are more predictable in estimating by the multivariate model, the VEC model. Import-export cargo, in particular, is closely related to the size of our country's economy, and transshipment cargo is closely related to the size of the Chinese and American economies. It also suggests a strategy to increase transshipment cargo as the size of China's economy appears to be closer than that of the U.S.

• Journal of Korea Water Resources Association
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• v.47 no.9
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• pp.825-838
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• 2014

The stationary Markov chain model has been widely used as a daily rainfall simulation model. A main assumption of the stationary Markov model is that statistical characteristics do not change over time and do not have any trends. In other words, the stationary Markov chain model for daily rainfall simulation essentially can not incorporate any changes in mean or variance into the model. Here we develop a Non-stationary hidden Markov chain model (NHMM) based stochastic downscaling scheme for simulating the daily rainfall sequences, using general circulation models (GCMs) as inputs. It has been acknowledged that GCMs perform well with respect to annual and seasonal variation at large spatial scale and they stand as one of the primary sources for obtaining forecasts. The proposed model is applied to daily rainfall series at three stations in Nakdong watershed. The model showed a better performance in reproducing most of the statistics associated with daily and seasonal rainfall. In particular, the proposed model provided a significant improvement in reproducing the extremes. It was confirmed that the proposed model could be used as a downscaling model for the purpose of generating plausible daily rainfall scenarios if elaborate GCM forecasts can used as a predictor. Also, the proposed NHMM model can be applied to climate change studies if GCM based climate change scenarios are used as inputs.

• Wind and Structures
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• v.24 no.1
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• pp.59-78
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• 2017

Non-stationarity and non-Gaussian property are two of the most important characteristics of wind. These two features are studied in this study based on wind speed records measured at different heights from a 325 m high meteorological tower during the synoptic wind storms. By using the time-frequency analysis tools, it is found that after removing the low frequency trend of the longitudinal wind, the retained fluctuating wind speeds remain to be asymmetrically non-Gaussian distributed. Results show that such non-Gaussianity is due to the weak-stationarity of the detrended fluctuating wind speed. The low frequency components of the fluctuating wind speeds mainly contribute to the non-zero skewness, while distribution of the high frequency component is found to have high kurtosis values. By further studying the decomposed wind speed, the mechanisms of the non-Gaussian distribution are examined from the phase, turbulence energy point of view.

• Journal of the Korean Institute of Landscape Architecture
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• v.41 no.6
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• pp.43-51
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• 2013

This study aims to examine the presence of non-stationary relationship between water quality and land use in watersheds. In investigating the relationships between land use and water quality, most previous studies adopted OLS method which is assumed stationarity. However, this approach is difficult to capture the local variation of the relationships. We used 146 sampling data and land cover data of Korean Ministry of Environment to build conventional regressions and GWR models for BOD, TN and TP. Regression model and GWR models of BOD, TN, TP were compared with $R^2$, AICc and Moran's I. The results of comparisons and descriptive statistics of GWR models strongly indicated the presence of Non-Stationarity between water quality and land use.