• Steel and Composite Structures
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• v.46 no.5
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• pp.611-619
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• 2023

In the present work, the flutter characteristics of porous nanocomposite cylindrical shells, reinforced with graphene platelets (GPLs) in supersonic airflow, have been investigated. Different distributions for GPLs and porosities have been considered which are named uniform and non-uniform distributions thorough the shell's thickness. The effective material properties have been determined via Halpin-Tsai micromechanical model. The cylindrical shell formulation considering supersonic airflow has been developed in the context of first-order shell and first-order piston theories. The governing equations have been solved using Galerkin's method to find the frequency-pressure plots. It will be seen that the flutter points of the shell are dependent on the both amount and distribution of porosities and GPLs and also shell geometrical parameters.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.214.2-214.2
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• 2011

In this work, porous carbon based electrodes are prepared by carbonization using poly(vinylidene fluoride) (PVDF)/carbon nanotube (CNT) composites to further increase the specific capacitance for supercapacitors. Electrode materials investigate the aspects of specific capacitance, pore size distribution and surface area: influence of carbonization temperatures of PVDF/CNT composites. The electrochemical properties are investigated by cyclic voltammetry, impedance spectra, and galvanostatic charge-discharge performance with in $TEABF_4$ (tetraethylammonium tetrafluoroborate)/acetonitrile as non-aqueous electrolyte. From the results, the highest value of specific capacitance of ~101 $F{\cdot}g^{-1}$ is obtained for the samples carbonized at $600^{\circ}C$. Furthermore, pore size of samples control be low 7 nm through carbonization process. It is suggested that micropores significantly contribute to the specific capacitance, resulting from improved charge transfer.

• Steel and Composite Structures
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• v.34 no.2
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• pp.215-226
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• 2020

The aim of this study is to investigate free vibration of functionally graded porous nanocomposite rectangular plates where the internal pores and graphene platelets (GPLs) are distributed in the matrix either uniformly or non-uniformly according to three different patterns. The elastic properties of the nanocomposite are obtained by employing Halpin-Tsai micromechanics model. The GPL-reinforced plate is modeled using a semi-analytic approach composed of generalized differential quadrature method (GDQM) and series solution adopted to solve the equations of motion. The proposed rectangular plates have two opposite edges simply supported, while all possible combinations of free, simply supported and clamped boundary conditions are applied to the other two edges. The 2-D differential quadrature method as an efficient and accurate numerical tool is used to discretize the governing equations and to implement the boundary conditions. The convergence of the method is demonstrated and to validate the results, comparisons are made between the present results and those reported by well-known references for special cases treated before, have confirmed accuracy and efficiency of the present approach. New results reveal the importance of porosity coefficient, porosity distribution, graphene platelets (GPLs) distribution, geometrical and boundary conditions on vibration behavior of porous nanocomposite plates. It is observed that the maximum vibration frequency obtained in the case of symmetric porosity and GPL distribution, while the minimum vibration frequency is obtained using uniform porosity distribution.

• Membrane Journal
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• v.22 no.3
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• pp.191-200
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• 2012

New composite membranes were manufactured by impregnating post-sulfonated poly(arylene ether sulfone)s containing perfluorocyclobutane (PFCB) groups into porous polytetrafluoroethylene (PTFE) films. Two kinds of post-sulfonated poly(arylene ether sulfone)s with two different monomer ratios (sulfonable biphenylene monomer : non-sulfonable sulfonyl monomer = 6 : 4, 4 : 6) were first prepared through three synthetic steps: synthesis of trifluorovinylether-terminated monomers, thermal cycloaddition polymerization and post-sulfonation using chlorosulfonic acid (CSA). The composite membranes were then prepared by adjusting the concentrations (5~20 wt%) of the resulting copolymers impregnated in the PTFE films. The water uptake, ion exchange capacity (IEC) and ion conductivity of the composite membranes were characterized and compared with their unreinforced dense membranes and Nafion. All the synthesized compounds, monomers and polymers were characterized by $^1H$-NMR, $^{19}F$-NMR and FT-IR and the composite membranes were observed with scanning electron micrographs (SEM).

• Bulletin of the Korean Chemical Society
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• v.25 no.9
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• pp.1371-1378
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• 2004

A porous stainless steel (SUS) as a substrate of silica composite membranes for hydrogen purification was used to improve mechanical strength of the membranes for industrial application. The SUS support was successfully modified by using submicron Ni powder, $SiO_2$ sols with particle size of 500 nm and 150 nm in turns. Silica top layer was coated on the modified supports under various preparation conditions such as calcination temperature, dipping time and repeating number of dipping-drying process. The calcination temperature for proper sintering was between H ttig temperature and Tamman temperature of the coating materials. Maximum hydrogen selectivity was investigated by changing dipping time. As repeating number of dipping-drying process increased, permeances of nitrogen and hydrogen were decreased and $H_2/N_2$ selectivity was increased due to the reduction of non-selective pinholes and mesopores. For the silica membrane prepared under optimized conditions, permeance of hydrogen was about $3\;{\times}\;10^{-5}\;cm^3{\cdot}cm^{-2}{\cdot}s^{-1}{\cdot}cmHg^{-1}$ combined with $H_2/N_2$ seletivity of about 20.

• Steel and Composite Structures
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• v.42 no.6
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• pp.805-826
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• 2022

The free and live load-forced vibration behaviour of porous functionally graded (PFG) higher order nanobeams in the thermal and magnetic fields is investigated comprehensively through this work in the framework of nonlocal strain gradient theory (NLSGT). The porosity effects on the dynamic behaviour of FG nanobeams is investigated using four different porosity distribution models. These models are exploited; uniform, symmetrical, condensed upward, and condensed downward distributions. The material characteristics gradation in the thickness direction is estimated using the power-law. The magnetic field effect is incorporated using Maxwell's equations. The third order shear deformation beam theory is adopted to incorporate the shear deformation effect. The Hamilton principle is adopted to derive the coupled thermomagnetic dynamic equations of motion of the whole system and the associated boundary conditions. Navier method is used to derive the analytical solution of the governing equations. The developed methodology is verified and compared with the available results in the literature and good agreement is observed. Parametric studies are conducted to show effects of porosity parameter; porosity distribution, temperature rise, magnetic field intensity, material gradation index, non-classical parameters, and the applied moving load velocity on the vibration behavior of nanobeams. It has been showed that all the analyzed conditions have significant effects on the dynamic behavior of the nanobeams. Additionally, it has been observed that the negative effects of moving load, porosity and thermal load on the nanobeam dynamics can be reduced by the effect of the force induced from the directed magnetic field or can be kept within certain desired design limits by controlling the intensity of the magnetic field.

• Applied Chemistry for Engineering
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• v.26 no.3
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• pp.239-246
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• 2015

The hybridization of carbon nano-materials enhances the efficiency of each function of the resulting structure or composites. Also, the addition of non-carbon elements to nanomaterials modifies the electrochemical properties. Electrodes combining porous carbon nanofibers (CNFs) and metal oxides benefit from the combination of the double-layer capacitance of the CNFs and the pseudocapacitive character associated with the surface redox-type reactions. Consequently, they demonstrate superior supercapacitor performance in terms of high capacitance, high energy/power efficiency and high rate capability. This paper presents a comprehensive review of the latest advances made in the development and application of various metal oxide/CNF composites (CNFCs) to supercapacitor electrodes.

• Bulletin of the Korean Chemical Society
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• v.32 no.4
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• pp.1321-1326
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• 2011

In this work, the effects of different surface functional groups on the elemental mercury adsorption of porous carbons modified by chemical treatments were investigated. The surface properties of the treated carbons were observed by Boehm's titration and X-ray photoelectron spectroscopy (XPS). It was found that the textural properties, including specific surface area and pore structures, slightly decreased after the treatments, while the oxygen content of the ACs was predominantly enhanced. Elemental mercury adsorption behaviors of the acidtreated ACs were found to be four or three times better than those of non-treated ACs or base-treated ACs, respectively. This result indicates that the different compositions of surface functional groups can lead to the high elemental mercury adsorption capacity of the ACs. In case of the acid-treated ACs, the $R_{C=O}/R_{C-O}$ and $R_{COOH}/R_{C-O}$ showed higher values than those of other samples, indicating that there is a considerable relationship between mercury adsorption and surface functional groups on the ACs.

• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.502-508
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• 1999

We prepared non-porous membrane on the $Al_2O_3$ substrate with the different pore by the size by the plasma polymerization of $CHF_3$. We studied the permeability characteristics of membrane by Ar treatment and the effect of substrate pore size on gas permeation mechanism. The selectivity was increased with Ar plasma treatment time and rf-power near the substrate to the cathode while the permeability was decreased. It was observed that the solution-diffusion model would be applied to non-porous layers while it is applied Knudsen diffusion model to the substrate. From the experimental observation, it could be concluded that the pore size of $Al_2O_3$ membrane influenced on the permeability and the selectivity.

• Journal of environmental and Sanitary engineering
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• v.13 no.2
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• pp.147-155
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• 1998

In this study, we prepared non-porous plasma membrane for having high permeability and selectivity and this membrane was deposited on the $Al_{2}O_{3}$ membrane by using $CHF_{3}$ & $SiH_{4}$ monomer. Also, we investigated for the permeation characteristics of the plasma polymer membrane by Ar plasma treatment. When the position of substrate was near cathode, the selectivity was increased with Ar plasma treatment time and rf-power. The pore size of $Al_{2}O_{3}$ membrane had an effect on the permeability and the position of substrate affected selectivity.