• Title/Summary/Keyword: Non-OPC

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원전 폐콘크리트의 방사성 폐기물 처분용 고화제로의 활용을 위한 고화체 특성 평가 (Characteristics Evaluation of Solidifying Agent for Disposal of Radioactive Wastes Using Waste Concrete Powder)

  • 서은아;이호재;권기현;김도겸
    • 한국건설순환자원학회논문집
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    • 제9권4호
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    • pp.451-459
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    • 2021
  • 이 연구에서는 원전 해체 콘크리트에서 분리된 폐콘크리트 미분말을 방사성 폐기물용 고화제로 재활용하기 위한 성능평가를 수행하였다. 원전 해체 콘크리트에서 분리된 폐콘크리트 미분말을 모사한 시료를 제작하였으며, 주요 변수는 결합재 종류와 제올라이트 혼입율이었다. 고화제 특성평가는 유동성과 압축강도 및 비방사성 세슘에 대한 침출 저항성을 수행하였다. 폐콘크리트 모사시료의 압축강도는 제올라이트 혼입율이 증가함에 따라 증가하였으며, 제올라이트가 5% 이상 혼입된 고화제는 인수기준 대비 1.4~1.7배 높은 압축강도를 나타내었다. 모든 시험체의 세슘 침출지수는 6 이상으로 인수기준을 만족하였으며, SA의 침출지수는 OPC 대비 1.47~1.63배 높게 나타났다. 특히, 제올라이트 5% 치환 고화제의 28일 이후 평균 침출지수는 9.15으로 OPC 대비 약 6.4% 향상되었으며, 전 기간 동안 안정적인 성능을 나타내어 제올라이트가 세슘이온에 대한 침출저항성 향상에 효과적임을 확인하였다.

비소성시멘트를 사용한 고강도 콘크리트의 조기강도 추정 연구 (A Study on Early Strength Estimation of High-strength Concrete Using Non-sintering Cement (NSC))

  • 김한식;임상준;강인석;박무영;문경주;정상진
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.609-612
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    • 2006
  • The quality of the concrete compression strength can be determined after the passage of 28 days, but if any defect is found the quality of concrete after that length of time, there can be serious problems in dismantling and repair. Thus, in response to the use of concrete using non sintering cement (NSC), the present study purposed to propose a method of managing the strength of high strength concrete using NSC in comparison with high strength concrete using ordinary Portland cement (OPC) through early strength estimation using microwave, which enables the quick estimation of the strength of high strength concrete using NSC.

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비소성 시멘트 경화체의 공극구조 (Pore Structure of Non-Sintered Cement Matrix)

  • 문경주;박원춘;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.329-332
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    • 2004
  • This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also investigates the pore structure of NSC Matrix. The result of experiment of pore structure properties, showed no considerable difference for total pore volume by cement mixing ratio but shows a large distinction in distribution of pore diameter. On the whole, pore-diameter of paste of NSC show that occupation ratio of pore diameter below 10mm is larger and is smaller than OPC and BFSC at pore diameter of over 10nm. Such a reason is that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

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비소성 시멘트 경화체내 염화물 고정화 특성 (The Characteristics of Chloride Fixation in Non-Sintering Cement Matrix)

  • 문경주;형원길;박원춘;소승영;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.725-728
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    • 2006
  • This research investigates the characteristics of chloride fixation in non-sintering cement(NSC) matrix. NSC was manufactured by adding phosphogypsum and slack lime to granulated blast furnace slag as sulfate and alkali activators. As a result, the concentration of chloride ion in pore solution of NSC-solidified matrix is more low than that of OPC-solidified matrix containing the same chloride content in cement paste. Also, the concentration of chloride ion in pore solution of NSC-solidified matrix is similar with that of BSC-solidified matrix containing the same chloride content in cement paste.

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The non-shrinkage grout to use ground fly ash as admixture

  • Kim, Yoo;Chu, Yong-Sik;Seo, Sung-Kwan;Kim, Jang-ho Jay
    • Journal of Ceramic Processing Research
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    • 제19권6호
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    • pp.509-513
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    • 2018
  • This study uses fly ash for non-shrinkage grout in order to develop strength of grout and improve its durability. We grind fly ash to the extent of $7,000cm^2/g$ and use ground fly ash and raw fly ash respectively at the proportion of 10%, 20%, 30% instead of OPC and compare the results drawn on the condition of each proportion. As a mixed material of grout, EVA and water-reducing agent is added in order to prevent bleeding and improve segregation resistance, CSA is added with a view to preventing drying shrinkage and improving early strength property. In regard to flow and flow time test for analyzing and evaluating workability, it is revealed that grouts of all mix proportions except raw fly ash 30% mix proportion satisfy all performance criteria. With regard to length change rate, grout with no admixture shows the highest shrinkage rate, but the rate is 0.0005%, extremely insignificant rate. As material age increases, compressive strength of two grouts, that is to say ground fly ash 10% and 20%-used grouts, exceed that of grout with no admixture or show high-level compressive strength.

고로슬래그 미분말과 플라이애시를 사용한 비소성 시멘트 모르타르의 촉진 탄산화에 따른 압축 강도 특성 (Properties of Compressive Strength after Accelerated Carbonation of Non-Sintered Cement Mortar Using Blast Furnace Slag and Fly Ash)

  • 류지수;나형원;형원길
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
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    • pp.297-298
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    • 2023
  • In the concrete industry, efforts are being made to reduce CO2 emissions, and technologies that collect, store, and utilize CO2 have recently been studied. This study analyzed the change in compressive strength after the accelerated carbonation test of Non-Sintered Cement(NSC) mortar. Type C Fly Ash and Type F Fly Ash were mixed in a 1:1 ratio and then mixed with Blast Furnace Slag fine powder to produce NSC. The mortar produced was cured underwater until the target age. In addition, an accelerated carbonation test was conducted under the condition of a concentration of 5 (±1.0%) of CO2 gas for 14 days. The mortar compressive strength was measured before and after 14 days of accelerated carbonation test based on the 7th and 28th days of age. As a result of the experiment, the compressive strength was improved in all binder. In general, the compressive strength of NSC mortar subjected to the accelerated carbonation test was similar to that of Ordinary Portland Cement(OPC) mortar not subjected to the accelerated carbonation test.

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순환자원 활용 지반차수재의 노후저수지 보강 적용사례 및 성능검증에 관한 연구 (A Study on Application and Performance Verification of Aged Reservoir Reinforcing Method using Ground Injection Material of Utilizing Circulation Resources.)

  • 박성훈;서세관;송상훤
    • 한국농촌건축학회논문집
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    • 제22권3호
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    • pp.17-24
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    • 2020
  • Reservoirs, which make up most of South Korea's reservoirs, are located in rural areas. In the case of rural reservoirs, about 75% have been reported over 50 years old aged reservoirs constructed before the 1960s. Reservoirs are important facilities that store and supply water necessary for daily life. However, if it is destroyed, the reservoir can cause a lot of damage, so continuous management is necessary. As a method for strengthening old reservoirs, a method using cement has been widely applied. However, OPC is a product that uses a lot of carbon dioxide and natural resources. Therefore, the amount of cement should be reduced. Against this background, in this study, the ground injection material of utilizing circulation resources was applied to the site. Applied reservoirs have been around for 75 years and leaks have occurred in some sections. The application method was constructed in two rows, up to a depth of 12m. After reinforcement, the electrical resistivity test was conducted three times. As a result, similar resistance was shown at 1 month after construction. And after 6 months, the saturation area decreased. And the performance after reinforcing the aged reservoir was examined. As a result of the review, this study confirmed that the applicability was equivalent to that of OPC, and the excellent performance of reinforcing the aged reservoir was shown.

안료의 혼입에 따른 블랙모르타르의 유동성 및 응결시간에 관한 연구 (A Study of Black Mortar Fluidity and Setting Time by Mixing of Pigment)

  • 장홍석;문경주;소승영;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.673-676
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    • 2008
  • 최근 미관에 대한 새로운 요구가 증대되고, 건축가들의 의도에 따라 각종 색상, 질감, 형태 등의 디자인요소를 콘크리트 구조물에 반영하여 아름다움을 추구하는 경향이 증가하고 있다. 특히 안료를 혼입하여 착색한 컬러콘크리트는 콘크리트가 가지는 본래의 구조적 기능뿐만 아니라 그 자체를 마감재로 활용함으로써 고유한 질감과 색감을 적극적으로 외관에 활용한 것으로 그 수요가 증가하고 있는 추세이다. 그러나 이러한컬러 콘크리트는 소요의 색상발현을 위하여 무기계 콘크리트용 안료의 사용이 필수적이며, 이러한 안료의 혼입으로 인하여 컬러콘크리트는 물성이 변하게 된다. 이에 본 연구는 일반 OPC(Ordinary Portland Cement, 이하 OPC), 백색시멘트(White Cement, 이하 WC), 산업부산물을 활용한 백시멘트(Non-White Cement, 이하 NWC)를 바인더로 색상의 가장 기본이 되는 검정 모르타르 시험체를 제조하여 안료의혼입에 따른 모르타르의 굳지 않은 콘크리트의 슬럼프 플로우 시험과 모르타르 관입저항 시험을 통한 응결 시간 시험을 진행하여 안료를 혼입한 검정 모르타르의 기초 물성을 평가하였다. 연구 결과 안료의 혼입량의 증가에 따라 슬럼프 플로우 값은 저하하는 경향을 보였으며, 특히 사용하는 안료의 종류에 따라 큰 차이를 보였다. 또한 색상 발현을 위해 안료의 혼입량이 증가할수록 비표면적과 응집력 등 사용된 안료의 특성에 따라 초결, 종결 시간이 변화함을 확인 하였다.

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고밀도 섬유 시멘트 복합체 불연특성 개선에 관한 연구 (A Study on Improving the Non-Combustible Properties of High-Density Fiber Cement Composites)

  • 송태협;장경필
    • 한국건설순환자원학회논문집
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    • 제9권4호
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    • pp.521-528
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    • 2021
  • 진공 압출성형 방법에 의하여 생산되는 섬유 시멘트 복합체는 연속 생산이 가능하고 고밀도 무기질 재료의 구성이 가능한 제품이다. 보강섬유로 사용하고 있는 폴리프로필렌과 펄프의 연소에 따른 가스의 발생과 이로 인하여 불연성능 시험 중 중심부에 지속적으로 불꽃이 발생하여 성능을 충족하지 못하는 경우가 발생한다. 본 연구에서는 불연 특성 개선을 위하여 내알칼리 성능을 개선한 ARG(Alkali resistant glass)섬유를 보강섬유로 사용하여 시험체를 제조하고 성능 평가를 실시하였다. 섬유량은 부피비를 기준으로 하여 적용하였다. 측정결과 폴리프로필렌을 전량 유리섬유로 대체하고 펄프 사용량을 50% 감소하여 배합할 경우 불꽃은 발생하지 않거나 5초 이내 소화 되는 것을 확인하였다. 패널의 압출성과 생산성, 그리고 경화 후 적정한 인성 및 취성재료의 개선을 위하여 펄프 사용량은 기존 사용량의 50%를 유지하는 것이 바람직하며, 불연성능의 개선을 위하여 별도의 결합재 변경은 필요하지 않은 것으로 확인되었다.

Effects of loading conditions and cold joint on service life against chloride ingress

  • Yang, Keun-Hyeok;Mun, Ju-Hyun;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Computers and Concrete
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    • 제22권3호
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    • pp.319-326
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    • 2018
  • RC (Reinforced Concrete) members are always subjected to loading conditions and have construction joints when constructed on a big scale. Service life for RC structure exposed to chloride attack is usually estimated through chloride diffusion test in sound concrete, however the test is performed without consideration of effect of loading and joint. In the present work, chloride diffusion coefficient is measured in concrete cured for 1 year. In order to evaluate the effect of applied load, cold joint, and mineral admixtures, OPC (Ordinary Portland Cement) and 40%-replaced GGBFS (Ground Granulated Blast Furnace Slag) concrete are prepared. The diffusion test is performed under loading conditions for concrete containing cold joint. Investigating the previous test results for 91 days-cured condition and the present work, changing diffusion coefficients with applied stress are normalized considering material type and cold joint. For evaluation of service life in RC continuous beam with 2 spans, non-linear analytical model is adopted, and service life in each location is evaluated considering the effects of applied stress, cold joint, and GGBFS. From the work, varying service life is simulated under various loading conditions, and the reduced results due to cold joint and tensile zone are quantitatively evaluated. The effect of various conditions on diffusion can provide more quantitative evaluation of chloride behavior and the related service life.