• Bulletin of the Korean Chemical Society
• /
• 제10권6호
• /
• pp.504-509
• /
• 1989

The effect of oxygen-deficiency on the charge distributions and orbital energies for small copper oxide clusters representing the superconducting materials $YBa_2Cu_3O_x (6{\leq}x{\leq}7)$ were investigated by the extended Huckel molecular orbital (EHMO) method with the tight-binding model. Our calculations show +3 oxidation state of Cu(1) in the $CuO_3$ chain and +2 or +1 of Cu(2) in the $CuO_2$ layers for $YBa_2Cu_3O_7$ with the nominal charge of $Cu_3$ = +7 (or +5), while for $YBa_2Cu_3O_6$ +1 oxidation state of Cu(1) and +3 (or +2) of Cu(2) in the $CuO_2$ layers with the nominal charge of $Cu_3$ = +7 (or +5). For $Cu_3O_{12}$ cluster representing $YBa_2Cu_3O_7$ with the nominal charge of $Cu_3$ = +7 the Cu(2) $d_{{x^2}-{y^2}}$ orbitals in the $CuO_2$ layers is a typical Jahn-Teller $d^9$ system with the partial hole and the Cu(1) $d_{{_z2}-{_y2}}$ orbital in the $CuO_3$ chain contains hole occupancy. For $Cu_3O_{10}$ cluster representing $YBa_2Cu_3O_6$ with the nominal charge of Cu = +5 the orbital character of the highest partially occupied MO (HPOMO) and the lowest completely unoccupied MO (LCUMO) of $Cu_3O_{12}$ representing $YBa_2Cu_3O_7$ with the nominal charge of $Cu_3$ = +7 is reversed, and the character of Cu(1) $d{{x^2}-{y^2}}$ orbital of LCUMO of the $Cu_3O_{12} $cluster is vanished. It is suggested that the local crystal field environment of Cu(1) by the oxygens in the Cu(1) chain may play a vital role in conductivity and superconductivity, either alone or through cooperative electronic coupling with the Cu(2) layers in $YBa_2Cu_3O_7.$.

• Steel and Composite Structures
• /
• 제35권6호
• /
• pp.799-813
• /
• 2020

Fatigue cracks of rib-to-deck (RD) joints have been frequently observed in the orthotropic steel decks (OSD) using conventional U-ribs (CU). Thickened edge U-rib (TEU) is proposed to enhance the fatigue strength of RD joints, and its effectiveness has been proved through fatigue tests. In-depth full-scale tests are further carried out to investigate both the fatigue strength and fractography of RD joints. Based on the test result, the mean fatigue strength of TEU specimens is 21% and 17% higher than that of CU specimens in terms of nominal and hot spot stress, respectively. Meanwhile, the development of fatigue cracks has been measured using the strain gauges installed along the welded joint. It is found that such the crack remains almost in semi-elliptical shape during the initiation and propagation. For the further application of TEUs, the design curve under the specific survival rate is required for the RD joints using TEUs. Since the fatigue strength of welded joints is highly scattered, the design curves derived by using the limited test data only are not reliable enough to be used as the reference. On this ground, an experiment-numerical hybrid approach is employed. Basing on the fatigue test, a probabilistic assessment model has been established to predict the fatigue strength of RD joints. In the model, the randomness in material properties, initial flaws and local geometries has been taken into consideration. The multiple-site initiation and coalescence of fatigue cracks are also considered to improve the accuracy. Validation of the model has been rigorously conducted using the test data. By extending the validated model, large-scale databases of fatigue life could be generated in a short period. Through the regression analysis on the generated database, design curves of the RD joint have been derived under the 95% survival rate. As the result, FAT 85 and FAT 110 curves with the power index m of 2.89 are recommended in the fatigue evaluation on the RD joint using TEUs in terms of nominal stress and hot spot stress respectively. Meanwhile, FAT 70 and FAT 90 curves with m of 2.92 are suggested in the evaluation on the RD joint using CUs in terms of nominal stress and hot spot stress, respectively.

• 인터넷정보학회논문지
• /
• 제8권4호
• /
• pp.105-117
• /
• 2007

프로젝트 관리자는 입찰 또는 개발을 성공하기 위해 비용과 일정을 프로젝트 초기 단계에서 보다 정확히 추정해야만 한다. 평균적으로 대부분의 프로젝트들이 수행하고 있는 명목상의 개발기간은 경험법칙, 선형함수 추정경험 또는 개략적 일정 추정표로부터 유도할 수 있다. 명목상 개발기간에는 다양한 경험법칙이 존재하며, 선형함수 모델은 충분한 정보를 제공하지 못하여 특정 규모의 프로젝트에 적합한 개발노력과 일정을 결정하기 어렵다. 본 논문은 개략적 일정 추정표로부터 개발노력과 일정을 유도하는 통계적 회귀분석 모델을 제시하였다. 먼저, 개략적 일정 추정표에서 제시하고 있는 최대 단축기간, 효율적 개발기간과 명목상 개발기간을 재정의 하였다. 다음으로 개발노력과 기간과의 관계를 고찰하고, 개략적 일정추정표에 제시되지 않은 특정 규모의 소프트웨어에 대한 개발노력 추정 모델과 개발노력에 따른 일정을 보다 정확히 추정할 수 있는 모델을 제시하였다. 제시된 회귀분석 모델은 기존의 방법들과 비교하여 상대오차를 최대 2%까지 줄이는 효과를 얻었다. 또한, 특정 규모의 소프트웨어에 대해서도 개발노력과 일정을 추정할 수 있었다.

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 1994년도 Proceedings of the Korea Automatic Control Conference, 9th (KACC) ; Taejeon, Korea; 17-20 Oct. 1994
• /
• pp.548-552
• /
• 1994

The robust compensation controller, which has been proposed by one of the authors and is based on the fundamental principle of making the plant follow the reference model, consists of the reference model and the robust compensator. The reference model is constructed by using the nominal model of the plant and determines the input-output properties of the resultant system. The robust compensator is obtained as a solution of the mixed sensitivity problem in H infinity control theory. Therefore the resultant system is of low sensitivity and robust stability. In the case where uncertainty does not occur in the plant, the plant follows perfectly the reference model. Therefore, in the case where uncertainty occurs in the plant, we propose the system configuration which improves the following accuracy without replacing the 개bust compensator but by identifying, the plant and reconstructing the reference model.

• 대한전기학회논문지:시스템및제어부문D
• /
• 제52권8호
• /
• pp.462-470
• /
• 2003

This paper presents an algorithm of identifying parametric uncertainty by way of an interval model. For a given set of frequency response data from an uncertain linear SISO system of which the upper and the lower bounds of both magnitude and phase responses are represented, the proposed algorithm consists of two main parts: first, the nominal model is identified by using Least Square Estimation (LSE), and then an interval model is constructed by expanding the extremal properties of interval systems, so that tightly enclose the given envelopes within those of interval model. Two numerical examples are given to demonstrate and verify the developed algorithm. The identified interval model can be used for evaluating the worst case performance and stability margins against parametric uncertainty by using some extremal properties on interval systems.

• Journal of Advanced Marine Engineering and Technology
• /
• 제24권1호
• /
• pp.94-103
• /
• 2000

This paper describes the model identification and the discrete-time sliding mode control of electro-hydraulic servo systems which are composed of servo valves, double-rod cylinder and load mass. The controlled plant is identified as a 3th-order discrete-time ARMAX model obtained from the prediction error algorithm, where a nominal model and modeling errors are zuantitatively constructed. The discrete sliding mode controller for 3th-order ARMAX model is designed in discrete-time domain, where all states are observed from Kalman filter. The discrete sliding mode controller has better tracking performance than that obtained from continuous-time sliding mode controller, in experiment.

• 한국정밀공학회지
• /
• 제23권4호
• /
• pp.44-51
• /
• 2006

This paper addresses sliding mode control of the anti-lock braking system (ABS) with a disturbance observer for model uncertainties such as vehicle parameter variation, un-modeled dynamics, and external disturbances. By using a nominal vehicle model, a sliding mode controller is designed to achieve a desired wheel slip ratio for ABS control. To compensate the model uncertainties, a disturbance observer is introduced with the help of a transfer function of a hydraulic brake dynamics. A proposed sliding mode controller with a disturbance observer is evaluated through simulations for model uncertainties. The simulation results show that the disturbance observer can enhance performances of sliding mode control for ABS.

• 한국철도학회논문집
• /
• 제10권4호
• /
• pp.409-413
• /
• 2007

A dynamically scaled model of the catenary with a nominal scaling factor of 18.5:1 is designed and constructed. The motivation for developing such a model is the great difficulty of making accurate measurements on the full-scale catenary and the difficulty of making experimental modifications to it. The scaled model is designed to be dynamically equivalent to the full scale catenary with respect to the mass and elastic strength. The scaled model is partially verified by comparing linear vibration and wave characteristics with those predicted by the simulation study.

• International Journal of Fuzzy Logic and Intelligent Systems
• /
• 제6권4호
• /
• pp.331-334
• /
• 2006

Original Support Vsctor Machines (SVMs) by Vapnik were used for binary classification problems. Some researchers have tried to extend original SVM to multiclass classification. However, their studies have only focused on classifying samples into nominal categories. This study proposes a novel multiclass SVM model in order to handle ordinal multiple classes. Our suggested model may use less classifiers but predict more accurately because it utilizes additional hidden information, the order of the classes. To validate our model, we apply it to the real-world bond rating case. In this study, we compare the results of the model to those of statistical and typical machine learning techniques, and another multi class SVM algorithm. The result shows that proposed model may improve classification performance in comparison to other typical multiclass classification algorithms.

• 로봇학회논문지
• /
• 제19권1호
• /
• pp.8-15
• /
• 2024

This paper proposes a linear model predictive control of 6-DOF remotely operated underwater vehicles using nonlinear robust internal-loop compensator (NRIC). First, we design a integrator embedded linear model prediction controller for a linear nominal model, and then let the real model follow the values calculated through forward dynamics. This work is carried out through an NRIC and in this process, modeling errors and external disturbance are compensated. This concept is similar to disturbance observer-based control, but it has the difference that H_∞ optimality is guaranteed. Finally, tracking results at trajectory containing the velocity discontinuity point and the position tracking performance in the disturbance environment is confirmed through the comparative study with a traditional inverse dynamics PD controller.