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A Study on Degradation of Nitrogen Compounds by Biofilm Reactor Packed with Porous Media (다공성 담체를 이용한 생물막 반응조의 질소화합물 분해에 관한 연구)

  • Cho, Hae-Mi;Kim, So-Yeon;Yoon, Ji-Hyun;Han, Gee-Bong
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.776-780
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    • 2007
  • A biofilm reactor packed with porous media was investigated for nitrogen removal of synthetic wastewater. The effect of different loading rates on the nitrification was sustained to be steady state with stable efficiency of 50~60% in the range of $0.0083{\sim}0.017gNH_4-N/gMLVSS{\cdot}day$ of F/MN ratio and $1{\sim}2kgNH_4-N/m^3{\cdot}day$ of media volumetric loading rate. However, nitrification efficiency was rapidly decreased to 25~30% as F/MN ratio and media volumetric loading rate were increased to the range of $0.025{\sim}0.034gNH_4-N/gMLVSS{\cdot}day$ and $3{\sim}4kgNH_4-N/m^3{\cdot}day$, respectively. Also the consumption rate of alkalinity was higher under 8 hours of HRT than unter 6 hours of HRT. Accordingly the influent loading rate variation by detention time with influent flow influenced more on the nitrification efficiency than the influent loading rate variation by the influent concentration did. The temperature effect on the nitrification showed 25% higher in summer than in winter as the results reported by other researchers who reported that the nitrification efficiency in biofilm showed 20% increase from 55% to 75% when the temperature was raised from $20^{\circ}C$ to $25^{\circ}C$. Denitrification with sulfur-media showed 90% removal efficiency under steady-state with no effect from the increase of influent concentration and empty bed contact time (EBCT) change such as EBCT was decreased from 8.4 hr to 4.3 hr and $NO_3-N$ loading rate was changed within the range of $0.1{\sim}0.4kgNO^3-N/m^3{\cdot}day$. Accordingly Denitrification with sulfur-media is feasible for post denitrification at the concentration less than $80mgNO^3-N/L$.

KEPCO-China Huaneng Post-combustion CO2 Capture Pilot Test and Cost Evaluation

  • Lee, Ji Hyun;Kwak, NoSang;Niu, Hongwei;Wang, Jinyi;Wang, Shiqing;Shang, Hang;Gao, Shiwang
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.150-162
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    • 2020
  • The proprietary post-combustion CO2 solvent (KoSol) developed by the Korea Electric Power Research Institute (KEPRI) was applied at the Shanghai Shidongkou CO2 Capture Pilot Plant (China Huaneng CERI, capacity: 120,000 ton CO2/yr) of the China Huaneng Group (CHNG) for performance evaluation. The key results of the pilot test and data on the South Korean/Chinese electric power market were used to calculate the predicted cost of CO2 avoided upon deployment of CO2 capture technology in commercial-scale coal-fired power plants. Sensitivity analysis was performed for the key factors. It is estimated that, in the case of South Korea, the calculated cost of CO2 avoided for an 960 MW ultra-supercritical (USC) coal-fired power plant is approximately 35~44 USD/tCO2 (excluding CO2 transportation and storage costs). Conversely, applying the same technology to a 1,000 MW USC coal-fired power plant in Shanghai, China, results in a slightly lower cost (32~42 USD/tCO2). This study confirms the importance of international cooperation that takes into consideration the geographical locations and the performance of CO2 capture technology for the involved countries in the process of advancing the economic efficiency of large-scale CCS technology aimed to reduce greenhouse gases

Hebei Spirit Oil Spill Exposure and Subjective Symptoms in Residents Participating in Clean-Up Activities

  • Cheong, Hae-Kwan;Ha, Mi-Na;Lee, Jong-Seong;Kwon, Ho-Jang;Ha, Eun-Hee;Hong, Yun-Chul;Choi, Ye-Yong;Jeong, Woo-Chul;Hur, Jong-Il;Lee, Seung-Min;Kim, Eun-Jung;Im, Ho-Sub
    • Environmental Analysis Health and Toxicology
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    • v.26
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    • pp.7.1-7.9
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    • 2011
  • Objectives: This study was conducted to examine the relationship between crude oil exposure and physical symptoms among residents participating in clean-up work associated with the Hebei Spirit oil spill, 2007 in Korea. Methods: A total of 288 residents responded to a questionnaire regarding subjective physical symptoms, sociodemographic characteristics and clean-up activities that occurred between two and eight weeks after the accident. Additionally, the urine of 154 of the respondents was analyzed for metabolites of volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs) and heavy metals. To compare the urinary levels of exposure biomarkers, the urine of 39 inland residents who were not directly exposed to the oil spill were analyzed. Results: Residents exposed to oil remnants through clean-up work showed associations between physical symptoms and the exposure levels defined in various ways, including days of work, degree of skin contamination, and levels of some urinary exposure biomarkers of VOCs, metabolites and metals, although no major abnormalities in urinary exposure biomarkers were observed. Conclusions: This study provides evidence of a relationship between crude oil exposure and acute human health effects and suggests the need for follow-up to evaluate the exposure status and long-term health effects of clean-up participants.

Anionic Effect on Photocatalytic Decomposition of Benzene (벤젠의 광촉매분해반응에 대한 음이온효과)

  • Kim, Young-Hee;Kim, Tae-Gyun;Lee, Chun-Sik
    • Clean Technology
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    • v.6 no.2
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    • pp.107-111
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    • 2000
  • In the photocatalytic degradation of benzene using $TiO_2$ as photocatalyst, anionic effects were investigated. When near UV and visible light was irradiated, the photodegradation of benzene was slightly increased in which $S_2O{_8}^{2-}$ or $NO{_3}^-$ coexisted with $TiO_2$. But $NO{_2}^-$ or $Cl^-$ diminished it remarkably, because these anions scavenged hydroxyl radical. While in the case of UV light irradiation, $S_2O{_8}^{2-}$ and $NO{_3}^-$ enhanced photodegradation of benzene due to photosensitization of these anions, but $NO{_2}^-$ or $Cl^-$ diminished it little.

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CFD-based Fire Accident Impact Analysis in Clean Room for semiconductor PR Process (반도체 PR 공정의 클린룸내 CFD 기반 화재 사고 영향 분석)

  • Chun, Kwang-Su;Yi, Jinseok;Park, Myeongnam
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.35-44
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    • 2021
  • The PR (Photo Resist) process in the semiconductor process is a process that uses a mixture of flammable substances. Due to the process equipment is installed in a clean room and when flammable substances leak, there is a high risk of suffocation, fire, and explosion. It is necessary to analyze the impact of accidents that may occur during operation and to evaluate whether the safety of workers can be guaranteed. In this study, the value of radiant heat and temperature change at the monitor point set up virtual inside the clean room was confirmed through CFD simulation of 10 leak and fire scenarios using the FLACS CFD - Fire Module. A fire that occurs inside a clean room transfers high radiant heat to the inter-story structure, but its scope is quite limited, and it is unlikely that it will collapse in a single fire accident. There was no scenario in which two stairs leading to the exit were exposed to high radiant heat at the same time due to a fire accident, therefore workers were able to escape in case of a fire. In addition, it was confirmed that the level of radiant heat and temperature rise rapidly decreased as they moved downstairs. According to the API 520 standard, workers exposed to 6.31 kW/m2 of radiant heat that workers can withstand for 30 seconds were confirmed that it was possible to sufficiently escape from the inside.

Numerical Simulation of the Odor Spreading in a Factory (공장에서 퍼지는 냄새에 관한 수치계산적 연구)

  • Vincent, Lijo;Song, Eun-Hwa;Nam, Hyun-Kyu;Shin, Choon-Sik;Kim, Heuy-Dong
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2540-2543
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    • 2008
  • Liquid crystal displays (LCD's) are continuously coated with some chemicals in the clean room of a factory. Spreading of these chemicals is causing serious problems both in controlling clean room quality as well as to the workers inside the factory. It is required to alleviate or properly control the offensive odor which is mainly composed of propylene glycol mono ethyl acetate, novolak resin and photo active compound. The control strategy employed is to bleed the offensive odor gas out the clean room. A full scale 3D CFD model was created with anisotropic porous media, chemical species transport with no volumetric reaction, and thermal diffusion with propane gas (tracer gas) to simulate the odor spreading. A segregated implicit solver with standard k-$\varepsilon$ model is employed. The detailed CFD analysis made it possible to develop an effective method of ventilating the coater room and optimizing their capacities.

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A Basic Study On the Estimative Direction of Responsible Ability for HNS National Contingency Plan Using Powersim (파워심을 이용한 HNS 국가방제기본계획의 방제능력 산정방향에 관한 기초 연구)

  • Lee Sang-Bae;No Chang-Gyun
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2006.06b
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    • pp.209-214
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    • 2006
  • This paper desires to assist ensuring of propriety clean-up equipment for clean-up shore or sea of pollution, there is not that responsible ability of a nation has an amount of skimmer or the length of boom. responsible ability of a nation must express overall evaluation what is considering quickly, system, and economizing in addition to an amount or clean-up equipment. responsible ability of a nation is complication and it's mutual relation of each other factor therefore responsible capacity of a nation is expressed using powersim with system dynamics theory.

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Atmospheric Corrosion Behavior of Carbon Steel by the Outdoor Exposure Test for 10 Years in Korea

  • Yoo, Y.R.;Choi, S.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.21 no.3
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    • pp.184-199
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    • 2022
  • Steel was exposed in an atmospheric environment, and atmospheric environmental factors that include chloride, humidity, SO2, NO2 etc. induced the corrosion of steel. Corrosivity categories classified by SO2 and chloride deposition rate were low, but those classified by TOW were high in the Korean Peninsula, and on these environmental categories, the corrosivity of atmospheres classified by corrosion rate in carbon steel was low medium, C2-C3, and medium, C3 for zinc, copper, and aluminum. This work performed the outdoor exposure test for 10 years at 14 areas in Korea and calculated the atmospheric corrosion rate of carbon steel. The atmospheric corrosion behavior of carbon steel is discussed based on the various corrosion factors. When the corrosion product forms on carbon steel by atmospheric corrosion, cracks may also be formed, and through these cracks, the environmental factors can penetrate into the interior of the product, detach some of the corrosion products and finally corrode locally. Thus, the maximum corrosion rate was about 7.3 times greater than the average corrosion rate. The color difference and glossiness of carbon steel by the 10 year-outdoor exposure tests are discussed based on the corrosion rate and the environmental factors.

Atmospheric Corrosion Behavior of Weathering Steel Exposed to the Outdoors for 10 Years in Korea

  • Yoo, Y.R.;Choi, S.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.21 no.4
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    • pp.258-272
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    • 2022
  • Steel structures exposed to the outdoors experienced several types of corrosion, which may reduce their thickness. Since atmospheric corrosion can induce economic losses, it is important to consider the atmospheric corrosion behavior of a variety of metals and alloys. This work performed outdoor exposure tests for 10 years at 14 areas in Korea and calculated the atmospheric corrosion rate of weathering steel. This paper discussed the atmospheric corrosion behavior of weathering steel based on various corrosion factors. The average corrosion rates in coastal, industrial, urban, and rural areas were found to range from (2.83 to 4.23) ㎛/y, (2.99 to 4.23) ㎛/y, (1.72 to 3.14) ㎛/y, and (1.57 to 2.85) ㎛/y respectively. It should be noted that the maximum corrosion rate was about 6.0 times greater than the average corrosion rate. Regardless of the exposure sites, the color differences were increased, but the glossiness was reduced and there was no relationship between the corrosion rate and environmental factors and the glossiness.

Sinus mucosal healing pattern according to pterygomaxillary disjunction type after Le Fort I osteotomy

  • Jang, Tae-Seok;Lee, Seung-Woo;Lee, Baek-Soo;Shim, Gyujo;Seon, Suyun;Ohe, Joo-Young
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.48 no.5
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    • pp.292-296
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    • 2022
  • Objectives: During Le Fort I osteotomy, the separation of the pterygomaxillary junction (PMJ) is a difficult procedure for most surgeons because it is invisible. In this process, damage to the posterior structures constituting the sinus or those adjacent to it, including the maxillary sinus posterior wall and pterygoid plate, may occur. We would like to investigate the effects of this on the inside of the maxillary sinus after surgery and whether there are complications. Materials and Methods: One-hundred patients who underwent Le Fort I osteotomy from 2013 to 2020 using cone-beam computed tomography images were classified into two groups (clean-cut type and fractured type) according to the PMJ cutting pattern. In addition, the mucosal thickness in the maxillary sinus was divided into preoperative, postoperative three months, one year, and the change over the course of surgery was evaluated retrospectively. Results: Of the total 100 cases, the clean-cut type numbered 28 cases and the fractured type totaled 72 cases. Among the fracture types, part of the sinus wall and the pterygoid plate were broken in 69 cases, and the maxillary sinus posterior wall was detached in three cases. There was no statistically significant difference in sinus mucosal thickening between the clean-cut type and fractured type of the PMJ, three months and one year after surgery between the two groups. However, there was a significant difference in sinus mucosal thickness at postoperative one year in the case where a partial detachment of the maxillary sinus posterior wall occurred compared to not. Conclusion: Even if there is some damage to the structures behind the PMJ, it may not be reasonable to spend some time on the PMJ separation process considering the overall postoperative complications, if there is no significant difference inside the sinus, or increased probability of postoperative complications.