• 한국환경농학회지
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• 제39권3호
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• pp.237-245
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• 2020

BACKGROUND: The closed chamber method is the most commonly used for measuring greenhouse gas emissions from upland fields. This method has the advantages of being simple, easily available and economical. However, uncertainty estimation is essential for accurate assessment of greenhouse gas emissions and verification of emission reductions. The nitrous oxide emissions from upland field is very important for the nitrogen budget in the agriculture sectors. Although assessment of uncertainty components affecting nitrous oxide emission from upland field is necessary to take account of dispersion characteristics, research on these uncertainty components is very rare to date. This study aims at elucidation of influencing factors on measurement uncertainty of nitrous oxide concentrations measured by an automated open closed chamber method from upland field. METHODS AND RESULTS: The nitrous oxide sampling system is located in the upland field in Gyeonggi-do Agricultural Research and Extension Services (37°13'22"N, 127°02'22"E). The primary measurement uncertainty components influencing nitrous oxide concentrations (influencing factors) investigated in this research are repeatability, reproducibility and calibration in the aspects of nitrous oxide sampling and analytical instrumentation. The magnitudes of the relative standard uncertainty of each influencing factor are quantified and compared. CONCLUSION: Results of this study show what influencing factors are more important in determination of nitrous oxide concentrations measured using the automated open closed chambers located in the monitoring site. Quantifying the measurement uncertainty of the nitrous oxide concentrations in this study would contribute to improving measurement quality of nitrous oxide fluxes.

• 한국기후변화학회지
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• 제7권4호
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• pp.427-432
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• 2016

Nitrous oxide is one of the main sources of greenhouse gases and its concentration has increased from 273 ppb in 1,750 to 315 ppb in 2005. Specially, nitrogen fertilizer used in agricultural soils is considered as an important source of atmospheric $N_2O$ emission. This study was conducted to estimate the difference of nitrous oxide emission as chamber position on furrow and ridge and crop existence in gas sampling chamber on upland. Four treatments used in this experiment were (1) no-fertilizer without crop in chamber on ridge, (2) fertilizer application without crop in chamber on ridge, (3) fertilizer application with crop in chamber on ridge, (4) fertilizer application without crop in chamber on ridge and furrow. Nitrous oxide emission at fertilizer application with crop in chamber on ridge were the highest while were the lowest at no-fertilizer without crop in chamber on ridge. There was no significant difference of nitrous oxide emission by chamber position, but total emission by crop existence in chamber was significant difference. Therefore, in order to estimate greenhouse gases emission using chamber method in upland, it should be considered in correlation with crop existence in chamber and characteristic changes like as the soil moisture, microbial flora by crop growth stage.

• 유기물자원화
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• 제31권2호
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• pp.19-38
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• 2023

하수처리장에서 생물학적 질소 제거를 위한 질산화, 탈질 과정 중 6대 온실가스 중 하나인 아산화질소가 발생한다. 이번 연구에서는 온실가스 발생량을 정량할 수 있는 컴퓨터 시뮬레이션 프로그램인 EQPS를 이용해 합류식 하수를 처리하는 MLE 공법 하수처리장의 내부반송유량, 수온 그리고 유입수의 일차침전지 by-pass %에 따라 아산화질소가 가장 적게 발생하는 운전 조건을 찾았다. 내부반송 유량은 유입 유량의 200 %이고, 생물반응조 수온이 20 ℃이고 일차침전지에서 생물반응조로 by-pass 되는 유입수가 15 %일 때 아산화질소 배출 계수가 가장 적은 조건임을 확인했다. 또한 깊은 수심에서 공기를 주입하는 심층폭기는 상대적으로 적은 공기공급을 필요로 하기 때문에 일반적인 폭기조에 비해 적은량의 아산화질소가 발생함을 확인하였다.

• 한국초지조사료학회지
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• 제40권4호
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• pp.274-278
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• 2020

Pig slurry (PS) is the most applicable recycling option as an alternative organic fertilizer. The application of pig slurry has the risk of air pollution via atmospheric ammonia (NH3) and nitrous oxide (N2O) emission. The zeolite has a porous structure that can accommodate a wide variety of cations, thus utilizing for the potential additive of deodorization and gas adsorption. This study aimed to investigate the possible roles of zeolite in mitigating NH3 and N2O emission from the pig slurry applied to the maize cropping. The experiment was composed of three treatments: 1) non-N fertilized control, 2) pig slurry (PS) and 3) pig slurry mixed with natural zeolite (PZ). Both of NH3 and N2O emission from applied pig slurry highly increased by more than 3-fold compared to non-N fertilized control. The NH3 emission from the pig slurry was dominant during early 14 days after application and 20.1% of reduction by zeolite application was estimated in this period. Total NH3 emission through whole period of measurement was 0.31, 1.33, and 1.14 kg ha-1. Nitrous oxide emission in the plot applied with pig slurry was also reduced by zeolite treatment by 16.3%. Significant increases in forage and ear yield, as well as nutrient values were obtained by pig slurry application, while no significant effects of zeolite were observed. These results indicate that the application of zeolite and pig slurry efficiently reduces the emission of ammonia and nitrous oxide without negative effects on maize crop production.

• 한국기후변화학회지
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• 제7권4호
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• pp.443-450
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• 2016

The major greenhouse gases (GHGs) in agricultural sector are methane ($CH_4$), nitrous oxide ($N_2O$), carbon dioxide ($CO_2$). GHGs emissions are estimated by pertinent source category in a guideline book from Intergovernmental Panel on Climate Change (IPCC) such as methane from rice paddy, nitrous oxide from agricultural soil and crop residue burning. The methods for estimation GHGs emissions in agricultural sector are based on 1996 and 2006 IPCC guideline, 2000 and 2003 Good Practice Guidance. In general, GHG emissions were calculated by multiplying the activity data by emission factor. The total GHGs emission is $10,863Gg\;CO_2-eq$. from crop cultivation in agricultural sector in 2013. The emission is divided by the ratio of greenhouse gases that methane and nitrous oxide are 64% and 34%, respectively. Each gas emission according to the source categories is $7,000Gg\;CO_2-eq$. from rice paddy field, $3,897Gg\;CO_2-eq$. from agricultural soil, and $21Gg\;CO_2-eq$. from field burning, respectively. The GHGs emission in agricultural sector had been gradually decreased from 1990 to 2013 because of the reduction of cultivation. In order to compare with indirect emissions from agricultural soil, each emission was calculated using IPCC default factors (D) and country specific emission factors (CS). Nitrous oxide emission by CS applied in indirect emission, as nitrogen leaching and run off, was lower about 50% than that by D.

• 한국초지조사료학회지
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• 제36권3호
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• pp.199-204
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• 2016

The objective of this study was to determine the effect of nitrification inhibitor dicyandiamide (DCD) and urease inhibitor hydroquinone (HQ) on ammonia ($NH_3$) and nitrous oxide ($N_2O$) emission from pig slurry applied to Timothy (Phleum pretense L.) sward. The daily emission of ammonia ($NH_3$) and nitrous oxide ($N_2O$) was monitored for 9 days in three different treatments; 1) control (only pig slurry application), 2) DCD treatment (pig slurry + DCD), and 3) HQ treatment (pig slurry + HQ). Most $NH_3$ emission occurred after 4~5 days in three treatments. Total $NH_3$ emission, expressed as a cumulative amount throughout the measurement time, was $1.33kg\;N\;ha^{-1}$ in the control. The DCD and HQ treatment decreased total $NH_3$ emission by 16.3% and 25.1%, respectively, compared to the control. Total $N_2O$ emission in the control was $47.1g\;N\;ha^{-1}$. The DCD and HQ treatment resulted in a reduction of 67.9% and 41.8% in total $N_2O$ emission, respectively, compared to the control. The present study clearly indicated that nitrification and urease inhibitor exhibited positive roles in reducing N losses through $NH_3$ and $N_2O$ emission.

• 한국토양비료학회지
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• 제45권6호
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• pp.1187-1193
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• 2012

Water control is mainly one of the key factors that can affect nitrous oxide ($N_2O$) emissions from soils. This study was undertaken to determine the effect of intermittent drainage compared to continuous flooding (conventional water regime) on $N_2O$ emission to global warming potential (GWP) with NPK (standard cultivation practice), NPK+Straw, and PK fertilizations. Nitrous oxide emission rates were collected twice a week using a closed chamber method. With continuous flooding, nitrogen (N) application increased $N_2O$ emission by 106.6% ($0.64kg\;ha^{-1}$ in NPK) with respect to the PK treatment ($0.31kg\;ha^{-1}$), and straw addition to NPK enhanced 148.3% of seasonal $N_2O$ flux ($0.77kg\;ha^{-1}$ in NPK+Straw). Although seasonal $N_2O$ emission slightly increased by 16.1-42.9% with intermittent irrigation, its seasonal $CH_4$ emission drastically reduced at 43.5-52.8% resulting in a lower GWP at 48.9-58.5% with respect to that of continuously flooded treatments ($4.51Mg\;CO_2\;ha^{-1}$, PK; $7.60Mg\;CO_2\;ha^{-1}$, NPK; $14.55Mg\;CO_2\;ha^{-1}$, NPK+Straw). Rice yield, at similar fertilization with the continuously-flooded rice field, was not affected by intermittent irrigation. Conclusively, intermittent irrigation can be very effective and a rational soil management strategy to mitigate GWP with considering rice productivity in a temperate paddy rice field like Korea.

• Journal of Microbiology and Biotechnology
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• 제23권1호
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• pp.99-105
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• 2013

In this study, nitrous oxide ($N_2O$) emission was compared between the operations of two different sequencing batch reactors, conventional sequencing batch reactor (CNVSBR) and simultaneous nitrification and denitrification sequencing batch reactor (SND-SBR), using synthetic wastewater. The CNV-SBR consisted of anoxic (denitrification) and aerobic phases, whereas the SND-SBR consisted of a microaerobic (low dissolved oxygen concentration) phase, which was achieved by intermittent aeration for simultaneous nitrification and denitrification. The CNV-SBR emitted 3.9 mg of $N_2O$-N in the denitrification phase and 1.6 mg of $N_2O$-N in the nitrification phase, resulting in a total emission of 5.5mg from 432mg of $NH_4^+$-N input. In contrast, the SND-SBR emitted 26.2mg of $N_2O$-N under the microaerobic condition, which was about 5 times higher than the emission obtained with the CNV-SBR at the same $NH_4^+$-N input. From the $N_2O$ yield based on $NH_4^+$-N input, the microaerobic condition produced the highest yield (6.1%), followed by the anoxic (0.9%) and aerobic (0.4%) conditions. It is thought that an appropriate dissolved oxygen level is critical for reducing $N_2O$ emission during nitrification and denitrification at wastewater treatment plants.

• 동력기계공학회지
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• 제18권6호
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• pp.106-112
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• 2014

The diesel engine, which has high compression ratio than other heat engines, has been using as the main power source of marine transport. Especially, since marine diesel engines offer better specific fuel consumption (SFC), it is environment-friendly compared to those used in other industries. However, attentio should be focused on emissions such as nitrous oxide ($N_2O$) which is generated from combustion of low-grade fuels. Because $N_2O$ in the atmosphere is very stable, the global warming potential (GWP) of $N_2O$ is 310 times as large as that of $CO_2$, and it becomes a source of secondary contamination after photo-degradation in the stratosphere. It has been hitherto noted on the $N_2O$ exhaust characteristics from stationary power plants and land transportations, but reports on $N_2O$ emission from the marine diesel engine are very limited. In this experimental study, a author investigated $N_2O$ emission characteristics by using changed diesel fuel components of nitrogen and sulfur concentration, assessed on the factors which affect $N_2O$ generation in combustion. The experimental results showed that $N_2O$ emission exhibited increasement with increasing of sulfur concentration in fuel. However, all kinds of nitrogen component additives used in experiment could not change $N_2O$ emission.

• Environmental Engineering Research
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• 제24권1호
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• pp.107-116
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• 2019

Nitrogen removal, nitrous oxide ($N_2O$) emission and microbial community in sequencing batch and continuous-flow intermittent aeration processes were investigated. Two sequencing batch reactors (SBRs) and two continuous-flow multiple anoxic and aerobic reactors (CMRs) were operated under high dissolved oxygen (DO) (SBR-H and CMR-H) and low DO (SBR-L and CMR-L) concentrations, respectively. Nitrogen removal was enhanced under CMR and low DO conditions (CMR-L). The highest total inorganic nitrogen removal efficiency of 91.5% was achieved. Higher nitrifying and denitrifying activities in SBRs were observed. CMRs possessed higher $N_2O$ emission factors during nitrification in the presence of organics, with the highest $N_2O$ emission factor of 60.7% in CMR-L. SBR and low DO conditions promoted $N_2O$ emission during denitrification. CMR systems had higher microbial diversity. Candidatus Accumulibacter, Nitrosomonadaceae and putative denitrifiers ($N_2O$ reducers and producers) were responsible for $N_2O$ emission.