• Title/Summary/Keyword: Nitrous oxide

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Adsorption-Desorption Characteristics of NO, $N_2O$ and $O_2$ over Mixed Oxide Catalysts of AlCoPd (1/1/0.05) and AlCoFe (1/1/2) (AICoPd (1/1/0.05) 및 AICoFe (1/1/2)의 혼합금속산화물 촉매에 의한 NO, $N_2O$$O_2$의 흡탈착 특성 연구)

  • Han, A-Reum;Hwang, Young-Ae;Chang, Kil-Sang
    • Clean Technology
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    • v.17 no.2
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    • pp.142-149
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    • 2011
  • The adsorption and desorption behaviors of NO and $N_2O$ over two mixed oxide catalysts, AlCoPd (1/1/0.05) and AlCoFe (1/1/2), have been investigated for the lean $NO_x$ trap applications. The catalysts showed good adsorption capabilities for NO and $N_2O$ without needing oxidation step. The adsorption decreased a lot when they are co-adsorbed with oxygen. While NO kept high adsorbability and selectivity with respect to oxygen, those of $N_2O$ decreased sharply. From the TPD results, NO and $N_2O$ are considered to decompose into nitrogen and oxygen in the higher temperature range and the oxygen seems to be strongly attached to the catalysts even at high temperature.

Transient State Theory of Significant Liquid Structure Applied to Nitrogen Oxides (액체 구조의 천이상태이론의 질소산화물들에 대한 적용)

  • Kim, Sang-Hyung;Pak, Hyung-Suk;Kim, Kak-Choong;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.11 no.3
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    • pp.105-110
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    • 1967
  • The transient state theory of significant liquid structure is applied to nitrous oxide and nitrogen tetroxide. The partition functions for the two liquids are derived according to the transient state theory. The various thermodynamic properties; such as, molar volumes, vapor pressures, entropies of vaporization, and critical point properties agree well with the experimental values.

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Possibilities for Reduction and the Emissions of Trace Gases from Livestock System (축산에서 기후변동 관련 기체의 발생원과 방지대책)

  • 류종원
    • Journal of Animal Environmental Science
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    • v.4 no.1
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    • pp.37-45
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    • 1998
  • There are a lot of trace gas of gaseous pollutants produced from farm animals. CO2 and CH4 are gases produced directly by the animal. NH3, N2O are produced from animal waste. Most of the effects of these gaseous pollutants on the farm animals have not been investigated in detail. CO2 emission from animal is very little. CH4 release from ruminant is also considered to be a significant factor in potential global warming. Nitrous oxide (N2O) emissions could be avoided by using organic or mineral fertilizer only as much as is needed by plant growing. This paper gives an overview about problems and solving strategies for possibilities for reduction of gaseous pollutants. The way to reduce the gaseous pollution risks from livestock systems are discussed.

An Integrated Emission Model of Greenhouse Gases to Assess Regional Climate Change

  • Moon, Yun-Seob;Oh, Sung-Nam;Hyun, Myung-Suk
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.421-422
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    • 2003
  • Greenhouse gases (GHGs) such as carbon dioxide ($CO_2$), methane (CH$_4$), nitrous oxide ($N_2$O), chlorofluorocarbons (CFCs), sulphur hexafluoride (SF$_{6}$), together with water vapour ($H_2O$) and ozone play an important role in determining the earth's climate. The primary cause of the enhancement of GHGs is the global use of fossil fuels to generate heat, power, and electricity for a growing world population, as well as the changes in the land use, especially for agriculture. In addition, biomass buring and biofuel emissions play major roles in the GHG emissions in the Asian region because they produce large amounts of carbon monoxide (CO), nonmethane volatile organic compounds(NMVOC), black carbon(BC) and other gases. (omitted)d)

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Combustion Characteristics of an Agricultural Diesel Engine using Biodiesel Fuel

  • Ryu, Kyunghyun;Oh, Youngtaig
    • Journal of Mechanical Science and Technology
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    • v.18 no.4
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    • pp.709-717
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    • 2004
  • Biodiesel has great potential as an alternative fuel for diesel engines that would reduce air pollution. It is a domestically produced, renewable fuel that can be manufactured from fresh or used vegetable oils, or from animal fats. In this study, a biodiesel fuel derived from rice bran oil was tested as an alternative fuel for agricultural diesel engines. The emissions were characterized for both neat and blended biodiesel fuels, and for conventional diesel fuel. Since this biodiesel fuel contained 11 % oxygen, it strongly influenced the combustion process. The use of biodiesel fuel resulted in lower carbon monoxide, carbon dioxide, and smoke emissions, without any increase in nitrous oxide emissions. The study demonstrated that biodiesel fuel could be effectively used as a renewable and environmentally innocuous fuel for agricultural diesel engines.

Effect of Annealing Conditions on $Ta_2$$O_5$ Thin Films Deposited By PECVD System (열처리 조건이 PECVD 방식으로 증착된 $Ta_2$$O_5$ 박막 특성에 미치는 영향)

  • 백용구;은용석;박영진;김종철;최수한
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.8
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    • pp.34-41
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    • 1993
  • Effect of high temperature annealing conditions on Ta$_{2}O_{5}$ thin films was investigated. Ta$_{2}O_{5}$ thin films were deposited on P-type silicon substrates by plasma-enhanced chemical vapor deposition (PECVD) using tantalum ethylate. Ta(C$_{2}H_{5}O)_{5}$, and nitrous oxide. N$_{2}$O. The microstructure changed from amorphous to polycrystalline above 700.deg. C annealing temperature. The refractive index, dielectric onstant and leakage current of the film increased as annealing temperature increased. However, annealing in oxygen ambient reduced leakage currents and dielectric constant due to the formation of interfacial SiO$_{2}$ layer. By optimizing annealing temperature and ambient, leakage current lower than 10$^{-8}$ A/cm$^{2}$ and maximum capacitance of 9 fF/${\mu}m^{2}$ could be obtained.

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Theoretical Study of the Interaction of N2O with Pd(110)

  • Kang, Dae-Bok
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2369-2376
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    • 2007
  • N2O has been found from experimental and theoretical considerations to bind on-top to the Pd(110) surface in a tilted end-on fashion via its terminal N atom. We use a frontier orbital description of the bonding interactions in the Pd-N2O system to obtain molecular insight into the catalytic mechanism of the activation of N2O by the Pd(110) surface giving rise to the formation of N2 and O on the surface. For the tilted end-on N2O binding mode, the LUMO 3π of N2O has good overlap with the Pd dσ and dπ orbitals which can serve as the electron donors. The donor-acceptor orbital overlap is favorable for electron transfer from Pd to N2O and is expected to dominate the surface reaction pathway of N2O decomposition.

Variation of Tracer Distribution During the Antarctic Polar Vortex Breakup Shown in ILAS and ILAS-II Data (ILAS와 ILAS-II 자료에서 나타난 남극 와동 붕괴기간의 미량기체 분포변화)

  • Choi, Wookap;Lim, Kyungsoo
    • Atmosphere
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    • v.20 no.3
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    • pp.367-377
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    • 2010
  • Variation of tracer distribution during the vortex-breakup period in the Antarctic region was observed by the data from the Improved Limb Atmospheric Spectrometer (ILAS) and ILAS-II. All four trace species including methane, nitrous oxide, ozone, and water vapor show similar patterns of vertical gradient in spite of different structures of zonal mean mixing ratio. Timings of vortex breakup on each level are estimated by two different methods, and they are compared with zonal standard deviations following the latitude circle of each trace species. Although the tracers have different chemical life times and sink/source, the zonal standard deviation patterns show remarkable similarities. The zonal standard deviation shown here to measure the zonal asymmetry of tracer distribution is believed to diagnose the timing of the Antarctic polar-vortex breakup reasonably well.

Factors Affecting and Techniques to Quantify $CH_4\;and\;N_2O$ Emissions from Stored Liquid Manure

  • Park, K.H.;Wagner-Riddle, Claudia
    • Journal of Animal Environmental Science
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    • v.13 no.1
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    • pp.1-12
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    • 2007
  • Stored animal manure is considered as a significant agricultural source of methane $(CH_4)$ and nitrous oxide $(N_2O)$ which have 23 and 297 times higher global warming effect when compared to carbon dioxide $(CO_2)$. Uncertainties caused by lack of understanding physical and biochemical environment in stored animal manure and by errors of emission measurement methods, even though many researches measuring $CH_4\;and\;N_2O$ emissions from stored manure have been conducted for a few decades. In this paper, general information of $CH_4\;and\;N_2O$ generation and emissions from stored animal manure and the measurement methods for quantifying $CH_4\;and\;N_2O$ emissions are discussed.

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Design and Manufacture Hybrid Rocket for Measuring Atmospheric Fine Dust (대기 중 미세먼지 농도 측정을 위한 하이브리드 로켓 설계 및 제작)

  • Park, Yeong-Hun;Kim, Gi-Mun;Lee, Dong-Wan;Mun, Hui-Jang;Kim, Jin-Gon
    • 한국항공운항학회:학술대회논문집
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    • 2015.11a
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    • pp.13-19
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    • 2015
  • 본 연구의 목적은 자체 설계 제작한 하이브리드 발사체를 이용하여 대기 중의 미세먼지를 측정하는데 있다. 대기 중의 미세먼지를 측정하기 위한 방법으로는 중량농도법을 이용하였으며, 미세먼지 측정을 위한 포집장치를 자체 제작하였다. 엔진은 5port의 HDPE(High Density Polyethylene)를 연료 그레인으로 사용하였고 $LN_2O$(Liquefied Nitrous Oxide)를 산화제로 사용하였다. 압력, 가속도, GPS 등을 수집하며, 하이브리드 발사체의 동체는 FRP(Fiberglass Reinforced Plastics)로 제작한다. 전체 비행시간은 총 95초로 예상되며. 연소시간은 3초, 고도는 800 m 이다.

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