• Progress in Superconductivity and Cryogenics
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• v.23 no.3
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• pp.20-25
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• 2021

Milking parlor wastewater contains high concentration suspended solid (SS), nitrogen, and/or phosphate as well as organic compounds. A new biological wastewater process by magnetic separation, magnetic activated sludge (MAS) process, was applied to milking parlor wastewater treatment process. A three step wastewater treatment process of coagulation sedimentation / ammonia stripping (C/S), magnetic activated sludge process and contact oxidation (CO) was proposed for removal of these pollutants. First step, C/S process recovered 96% TN and 96% PO₄^3--P as resource for fertilizer from the wastewater. 81% biochemical oxygen demand (BOD) in wastewater was removed after MAS process. As a results, all pollutant concentrations satisfied Japanese effluent standards. Most of residual BOD and SS were removed by the CO process. It was estimated that the proposed process could reduce the process space to 1/7.

• Analytical Science and Technology
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• v.36 no.4
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• pp.161-169
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• 2023

In this study, a straightforward and precise nitrogen/sulphur-codoped carbon dots (N/S-CD) was produced using a microwave irradiation approach. The N/S-CD was formulated from succinic acid (SA), bis-(3-aminopropyl)-amine (BAPA), and sodium thiosulphate (STS) as sources of carbon, nitrogen, and sulphur, respectively. The synthesized N/S-CD established a valuable quantum yield (QY) of 70 % and was sensitive to aluminium ion (Al³⁺) with a detection limit of 0.21 µM and a linear concentration range of 0-100 µM. When detecting Al³⁺ in real water samples, the N/S-CD resulted in a satisfactory recovery in the range of 91.14 %-103.37 %. Thus, the proposed study is very promising for Al³⁺ detection in environmental water samples.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.463-471
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• 2023

Nitrogen-rich carbon dots (NDots) were synthesized by using uric acid as carbon and nitrogen sources. The as-synthesized NDots showed strong dual emissions at 420 nm and 510 nm with excitation at 350 nm and 460 nm, respectively. The physicochemical analyses such as X-ray photoelectron spectroscopy, Transmission electron microscopy and Fourier transform infrared spectroscopy were used to analyze the chemical, physical and morphological structures of NDots. The as-synthesized NDots exhibited wide linear range (0-100 µM) and very low detection limit (124 nM) in Ag⁺ ion sensing. In addition, Ag⁺ saturated NDots could be used as an EDTA sensor by the EDTA induced PL recovery.

• Korean Journal of Soil Science and Fertilizer
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• v.31 no.2
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• pp.143-150
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• 1998

In order to evaluate the nitrogen (N) balance, from the different application methods and levels of $^{15}N$ applied to a satsuma mandarin orchard soils in spring, we surface-applied N as urea at the rates of 50 (water-dissolved), 100 (solid and water-dissolved) and 150% (solid) of the recommended rate ($180kg\;ha^{-1}$) in spring (lebeled N), summer (nonlebeled N) with application ratio of 5:2:3. Fruit yield and quality were not significantly affected by any treatment. Nitrogen contents of spring flush leaves in late August were 3.0% regardless of the treatments. The N recovery by parts of tree itself was in the order of leaves, fruits, roots, stems, and the highest recovery per tree was 22.3% in the 50% recommended water-dissolved surface broadcast while there were not much differences for N recovery (11.9 to 13.6%) among the other three treatments. Total N content in top 30cm of soils was 0.47% regardless of the treatments, but N proportion and total residual N from the fertilizer applied increased with increasing N rate while the N recovery in soils decreased. For the recommended N rate, N proportion and the residual N from the fertilizer applied were greater in the water-dissolved surface broadcast than those in soils surface broadcast. The highest total (tree + soils) N recovery was 70.9% in the 50% recommended water-dissolved surface broadcast, but tended to decrease to 52.2, 46.6, and 43.2% for the recommended water-dissolved surface broadcast, 100 and 150% of the recommended solid surface broadcast, respectively.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.1094-1099
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• 2012

Green manure cultivation affects soil productivity and nutrient conservation in paddy soil at winter season. This study was to evaluate nitrogen behavior released from chinese milk vetch (CMV) as green manure by using stable $^{15}N$ trace during rice cultivation. The CMV used in the experiment was 29.9 of C/N ratio and 14.1 g N $kg^{-1}$ ($^{15}N$ 0.388 atom % excess) and was applied at rates of 10 and $30Mg\;ha^{-1}$ in pot of 1/2000a size. Rice growth and N uptake increased with higher levels of CMV application at harvesting stage. Among total N uptake, 14.6 and 26.8 % of nitrogen was released respectively from the two different rates of CMV application. Stable $^{15}N$ recovery by rice biomass was 60%, 54% to the $^{15}N$ input, respectively, of CMV application, which decreased in order of grain, root, and straw of rice biomass. Total N content in the soil after rice harvest was 1.9 and 2.1 g N $kg^{-1}$, respectively, with increasing N input by the different rates of CMV application and the rate of $^{15}N$ recovery derived from CMV in the soil was 3.8 and 4.8 %, respectively. N input by CMV application induced rice growth and productivity during rice cultivation. However, it might need proper managements to reduce N loss because about 36-41 % of nitrogen was lost from N input by CMV application.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.1
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• pp.61-66
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• 2006

The combined ADEPT(Anaerobic Digestion Elutriated Phased Treatment)-SHARON(Single reactor system for High Ammonium Removal Over nitrite)-ANAMMOX(Anaerobic ammonium oxidation) processes were operated for resources recovery and nitrogen removal from slurry-type piggery waste. The ADEPT process operated at an acidogenic loading rates of 3.95 gSCOD/L-day, the SCOD elutriation rate and acid production rate were 5.3 gSCOD/L-day and 3.3 gVFAs(as COD)/L-day, respectively. VS reduction and SCOD reduction by the hydrolysis were 13% and 0.19 $gSCOD_{prod.}/gVS_{feeding}$, respcetively. Also, the acid production rate was 0.80 $gVFAs/gSCOD_{prod}$. In methanogenic reactor, the gas production rate and methane content were 2.8 L/day($0.3m^3CH_4/kgCOD_{removal}@STP$) and 77%, respectively. With these operating condition, the removals of nitrogen and phosphorus were 94.1% as $NH_4-N$(86.5% as TKN) and 87.3% as T-P respectively.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.27 no.1
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• pp.66-71
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• 1982

Field experiments of nitrogen application (0, 100, 200, 400, 800kg N/ha year) were carried out to study the nitrogen response of Sudangrass at College Farm, Seoul National Univ., in 1979 and 1980. Dry matter yield and leaf area index increased up to 400kg N/ha in 1979 and 800kg N/ha in 1980. The forage yield of 1980 was less than that of 1979, due to the extraordinarily low temperature and the decreased solar radiation during summer. Total nitrogen contents in forage increased with nitrogen application, but maximum contents were found either 400 or 800kg N levels depend on each cutting stages. Nitrate nitrogen content in forage exceded over 2000 ppm at 800kg N application. Overall percentages of N recovery were below 50% with average 34%. Net assimilation rate and nitrogen use efficiency of Sudangrass were improved in higher temperature and more sunlight condition during regrowth period.

• Journal of Environmental Health Sciences
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• v.46 no.6
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• pp.646-654
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• 2020

Objectives: Users of parks or children's play facilities have pointed to pets' bowel movements as the most serious problem when using them. In prior studies, a very low detection rate of parasites (eggs) in sand flooring materials has been found. Even though feces have been identified, no parasites (eggs) have been detected. Method: A standard solution of nitrate nitrogen was used to verify the reliability of a new nitrogen analysis method. The linearity, precision, and accuracy of the nitrate nitrogen analysis method were verified. Using this method, the pollution distribution of the sand flooring material and the degree of pollution at each point were investigated. Results: As a result of the verification of the nitrogen analysis method, the linearity was found to be good at r2=0.999 when distilled water is mixed in a standard substance solution. The standard substance additive solution r2=0.968 was found to be good. Precision represented 0.01 to 0.06% RSD for peak height. The recovery rate was 92.4 to 104.0 percent, indicating high accuracy. According to the same method of analysis, the flooring material sand at a general amusement facility with the largest number of concealed spaces was nitrate nitrogen 6.1 times higher than at the entrance of the playground. Also, in a comparison between clean sand and sandy flooring, the average nitrogen concentration of the sand flooring material was 24.4-167 times higher than pure sand. Conclusions: As such, no parasites (eggs) were detected at all points under investigation, but the sand flooring was exposed to animal fecal contamination. Therefore, the management of nitrogenous components should allow accurate identification of animal fecal contamination so that the timing of sand replacement can be managed hygienically and safely.

• Korean Journal of Soil Science and Fertilizer
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• v.35 no.1
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• pp.38-46
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• 2002

Chrysanthemum boreale M. (hereafter, C. boreale M.), a perennial flower, has been historically used as a natural medicine in Korea. With increasing concerns for health-improving foods, the demand for C. boreale M. has become higher than ever. Howevr, the amount of wild C. boreale M. collected from mountainous areas is not enough to cover all demands. The cultivation system and fertilization strategy are required to meet increasing demand on C. boreale M. with a good quality. We investigated the effects of nitrogen application on plant growth and effective components of C. boreale M. to suggest optimum rate of nitrogen fertilization. C. boreale M. was cultivated in a pot scale (1/2000a scale), and nitrogen applied with rate of 0(N0), 50(N50), 100(N100), 150(N150), 200(N200), and $250(N250)kg\;ha^{-1}$. Phosphate and potassium were applied at the same level ($P_2O_5-K_2O=80-80kg\;ha^{-1}$) in all treatments. Maximum yield achieved in 246 and $226kg\;ha^{-1}$ N treatment on the whole plant and the flower part, a valuable part as a herbal medicine, respectively. Proline was the most abundant amino acid in the flower of C boreal M. and the contents of amino acids increased with increasing nitrogen application rate in flower. Nitrogen recovery efficiency was high more than 41% in all nitrogen treatments and increased to 61.8% in nitrogen N100 treatment. From the nitrogen content, the high nitrogen uptake, the low residue of mineral N and the reasonably good apparent fertilizer recovery, it can be inferred that C. boreale M. made efficient use of the available nitrogen. In flower, contents of Cumambrin A. which is a sesquiterpene compound and has the effect of blood-pressure reduction, decreased with increasing nitrogen application. However, the amount of Cumambrin A in flower increased as nitrogen rate increased, because of increasing flower yield. Conclusively, nitrogen fertilization could increase yields and enhance quality. The optimum nitrogen application rate might be on the range of $225{\sim}250kg\;ha^{-1}$ in a mountainous soil.

• Journal of Korean Society of Forest Science
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• v.104 no.3
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• pp.352-359
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• 2015

This study was conducted to evaluate how the special protection area designations of degraded trails effect on the soil and vegetation recovery of degraded trails. The study areas were established on an opened trail and a 16-year closed trail, which was prohibited to enter after the designation as a special protection area for recovery, at Bukhansan National Park. Soil core sampling and measurements of vegetation cover were performed to compare soil and vegetation properties of the trails. Soil bulk density increased and soil water total nitrogen decreased on the opened trail, while no significant differences were found on bulk density, soil water, total nitrogen, acidity, and organic matter on the closed trail. On the opened trail, vegetation cover was seemed to be degraded, because vegetation litter cover ratio was low and barren rock cover ratio was high. On the closed trail, litter rock barren cover ratio of the closed trail was recovered, but only limited recovery was found on vegetation cover by applying environmental damage condition rating class. In conclusion, the closed trail was recovered by designation of special protection area, while difference in recovery progress of soil and vegetation was found. Therefore, designation of special protection area of degraded area should be based on scientific basis of recovery characteristics of the area. In order to improve the effectiveness of special protection area system, further specific standards for special protection area designation and management would be needed, considering ecological and social importance of target areas.