• 제목/요약/키워드: Nitrogen rate

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영산강과 섬진강 수계의 질소 분포와 유기질소 분해속도 (The Distribution of Nitrogen and the Decomposition Rate of Organic Nitrogen in the Youngsan River and the Sumjin River, Korea)

  • 김지혜;김범철;신명선;김재구;정성민;이윤경;박주현
    • 한국물환경학회지
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    • 제25권1호
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    • pp.142-150
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    • 2009
  • The distribution of organic nitrogen and its decomposition rate were studied in the Youngsan River and the Sumjin River system in Korea. Samples were conducted seasonally in June, August, December of 2006, and February of 2007. Collected samples were incubated for 20 days in a dark chamber ($20{\pm}1^{\circ}C$) and analyzed the changes of nitrogen form (particulate organic nitrogen, dissolved organic nitrogen, ammonia, nitrite, and nitrate). The mean total nitrogen (TN) concentration in the Youngsan River and the Sumjin River were $2.62mgN{\cdot}L^{-1}$ and $1.53mgN{\cdot}L^{-1}$, respectively. TN comprised of 65% DIN and 35% ON. The decomposition coefficients of organic nitrogen were also determined by two different fitting models. The decomposition rates of nitrogen species (TON, LPON, LDON, ${NH_4}^+$ and ${NO_2}^-$) ranged from 0.024 to $1.043day^{-1}$ in the Youngsan River and 0.008 to $0.693day^{-1}$ in the Sumjin River, respectively. The result of this study can give a guide to the selection of parameters in the calibration processes of water quality models.

액체질소 냉각용 극저온 열교환기의 최적설계를 위한 열전달 및 압력강하 특성 분석 (An Analysis of Heat Transfer and Pressure Drop Characteristics for Optimum Design of Cryogenic Heat Exchanger used for Liquid Nitrogen Cooling)

  • 고지운;전동순
    • 설비공학논문집
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    • 제30권1호
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    • pp.24-32
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    • 2018
  • In this paper, analytical studies were conducted to obtain optimal design factors and analysis parameters of liquid nitrogen cooling exchanger applied in cryogenic refrigerator. The target value of heat transfer rate was more than 1 kW and pressure drop was less than 40 kPa. Design factors of cryogenic heat exchanger included width of channel and configuration of paths. Analytical factors of liquid nitrogen cooling exchanger included temperatures of coolant header surface and inlet liquid nitrogen. The width and number of channels in the design parameters were 0.0050~0.0150 m and 4~8, respectively. The configuration of channel path was 4 ways. Temperatures of coolant header surface and inlet liquid nitrogen in analytical parameters were 74 to 78K and 82 to 86K, respectively. As result, the design factor and analysis parameter satisfying the target values were obtained. The biggest heat transfer rate was 1.36 kW with pressure drop of 32.26 kPa.

아크릴섬유 폐수의 생물학적 질소제거공정의 개선 (Improvement of the Advanced Treatment for Nitrogen Removal of Acrylic Fiber Wastewater)

  • 이찬원;조인성;임경원
    • 한국환경과학회지
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    • 제15권5호
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    • pp.439-446
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    • 2006
  • The effluent discharge standards of industrial wastewater has become more stringent since 2003. Many industrial wastewater treatment plants has been upgraded to advanced treatment facilities. There are high concentrations of nitrate(>200 mg/L) and ammonium(>50 mg/L) nitrogen in the acrylic fiber wastewater of H textile Co. Wastewater from acrylic fiber industry containing acrylonitrile, which may affect the subsequent biological treatment process. Manufacturing of acrylic fiber also produces shock loadings. Excessive acrylonitrile and polymer debris produced in the polymerization process was screened, coagulated with CaO and settled down. A preaeration system was added to treat this high pH effluent to remove volatile organic compound and ammonia nitrogen by the air stripping effect. it was found that nitrification rate was not sufficient in the Anoxic/Oxic(AO) process. One denitrification tank was converted to nitrification reactor to extend HRT of nitrification. Nitrification rate of ammonia nitrogen was promoted from 32% to 67% by this modification and effluent nitrogen concentration was well satisfied with the effluent standards since then.

외부탄소원을 사용한 SBBR의 공정 특성 및 질소제거 (Evaluation of SBBR Process Performance Focused on Nitrogen Removal with External Carbon Addition)

  • 한혜정;윤주환
    • 한국물환경학회지
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    • 제22권3호
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    • pp.566-571
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    • 2006
  • A sequencing batch biofilm reactor (SBBR) operated with a cycle of anaerobic - aerobic - anoxic - aerobic has been evaluated for the nutrient removal characteristics. The sponge-like moving media was filled to about 10% of reactor volume. The sewage was the major substrate while external synthetic carbon substrate was added to the anoxic stage to enhance the nitrogen removal. The operational results indicated that maximum T-N and T-P removal efficiencies were 97% and 94%, respectively were achieved, while COD removal of 92%. The observations of significant nitrogen removal in the first aerobic stage indicated that nitrogen removal behaviour in this SBBR was different to conventional SBR. Although the reasons for aerobic nitrogen removal has speculated to either simultaneous nitrification and denitrification or anoxic denitrification inside of the media, further researches are required to confirm the observation. The specific oxygen uptake rate (SOUR) test with biofilm and suspended growth sludge indicated that biofilm in SBBR played a major role to remove substrates.

질소시비가 산국의 수량과 유효성분에 미치는 영향 (Effects of Nitrogen Fertilization on the Yield and Effective Components of Chrysanthemum boreale M.)

  • 이경동;양민석;이용복;김필주
    • 한국토양비료학회지
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    • 제35권1호
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    • pp.38-46
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    • 2002
  • 산국(Chrysanthemum boreale M.)은 국화과에 속하는 다년생 식물이며 우리나라에 널리 분포하는 자생식물자원으로서 오래 전부터 식용과 약용으로 널리 이용되어 왔다. 최근 건강에 대한 관심이 고조되면서 산국의 수요가 급증하고 있으나 자연채집을 위주로 하기 때문에 공급을 충당하지 못하고 있는 실정이다. 본 연구에서는 우수품질의 산국을 대량생산하기 위해 질소시비반응 시험을 실시하였다. 처리구는 질소수준에 따라 6처리구(0, 50, 100, 150, 200, $250kg\;ha^{-1}$)로 설정하였다. 이때 모든 처리구에서 기본적으로 $P_2O_5-K_2O=80-80kg\;ha^{-1}$을 시비하였다. 그 결과, 질소의 시비량이 증가할수록 수량이 증가하였다. 전체 산국을 건물중으로 하여 회귀곡선을 통해 추정한 결과 N $246kg\;ha^{-1}$였으며, 꽃의 수량은 N $226kg\;ha^{-1}$이였다. 꽃의 주요 아미노산은 proline이였고 질소의 시비량이 증가할수록 아미노산의 함량이 증가하였다. 이때 질소의 이용율은 41.5-61.8%였고 N100처리구에서 가장 높았다. Sespuiterpene계 화합물로서 우수한 혈압강하효과를 가지고 있는 물질인 Cumambrin A의 함량은 식물부위 중 꽃에 가장 많이 함유되어 있었다. 질소의 시비량이 증가할수록 Cumambrin A의 함량이 다소 감소하였으나 통계적 유의성은 인정되지 않았다. 꽃에서 Cumambrin A의 전체 함량은 산국의 수량증가에 따라 질소 시비량이 증가할수록 증가하는 경향을 보였다. 따라서 유효성분이 많이 함유된 양질의 산국재배를 위해 질소의 적정시비량은 $225{\sim}250kg\;ha^{-1}$ 수준으로 판단되었으며 포장시험을 통한 현장입증시험이 있어야 할 것으로 판단된다.

Nitrogen Removal from Milking Center Wastewater via Simultaneous Nitrification and Denitrification Using a Biofilm Filtration Reactor

  • Won, Seung-Gun;Jeon, Dae-Yong;Kwag, Jung-Hoon;Kim, Jeong-Dae;Ra, Chang-Six
    • Asian-Australasian Journal of Animal Sciences
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    • 제28권6호
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    • pp.896-902
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    • 2015
  • Milking center wastewater (MCW) has a relatively low ratio of carbon to nitrogen (C/N ratio), which should be separately managed from livestock manure due to the negative impacts of manure nutrients and harmful effects on down-stream in the livestock manure process with respect to the microbial growth. Simultaneous nitrification and denitrification (SND) is linked to inhibition of the second nitrification and reduces around 40% of the carbonaceous energy available for denitrification. Thus, this study was conducted to find the optimal operational conditions for the treatment of MCW using an attached-growth biofilm reactor; i.e., nitrogen loading rate (NLR) of 0.14, 0.28, 0.43, and $0.58kg\;m^{-3}\;d^{-1}$ and aeration rate of 0.06, 0.12, and $0.24\;m^3\;h^{-1}$ were evaluated and the comparison of air-diffuser position between one-third and bottom of the reactor was conducted. Four sand packed-bed reactors with the effective volume of 2.5 L were prepared and initially an air-diffuser was placed at one third from the bottom of the reactor. After the adaptation period of 2 weeks, SND was observed at all four reactors and the optimal NLR of $0.45kg\;m^{-3}\;d^{-1}$ was found as a threshold value to obtain higher nitrogen removal efficiency. Dissolved oxygen (DO) as one of key operational conditions was measured during the experiment and the reactor with an aeration rate of $0.12\;m^3\;h^{-1}$ showed the best performance of $NH_4-N$ removal and the higher total nitrogen removal efficiency through SND with appropriate DO level of ${\sim}0.5\;mg\;DO\;L^{-1}$. The air-diffuser position at one third from the bottom of the reactor resulted in better nitrogen removal than at the bottom position. Consequently, nitrogen in MCW with a low C/N ratio of 2.15 was successfully removed without the addition of external carbon sources.

질소비료 시비량에 따른 들잔디의 생육반응 (Growth Response of Zoysiagrass (Zoysia japonica Steud.) as Affected by Nitrogen Fertilizer Application Rate)

  • 배은지;한정지;이광수;박용배;최수민
    • Weed & Turfgrass Science
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    • 제4권4호
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    • pp.397-404
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    • 2015
  • 양질 다수확 들잔디를 생산하기 위한 적정 질소비료 시비량을 규명하기 위하여 질소 시비량에 따른 들잔디의 생육과 토양화학성의 변화를 알아보고자 와그너 포트시험과 잔디 재배지 포장시험을 수행하였다. 포트시험에서는 지상부와 포복경의 생체중과 건물중, 지상부 개체수는 질소 시비량이 증가함에 따라 증가하였고, 질소비료 시비량 24와 $48kg\;N\;10\;a^{-1}$ 처리구간의 유의한 차이를 보이지 않았다. 잔디재배지 포장시험에서는 질소비료 시비량이 높을수록 지상부길이, 지상부, 포복경과 지하부의 생체중과 건물중, 지상부 개체수와 전체 포복경 개수는 유의성 있게 증가하였으며, 질소비료 $24{\sim}32kg\;N\;10\;a^{-1}$ 처리구간에는 유의한 차이가 없었다. 질소비료 시비량이 증가할수록 토양 내 pH, 치환성 양이온 칼슘과 마그네슘이 낮아져 토양 화학성이 악화되었다. 따라서 들잔디 생육 및 토양의 화학성을 고려한 적정 질소비료 시비량은 $24kg\;N\;10\;a^{-1}$으로 판단되었다.

육우수정란 간역동결 및 융해방법에 관한 연구 제칠보. 내동제에 Sucrose 첨가에 따른 액체질소에 미치는 영향 (Studies on Simplified Procedures for Freezing and Thawing of Bovine Embryos VII. Effects of freezing procedures in a liquid nitrogen container on the survival rate of mouse embryos)

  • 김중규;강만종;김영훈;장덕지;강민수;김승호
    • 한국가축번식학회지
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    • 제12권2호
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    • pp.84-90
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    • 1988
  • This study was done with mouse embryos to determine effects of the freezing media with or without 10% sucrose, and seeding methods (pincette, no seeding, liquid nitrogen gas phase and copper wire coiled straw) on embryo survival were determined using the FDA test. The summarized results are the following. 1. The FDA score found with copper wire coiled straw, no seeding, pincette and liquid nitrogen gas phase was 3.6, 3.6, 3.3 and 3.0, respectively. There were no significant differences. 2. The embryo score shows higher (P<0.05) survival rate using a freezing medium with sucrose than the one without it. Among the seeding procedure, better resutls are copper wire coiled straw and no seeded. 3. The results suggest that copper wire coiled seeding no seeding be as good as seeding when the mouse embryos were frozen in a liquid nitrogen container using both the freezing and dilution media containing 10% sucrose.

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금형공구강의 표면성질 향상에 미치는 질소이온주입의 효과에 관한 연구 (A Study on Effect of Nitrogen Ion Implantation on Improvement of Surface Properties of Tool Steel)

  • 김화정;김용조
    • 한국기계가공학회지
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    • 제7권4호
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    • pp.3-9
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    • 2008
  • The ion implantation technology is generally used in order to improve surface mechanical properties, especially tribological properties, of engineering metals. In this study, experimental works were carried out to investigate the surface properties, such as hardness, wear quantity, wear rate and friction force, of a nitrogen ion implanted tool steel STD11 under dry condition. Specimens for the wear test were made to investigate the influences of the initial ion implantation temperature and the total ion radiation. Wear properties, such as the wear quantity and the wear rate, of the nitrogen ion implanted tool steel were considerably improved, especially under the low sliding speed and the low applied load.

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연속회분식 생물막 반응기(Sequencing Batch Biofilm Reactor)를 이용한 수중의 유기물, 질소 및 인의 동시 제거에 관한 연구 (A Study on the Biological Organic, Nitrogen and Phosphorus Removal in Sequencing Batch Biofilm Reactor)

  • 박민정;김동석
    • 한국환경보건학회지
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    • 제30권2호
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    • pp.84-91
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    • 2004
  • Biological nutrient removal(BNR) from wastewater was performed by adopting various process configurations. The simultaneous biological organics, phosphorus and nitrogen removal of synthetic wastewater was investigated in a sequencing batch biofilm reactor (SBBR). The other reactor was operating as a reference, without biofilm being added. The cycling time in SBR and SBBR was adjusted at 12 hours and then certainly included anaerobic and aerobic conditions. Both systems has been operated with a stable total organic carbon(TOC), nitrogen and phosphorus removal performance for over 90 days. Average removal efficiencies of TOC and total nitrogen were 83% and 95%, respectively. The nitrification rate in SBR was higher than that in SBBR. On the contrary, the denitrification rate in SBBR was higher than that in SBR. The phosphorus release was occurred in SBBR, however, not in SBR because of the inhibition effect of NO$_3$$^{[-10]}$ .