• Title/Summary/Keyword: Nitrogen oxidizing

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On Atmospheres for Firing the Thick Film Coper Conductors (Thick Film Copper Conductor 의 소결과 소성 분위기)

  • Lee, Joon
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.193-198
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    • 1991
  • Thick film copper conductors are of considerable interest in thick film industries because of both the potential cost saving compared to the noble metal conductors and the favorable properties in electrical conductivity, solderability, solder leach resistance and wire bondability, However, formation of the excellent copper thick film is a lot complicated due to easily oxidizing property of copper at high temperature. In order to get favorable thick film copper conductor, hybrid microcircuit industry utilizes majorly three kinds of firing atmosphere, such as nitrogen atmosphere, reactive atmosphere and air atmosphere. The processes and the three atmospheres for firing thick film copper conductor were extensively reviewed in this article.

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Development and culture optimization of mutants of Thiobacillus sp. IW for elimination of hydrogen sulfide

  • Kang, Sun-Chul;Lim, Kwang-Hee;Shin, Seung-Yong
    • 한국생물공학회:학술대회논문집
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    • 2005.10a
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    • pp.465-467
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    • 2005
  • UIW-10 mutant obtained by UV treatment using sulfur-oxidizing bacteria, Thiobacillus sp. IW was studied. The colony size of UIW-10 was found 2 $^{\sim}$ 3 times bigger in diameter than the parent colony on TAM medium. UIW-10 mutant growth was two times higher than parent strain at 6 h culture in liquid medium containing sulfides such as sulfur and sodium thiosulfate. Initial pH and temperature for the optimum growth of UIW-10 were 6.0 and $35-40^{\circ}C$, respectively. It was found that addition of 0.5% yeast extract and 0.5 to 2.0% tryptone as nitrogen sources and the constant agitation at 150 to 200 rpm had a positive effect and the growth of UIW-10 was increased.

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Photocatalytic oxidation reaction in removal of NH4-N by using TiO2 (TiO2를 이용한 암모니아성 질소 제거에 관한 광촉매 산화반응)

  • 박상원;김정배
    • Journal of Environmental Science International
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    • v.12 no.10
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    • pp.1071-1077
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    • 2003
  • The aim of this study is, firstly, to find out what kinds of inorganic species are produced in the photocatalytic oxidation of ammonium-nitrogen containing water and, secondly, to seek the influence of anion for the photocatalytic oxidation of ammonium contained compounds. The photoenergy above 3 eV(λ <415 nm) was effectively absorbed by TiO$_2$ and TiO$_2$/polymer was used to be oxidized NH$_4$-N in wastewater to NO$_3$-N. Existing the anion as Cl$\^$-/, the rate of photocatalytic oxidation decreased regardless of other condition. This result showed that the chloride ions reduced the rate of oxidation by scavenging oxidizing radical species as OH$\^$-/ and OCl$\^$-/. Some of the added ion might have blocked the active sites of the catalyst surface, thus deactivated the catalyst.

Optimum Conditions of Super-critical Water Oxidation Process for Treatment of Slurry Piggery Wastewater (슬러리형 돈사분뇨처리를 위한 초임계수 산화공정의 최적 조건)

  • Kim, Ean-Ho;Seo, Jeoung-Yoon
    • Journal of Environmental Health Sciences
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    • v.34 no.4
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    • pp.333-341
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    • 2008
  • In this study, the possibility and the optimal conditions for treating slurry type piggery wastewater using supercritical water oxidation were tested in the laboratory. The results could be summarized as follows; The slurry type piggery wastewater, which was diluted 50 times, was treated most effectively at the pressure of 300 bar, the temperature of $550^{\circ}C$ and the residence time of 10 minutes. The air saturated water was injected, as an oxidizing agent, and the removal efficiencies of $COD_{Cr}$, T-N, $NH_4^+$-N and T-Pattheoptimal conditions were 92, 40, 59 and 100%, respectively. Therefore, analte rnativemea suremu stbetaken to improve theremo valefficiency of the nitrogen compounds.

A Study of Thermal Stability on Polymers and Sodium Azide Mixture by DSC (DSC에 의한 고분자물과 나트륨아지드 혼합물의 열안정성에 관한 연구)

  • 이내우;박준조
    • Journal of the Korean Society of Safety
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    • v.12 no.2
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    • pp.87-94
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    • 1997
  • If sodium azide is impinged by certain reasons, it will be produced explosives by heavy metals and toxic materials. But it is used propellent for inflating automotive safety bags and the other chemical manufacturing purpose. The investigation of thermal hazard potential of sodium azide itself and with polymers ate very important because some parts of automotives, transporting vessels of reactive chemicals and many any other constituents of structures in factories are made of polymers. The range of decomposition temperatures are about $360-380^{\circ}C$, even if it depends on heating rate and sample weight. Thermal decomposition heat of sodium azide in air is higher than in nitrogen atmosphere, because the former is included oxidizing heats of sodium metal which is made by decomposition of sodium azide to end. Especially decomposition temperature of polymers are increased on the order of bonding energy between atoms in hydrocarbon moleculars.

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Analysis and Quantification of Ammonia-Oxidizing Bacteria Community with amoA Gene in Sewage Treatment Plants

  • Hong, Sun Hwa;Jeong, Hyun Duck;Jung, Bongjin;Lee, Eun Young
    • Journal of Microbiology and Biotechnology
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    • v.22 no.9
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    • pp.1193-1201
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    • 2012
  • The analysis and quantification of ammonia-oxidizing bacteria (AOB) is crucial, as they initiate the biological removal of ammonia-nitrogen from sewage. Previous methods for analyzing the microbial community structure, which involve the plating of samples or culture media over agar plates, have been inadequate because many microorganisms found in a sewage plant are unculturable. In this study, to exclusively detect AOB, the analysis was carried out via denaturing gradient gel electrophoresis using a primer specific to the amoA gene, which is one of the functional genes known as ammonia monooxygenase. An AOB consortium (S1 sample) that could oxidize an unprecedented 100% of ammonia in 24 h was obtained from sewage sludge. In addition, real-time PCR was used to quantify the AOB. Results of the microbial community analysis in terms of carbon utilization ability of samples showed that the aeration tank water sample (S2), influent water sample (S3), and effluent water sample (S4) used all the 31 substrates considered, whereas the AOB consortium (S1) used only Tween 80, D-galacturonic acid, itaconic acid, D-malic acid, and $_L$-serine after 192 h. The largest concentration of AOB was detected in S1 ($7.6{\times}10^6copies/{\mu}l$), followed by S2 ($3.2{\times}10^6copies/{\mu}l$), S4 ($2.8{\times}10^6copies/{\mu}l$), and S3 ($2.4{\times}10^6copies/{\mu}l$).

Microbial Community of Tannery Wastewater Involved in Nitrification Revealed by Illumina MiSeq Sequencing

  • Ma, Xiaojian;Wu, Chongde;Jun, Huang;Zhou, Rongqing;Shi, Bi
    • Journal of Microbiology and Biotechnology
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    • v.28 no.7
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    • pp.1168-1177
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    • 2018
  • The aim of this study was to investigate the microbial community of three tannery wastewater treatment plants (WWTPs) involved in nitrification by Illumina MiSeq sequencing. The results showed that highly diverse communities were present in tannery wastewater. A total of six phyla, including Proteobacteria (37-41%), Bacteroidetes (6.04-16.80), Planctomycetes (3.65-16.55), Chloroflexi (2.51-11.48), Actinobacteria (1.91-9.21), and Acidobacteria (3.04-6.20), were identified as the main phyla, and Proteobacteria dominated in all the samples. Within Proteobacteria, Beta-proteobacteria was the most abundant class, with the sequence percentages ranging from 9.66% to 17.44%. Analysis of the community at the genus level suggested that Thauera, Gp4, Ignavibacterium, Phycisphaera, and Arenimonas were the core genera shared by at least two tannery WWTPs. A detailed analysis of the abundance of ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB) indicated that Nitrosospira, Nitrosomonas, and Nitrospira were the main AOB and NOB in tannery wastewater, respectively, which exhibited relatively high abundance in all samples. In addition, real-time quantitative PCR was conducted to validate the results by quantifying the abundance of the AOB and total bacteria, and similar results were obtained. Overall, the results presented in this study may provide new insights into our understanding of key microorganisms and the entire community of tannery wastewater and contribute to improving the nitrogen removal efficiency.

Effects of Nitrifying Bacterial Communities with Different HRTs and Backwashing Periods in Modified BAF Process (Modified BAF 공정에서 HRT 및 역세주기가 질산화 미생물의 군집에 미치는 영향)

  • Jung, Chul-Soo;Park, Jeung-Jin;Ju, Dong-Jin;Kwon, Soo-Youn;Choi, Won-Seok;Byun, Im-Gyu;Park, Tae-Joo
    • Journal of Korean Society on Water Environment
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    • v.23 no.6
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    • pp.920-926
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    • 2007
  • The upflow Biobead$^{(R)}$ process, one of biological aerated filters (BAF), which was used commercially, invented for removal of organic materials and nitrification. This process was modified to enhance the ability of denitrification through the induction of pre-anoxic tank. In this research, we investigated the effects of hydraulic retention time (HRT) and backwashing period in aerobic tank. The characteristics of nitrifying bacteria, which are composed of ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB), also investigated using fluorescence in situ hybridization (FISH). Even though the HRT was shortened, the efficiency of nitrification was not decreased when the organic loading rate and ammonium-nitrogen loading rate were $2.10kg/m^3/day$ and $0.25kg/m^3/day$, respectively. And then the distribution ratios of AOB and NOB showed the similar patterns. However, when the backwashing period was lengthened from 12 hours to 24 hours in aerobic 1 tank, the nitrification efficiency was decreased to 63.9% from 89.2%. The results of FISH explained that this decrease of nitrification efficiency was caused by the decrease of distribution ratio of AOB in aerobic 1 tank. The nitrification efficiencies of aerobic 1 and aerobic 2 tank were increased when the backwashing period was lengthened because of relative high distribution ratios of nitrifying bacteria.

Optimization of Mutant Strain of the Sulfur-Oxidizing Bacteria, Thiobacillus sp. UIW-6 (황산화 세균 Thiobacillus sp. UIW-6 변이주의 성장 최적화)

  • Shin, Seung-Yong;Kang, Sun-Chul
    • Korean Journal of Environmental Agriculture
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    • v.25 no.2
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    • pp.124-128
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    • 2006
  • To reducing offensive odor form compost UIW-6 mutant obtained by UV treatment from sulfur-oxidizing bacteria, Thiobacillus sp. IW. The UIW-6 mutant was found 1.6 times faster in growth than the parent strain on thiosulfate medium (TM) at 36 h after incubation. Initial pH, temperature and agitation for the optimum growth of UIW-6 were 6.5, $35^{\circ}C$ and 200 rpm, respectively. The UIW-6 mutant growth was two times higher than parent strain at 6 h culture in TM liquid medium containing 50 mM sodium thiosulfate. The UIW-6 mutant used fructose and sucrose as carbon sources and yeast extract> tryptone> peptone as nitrogen ones. It was found that the growth of UIW-6 was increased in addition of 0.2% yeast extract.

The Formation of Reactive Species on the Nitrogen Oxide in the Ultraviolet Photolysis of N-Nitrosodimethylamine (N -Nitrosodimethylamine의 자외선 광분해 시 질소산화물 생성에 미치는 반응성 화학종의 형성)

  • Kwon, Joongkuen;Kim, Jongoh;Kwon, Bumgun
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.2
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    • pp.75-81
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    • 2012
  • Because N-Nitrosodimethylamine(NDMA) is well-known as a potential carcinogen, extensive research has addressed its treatment by ultraviolet(UV) and its degradation pathway. However, the detailed mechanism by which NDMA is photolyzed to form oxidized products, i.e., ${NO_2}^-$ and ${NO_3}^-$, is still not understood. This study reveals a key reactive species during the photolysis of NDMA. The study on a key reactive species was indirectly performed with the formation of nitrogen oxidized products and reactions between methanol and an unknown reactive species formed during the photolysis of NDMA. The peroxynitrite($ONOO^-$) generated by the direct UV photolysis of NDMA would be identified as a key reactive species in oxidizing nitrogen intermediates to ${NO_2}^-$and ${NO_3}^-$.