• Title/Summary/Keyword: Nitrogen flow ratio

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Synthesis of Ultrafine Silicon Nitride Powders by the Vapor Phase Reaction (기상반응에 의한 $Si_3N_4$ 미세분말의 합성)

  • 유용호;어경훈;소명기
    • Journal of the Korean Ceramic Society
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    • v.37 no.1
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    • pp.44-49
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    • 2000
  • Silicon nitride powders, were synthesized by the vapor phase reaction using SiH4-NH3 gaseous mixture. The reaction temperature, ratio of NH3 to SiH4 gas and the overall gas quantity were varied. The synthesized powders were characterized using X-ray, TEM, FT-IR and EA. The synthesized silicon nitride powders were in amorphous state, and the average particle size was about 100nm. TEM analysis revealed that the particle size decreased with increasing reaction temperature and gas flow quantity. As-received amorphous powders were annealed in nitrogen atmosphere at 140$0^{\circ}C$ for 2h, then the powders were completely crystallized at 0.2 ratio of NH3 to SiH4.

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Oxygen Transfer Rate Coefficient of Membrane Aeration Bioreactor for Vero Cell Culture

  • Jeon, Ju-Mi;Jeong, Yeon-Ho;Kim, Ik-Hwan;Lee, Sang-Jong;Jang, Yong-Geun;Jeon, Gye-Taek
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.269-270
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    • 2002
  • Oxygen is a key substrate in animal cell metabolism and its consumption is thus a parameter of great interest for monitoring and control in animal cell culture bioreactor. The use of a gas-permeable membrane offered the possibility to provide the required quantity of oxygen into the culture. while avoiding problems of foaming or shear damage generally linked to sparging. For determining the optimum DO control strategy of this gas-permeable membrane aeration bioreactor, the oxygen transfer rate coefficient was measured with varying $N_2$ ratio in inlet air. The results showed that an increasing mass flow rate of nitrogen reduced the $K_La$ value. and 5% nitrogen in air did not result in any oxygen limitation.

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Characteristic of Tantalum Nitride Thin-films for High Precision Resistors (고정밀 저항용 질화탄탈 박막의 특성)

  • Choi, Sung-Kyu;Na, Kyung-Il;Nam, Hyo-Duk;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.537-540
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    • 2001
  • This paper presents the characteristics of Ta-N thin-film for high precision resistors, which were deposited on Si substrate by DC reactive magnetron sputtering in an argon-nitrogen atmosphere(Ar-(4~16 %)$N_2$). Structural properties studied using X-ray diffraction(XRD) indicate the presence of TaN, $Ta_3N_5$ or a mixture of Ta-N phases in the films depending on the amount of nitrogen in the sputtering gas. The chemical composition are investigated by auger electro spectroscopy(AES). The optimized conditions of Ta-N thin-film resistors were deposited in 4 % $N_2$ gas flow ratio. Under optimum conditions, the Ta-N thin-film resistors are obtained a high resistivity, $\rho=305.7{\mu}{\Omega}cm$, a low temperature coefficient of resistance, TCR=-36 $ppm/^{\circ}C$.

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Structure Behavior of Sputtered W-B-C-N Thin Film for various nitrogen gas ratios (PVD법으로 증착한 W-B-C-N 박막의 질소량에 따른 구조변화 연구)

  • Song, Moon-Kyoo;Lee, Chang-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.109-110
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    • 2005
  • We have suggested sputtered W-C-N thin film for preventing thermal budget between semiconductor and metal. These results show that the W-C-N thin film has good thermal stability and low resistivity. In this study we newly suggested sputtered W-B-C-N thin diffusion barrier. In order to improve the characteristics, we examined the impurity behaviors as a function of nitrogen gas flow ratio. This thin film is able to prevent the interdiffusion during high temperature (700 to $1000^{\circ}C$) annealing process and has low resistivity ($\sim$200$\mu{\Omega}-cm$). Through the analysis of X-Ray diffraction, resistivity and XPS, we studied structure behavior of W-B-C-N diffusion barrier.

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An Emission Characteristics of a Controlled Auto-Ignition Gasoline Engine (제어자발화 가솔린기관의 배기 특성)

  • Kim, H.S.
    • Journal of Power System Engineering
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    • v.13 no.3
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    • pp.5-10
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    • 2009
  • This work deals with a controlled auto-ignition (CAI) single cylinder gasoline engine, focusing on the extension of operating conditions. The fuel is injected indirectly into electrically heated inlet air flow. In order to keep a homogeneous air-fuel mixing, the fuel injector is cooled by the water of a specially designed coolant passage. The engine emission characteristics were investigated under the wide range of operating conditions such as 32 to 63 in the air-fuel ratio, 1000 to 1800 rpm in the engine speed, and 150 to $180^{\circ}C$ in the inlet air temperature. The ultra lean-burn can be achieved by the auto-ignition of gasoline fuel due to the heated inlet air in the compression ignition gasoline engine. It is confirmed that the emission concentrations of carbon monoxide, hydrocarbons and nitrogen oxide can be significantly reduced by CAI combustion compared with the combustion of a conventional spark ignition engine.

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Characteristic of Tantalum Nitride Thin-films for High Precision Resistors (고정밀 저항용 질화탄탈 박막의 특성)

  • 최성규;나경일;남효덕;정귀상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.537-540
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    • 2001
  • This paper presents the characteristics of Ta-N thin-(ibm for high precision resistors, which were deposited oni substrate by DC reactive magnetorn sputtering in an argon-nitrogen atmosphere(Ar-(4∼16%)N$_2$). Sturcutural properties sutided using X-ray diffraction (XRD) indicate the presence of TaN, Ta$_3$N$\sub$5/ or a mixture of Ta-N phases in the films depending on the amount of nitrogen in the sputtering gas. The chemical composition are investigated by auger electro spectroscopy(AES). The optimized conditions of Ta-N thin-film resistors were deposited in 4 % N$_2$ gas flow ratio. Under optimum conditions, the Ta-N thin-film resistors are obtained a high resistivity, $\rho$=305.7 ${\mu}$Ωcm, a low temperature coefficient of resistance, TCR=-36 ppm/$^{\circ}C$.

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Performance and Emission Characteristics of Compression Ignition Gasoline Engine (압축점화 가솔린기관의 성능 및 배기특성)

  • Kim, Hong-Sung;Kim, Mun-Heon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.7
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    • pp.1007-1014
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    • 2003
  • This work deals with a controlled auto-ignition (CAI) single cylinder gasoline engine, focusing on the extension of operating conditions. The fuel is injected indirectly into electrically heated inlet air flow. In order to keep a homogeneous air-fuel mixing, the fuel injector is water-cooled by a specially designed coolant passage. Investigated are the engine performance and emission characteristics under the wide range of operating conditions such as 32 to 63 in the air-fuel ratio, 1000 to 1800 rpm in the engine speed, and 150 to 18$0^{\circ}C$ in the inlet air temperature. The compression ignition gasoline engine can be achieved that the ultra lean-burn with self-ignition of gasoline fuel by heating inlet air. For example. the allowable lean limit of air-fuel ratio is extended until 63 at engine speed of 1000 rpm and inlet air temperature of 17$0^{\circ}C$. It can be achieved that the emission concentrations of carbon monoxide, hydrocarbons and nitrogen oxide had been significantly reduced by CAI combustion compared with conventional spark ignition engine.

An Experimental Study on the Pumping Performance of the Multi-stage Disk-type Drag Pump (다단 원판형 드래그펌프의 배기 성능에 관한 실험적 연구)

  • 권명근;허중식;황영규
    • Journal of the Korean Vacuum Society
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    • v.12 no.2
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    • pp.79-85
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    • 2003
  • Experimental investigations are performed for the rarefied gas flows in a multi-stage disk-type drag pump. The pump considered in the present study consists of grooved rotors and stators. The flow-meter method is adopted to calculate the pumping speed. Compression ratios and pumping speeds for the nitrogen gas are measured under the outlet pressure range of 0.13∼533 Pa. The present experimental data show the leak-limited value of the compression ratio in the molecular transition region. The rotational speed of the pump is 24,000rpm, and nitrogen is used as a test gas. The pumping characteristics of various drag pumps are performed. The inlet pressures are measured for various outlet pressures of the test pump. The ultimate pressures for zero throughput are measured for three-stage, two-stage and single-stage disk-type, respectively.

Simultaneous Denitrification and Methanogenesis at Various ${NO_3}^--N/COD$ Ratios in an USB Reactor (USB 반응조에서 ${NO_3}^--N/COD$ 비해 따른 탈질과 메탄화 동시반응)

  • Park, Sang-Min;Jun, Hang-Bae;Park, Noh-Back;Oh, Gyu-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.11
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    • pp.1174-1179
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    • 2005
  • Up-flow sludge blanket(USB) reactors were used to investigate the effects of N/C(${NO_3}^--N/COD$) ratio on simultaneous denitrification and methanogenesis processes. Without nitrate feeding, 84% of the influent COD was converted into methane. With the increase of N/C ratio, nitrogen gas increased while methane production decreased and stopped finally at the N/C ratio over 0.20. Influent nitrate was completely denitrified into nitrogen gas while nitrate removal efficiency dropped below 40% at N/C ratio of 0.40 because of deficiency in organic carbon. Fraction of COD utilized by denitrification increased at higher N/C ratios. Methanogenesis started to be effected at N/C ratio of 0.05, which could explain the competition for organic carbon between these microorganisms such as denitrifiers and methanogens, rather than inhibitory effect of nitrate and its intermediates. Critical N/C ratio for simultaneous denitrification and methanogenesis was found to be 0.20. Influent COD was removed over 92% by denitrification, methanogenesis and other biochemical reactions including cell growth at these N/C ratios.

The Research about the Water Quality Prediction at Imha Reservoir Using a WASP7 Model (WASP7 모형을 이용한 임하호 수질모의에 관한 연구)

  • Ahn, Seung-Seop;Seo, Myung-Joon;Jung, Do-Joon;Park, Ro-Sam
    • Journal of Environmental Science International
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    • v.17 no.6
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    • pp.611-621
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    • 2008
  • This study intends to provide the necessary basic data needed for predicting the water quality and examining changes in water quality on the basis of the hydrological changes: an outflow or the character of a flow by investigating the interaction of the parameters through the estimation of optimal parameters need for predicting the water quality of the dam basin and the sensitivity among those estimated parameters. Im-Ha Dam in the upstream area of the Nakdong River was selected for analysis, and the water quality survey data necessary for parameter estimation was based on the monthly water quality data (water temperature, BOD, T-N and T-P) between December 1, $2005{\sim}$November 31, 2006. K1C(the saturated growth rate of plant plankton), K1RC (endogenous respiratory quotient of plankton), KDC(deoxidized ratio), K71C(minealized ratio of dissolved organic phosphorus), K83C(mineralized ratio of dissolved organic nitrogen) have been considered as the factors of the water quality performed in this water quality simulation, that is, the most effective parameters on BOD, T-N and T-P. In the result of the analysis of the sensitivity, KDC(deoxidized ratio) was the most sensitively reacted parameter on BOD and it was K71C(mineralized ratio of dissolved organic phosphorus) and K83C(mineralized ratio of dissolved organic nitrogen) on T-N and T-P. It is considered that it will be possible to apply the most optimal parameter to an analysis of the water quality simulation at Im-Ha Ho basin in the goal year by examining the interaction of the parameters through the parameters sampling which are able to applicable to prediction of the water quality and the analysis of the its sensitivity, in the future, also the analysis on the basis of the hydrological conditions: an outflow or the character of a flow will be needed.