• Title/Summary/Keyword: Nitrogen dioxide($NO_2$)

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Scenario Analysis of Personal Nitrogen Dioxide Exposure with Monte Carlo Simulation on Subway Station Workers in Seoul (확률론적 모의실험 기법을 이용한 일부 지하철 근무자들의 이산화질소 개인노출 시나리오 분석)

  • 손부순;장봉기;양원호
    • Journal of Environmental Science International
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    • v.10 no.3
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    • pp.195-200
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    • 2001
  • The personal exposures of nitrogen dioxide(NO$_2$), microenvironmental levels and daily time activity patterns on Seoul subway station workers were measured from February 10 to March 12, 1999. Personal NO$_2$exposure for 24 hours were 29.40$\pm$9.75 ppb. NO$_2$level of occupational environment were 27.87$\pm$7.15 ppb in office, 33.60$\pm$8.64 ppb in platform and 50.13$\pm$13.04 ppb in outdoor. Personal exposure time of subway station workers was constituted as survey results with $7.94\pm$3.00 hours in office, $2.82\pm$1.63 hours in platform and 1 hours in outdoor. With above results, personal $NO_2$exposure distributions on subway station workers in Seoul were estimated with Monte Carlo simulation which uses statistical probabilistic theory on various exposure scenario testing. Some of distributions which did not have any formal patterns were assumed as custom distribution type. Estimated personal occupational $NO_2$exposure using time weighted average (TWA) model was 31.$29\pm$5.57 ppb, which were under Annual Ambient Standard (50ppb) of Korea. Though arithmetic means of measured personal $NO_2$exposure was lower than that of occupational $NO_2$exposure estimated by TWA model, considering probability distribution type simulated, probability distribution of measured personal $NO_2$exposures for 24 hours was over ambient standard with 3.23%, which was higher than those of occupational exposure(0.02%). Further research is needed for reducing these 24 hour $NO_2$personal excess exposures besides occupational exposure on subway station workers in Seoul.

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A Case of Pulmonary Injuny Induced by Accidental Exposure to High Level of Nitrogen Dioxide ($NO_2$) (고농도의 이산화질소($NO_2$)흡입으로 유발된 급성 폐손상 1례)

  • Chang Jin Hyuck;Kim Do Youn;Kim Young;Chang Yoon Soo;Kim Hyung Jung;Ahn Chul Min;Kim Sung Kyu;Kim Tae Hoon
    • Journal of The Korean Society of Clinical Toxicology
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    • v.3 no.1
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    • pp.40-44
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    • 2005
  • Nitrogen dioxide ($NO_2$), which produced during the process of silage, metal etching, explosives, rocket fuels, welding, and by-product of burning of fossil fuels, is one of major components of air pollutant. Accidental exposure of high level of $NO_2$ produces cough, dyspnea, pulmonary edema which may be delayed $4\~12$ hours and, in $2\~6$weeks, bronchiolitis obliterans. We experienced a case of acute pulmonary injuny induced by industrial exposure to high level of $NO_2$ during repair of $NO_2$ pipeline in a refinery. A 55-year-old man experienced nausea and severe dyspnea in 6 hours after $NO_2$ inhalation. Initial blood gas examination revealed severe hypoxemia accompanying increased alveolar-arterial O2 difference. Radiological examination showed diffuse ground glass opacities in both lung fields. Clinical symptoms and laboratory findings, including radiological study and pulmonary function test were improved with conservative treatment using inhaled oxygen and bronchodilator. and there was no evidence of bronchial fibrosis and bronchiolitis obliterance in chest high resolution computed tomography performed 6 weeks after exposure. Here, we report a case of $NO_2$ induced acute pulmonary injuny with a brief review of the relevant literature.

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$PM3.5/NO_2$ Concentration Ratio in Roadside and Exposure Assessment of Shoes Repairmen in Seoul (서울시 도로변의 $PM3.5/NO_2$ 농도비 및 구두수선대 근로자의 노출평가)

  • 배현주;양원호;김나리;정문호
    • Journal of environmental and Sanitary engineering
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    • v.16 no.4
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    • pp.21-30
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    • 2001
  • Vehicles, especially diesel-using, are a major source of airborne particulate matter(PM), nitrogen dioxide($NO_2$) and so on in metropolitan cities such as Seoul. Therefore workers, who are mainly merchants, near roadside may be highly exposed to air pollutants from exhausted emissions of vehicles. This means that occupational type and location can affect the workers'health by exposure to outdoor pollutions of ambient as well as indoor pollutions of working condition, respectively. In this study, we simultaneously measured the PM3.5 and $NO_2$concentrations in indoor and outdoor of shoes repair shops in Seoul, which were generally located at roadside in Korea. Shoes repairmen were highly exposed to PM3.5 and $NO_2$ both indoor and outdoor of repair shops comparing with other sub-population groups. High exposure to air pollutants for shoes repairmen was considered to be outdoor source from exhausted emission of vehicles and indoor source from working condition. The $PM3.5/NO_2$ concentration ratio was $1.17{\pm}$0.59 in roadside, of which ratio was higher 7han ratios of other studies. This result suggested that major air pollutant in Seoul was fine particle. Also, this PM3.5 to $NO_2$ ratio will be used in environmental exposure and risk assessment by estimation of PM3.5 concentration as measuring the only $NO_2$ concentration with small and accurate $NO_2$ passive sampler.

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Potential Exposure of Indoor Air Pollutants inside Vehicle for Professional Taxi Drivers (영업용 택시 운전자들의 공기오염물질 노출평가)

  • Yang Won-Ho;Kim Dae-Won;Kim Young-Hee;Kim Jong-Oh
    • Journal of environmental and Sanitary engineering
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    • v.20 no.4 s.58
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    • pp.69-75
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    • 2005
  • Professional taxi driver exposure to indoor air pollutants has been a subject of concern in recent years because of higher levels of air pollutants, comparing to the surrounding atmosphere. This study evaluated the potential exposure to respirable suspended particulate (RSP), nitrogen dioxide $(NO_2)$ and volatile organic compounds (VOCs; benzene and toluene) for professional taxi drivers inside each of 10 vehicles in Pusan, comparing weekday (Monday and Thursday) and weekend (Saturday). Indoor mean concentrations of RSP inside vehicle were $53.88\;ug/m^3\;and\;75.52\;ug/m^3$ on weekday and weekend, respectively. Measured indoor $NO_2$ concentrations were 28.32ppb and 40.69 ppb, respectively. Benzene and toluene mean concentrations inside vehicle were 5.41 ppb and 11.36 ppb, respectively. Considering no smoking of taxi drivers inside vehicle, closed window in winter, and increased usage of taxi on weekend, source of indoor air pollutants inside taxi might be mainly suggested from the number of passenger's carried, faulty exhaust systems, and engine and carburetor evaporative emissions.

A Study on the Emission Factors of Air Pollutants for the Melting Furnaces of the Iron and Steel Industry (철강산업 용융로의 대기오염물질 배출계수 산정 연구)

  • 석광설;방선애;홍지형;이석조;김대곤;이대균;허정숙;이은정
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.4
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    • pp.571-578
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    • 2004
  • The purpose of this study is to estimate of emission factors of the air pollutants for the melting furnaces for the iron and steel industry. The result of this study is able to obtaine the emission factor of particulate matters (PM), sulfur dioxide. nitrogen oxides for melting furnace. The emission factors of each pollutants were as follows : - the emission factor varied between 6.13E-03~6.12E-01 kg/ton for PM -1.59E-01~2.45E+00kg/ton for $SO_2$ - 6.82E-02~6.88E-01 kg/ton for NOx, respectively. Analysis of the differences in the emission factors of ours and U.S. EPA's yielded the following results for the Wilcoxon method : p>0.05. The statistical analysis showed no differences in the our emission factors and U.S. EPA's

Determination of Nitrogen Dioxide Exposure for University Students by Activity Pattern of Weekday and Weekend (평일과 주말의 활동변화에 따른 대학생들의 이산화질소 노출)

  • 양원호;손부순;박종안;정문호
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.58-64
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    • 2000
  • Indoor air quality tends to be the dominant contributor to personal exposure, because most people spend over 80% of their time indoors. In this study, indoor and outdoor NO$_2$ concentrations were measured and compared with simultaneously personal exposures of 21 university students in weekday and weekend. House characteristics and activity pattern were used to determine the impacts of these factors on personal exposure. Since university students spent most of their times in indoor, their NO$_2$ exposure was associated with indoor NO$_2$ level rather than outdoor NO$_2$ level both weekday and weekend in spite of different time activity. Using time-weighted average model, NO$_2$ exposures of university students were estimated by NO$_2$ measurements in indoor home, indoor school, and outdoor home levels. Estimated NO$_2$ personal exposures were significantly correlated with measured NO$_2$ personal exposures($r^2$=0.87). However, estimated personal NO$_2$ exposures by time-weighted average model were underestimated, comparing with the measured personal NO$_2$ exposure. Using multiple regression analysis, effect of personal NO$_2$ exposure for transportation was confirmed.

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Comparison Study of Nitrogen Dioxide and Asthma Doctor's Diagnosis in Seoul - Base on Community Health Survey 2012~2013 - (서울시 대기 중 이산화질소 농도와 천식증상의 비교 연구 - 2012~2013년 지역사회건강조사 자료를 중심으로 -)

  • Lee, Sang-Gyu;Lee, Yong-Jin;Lim, Young-Wook;Kim, Jung-Su;Shin, Dong-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.575-582
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    • 2016
  • Seoul city has high population density as well as high traffic congestion, which are vulnerable to exposure of environmental pollutions caused by car traffic. However, recent studies are only on local regions about road traffic and air pollution or health effect of road traffic on residents. Thus, comprehensive study data are needed in terms of overall Seoul regions. In this study utilized the nitrogen dioxide concentration through the national air pollution monitoring network data, 2012 to 2013. It also divided regions into high and low exposure districts via the Origin destination data developed by the Korea transport institute to quantify and evaluate the effect of transport policies and analyzed a correlation of asthma symptoms with high and low exposure districts through raw data of community health survey from the Korea centers for disease control and prevention. Based on the collected data, the pearson's correlation analysis was conducted between air pollution substance concentration and high exposure district and multiple logistic regression analysis was conducted to determine the effect of traffic environment and factors on asthma symptoms of residents. Accordingly, the following results were derived. First, the high exposure district was higher concentrations of nitrogen dioxide ($NO_2$) as per time compared to those of the low exposure district (p<0.01). Second, analysis on correlation between average daily environmental concentration in the air pollution monitoring network and road traffic showed that nitrogen dioxide had a significant positive correlation (p<0.01) with car traffic and total traffic as well as with truck traffic (p<0.05) statistically. Third, an adjusted odds ratio about asthma doctor's diagnosis in the high and low exposure districts was analyzed through the logistic regression analysis. With regard to an adjusted model 2 (adjusted gender, age, health behavior characteristics, and demographic characteristics) odds ratio of asthma doctor's diagnosis in the high exposure district was 1.624 (95% CI: 1.269~2.077) compared to that of the low exposure district, which was significant statistically (p<0.001).

Estimation of Source Strength and Deposition Constant of Nitrogen Dioxide Using Compartment Model (구획모델을 이용한 주택에서 이산화질소의 발생강도 및 감소상수 동시 추정)

  • Yang Won-Ho;Son Bu-Soon;Sohn Jong-Ryeul
    • Journal of Environmental Health Sciences
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    • v.31 no.4 s.85
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    • pp.260-265
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    • 2005
  • Indoor air quality might be affected by source strength of indoor pollutants, ventilation rate, decay rate, outdoor level, and so on. Although technologies measuring these factors exist directly, direct measurements of all factors are not always practical in most field studies. The purpose of this study was to develop an alternative method to estimate the source strength and deposition constant by application of multiple measurements. For the total duration of 60 days, indoor and outdoor $NO_2$ concentrations every 3 days were measured in 30 houses in Seoul, Asan and Daegu. Using a compartment model by mass balance and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor (emission rate divided by sum of air exchange rate and deposition constant) were calculated. Subsequently, the source strength and deposition constant were estimated. Natural ventilation was $1.80{\pm}0.42\;ACH,\;1.11{\pm}0.50\;ACH,\;0.92{\pm}0.26\;ACH$ in Seoul, Asan and Daegu, respectively. Calculated deposition constant(K) and source strength of $NO_2,$ in this study were $0.98{\pm}0.28\;hr^{1}\;and\;16.28{\pm}7.47\;ppb/h,$ respectively.

Air pollution study using factor analysis and univariate Box-Jenkins modeling for the northwest of Tehran

  • Asadollahfardi, Gholamreza;Zamanian, Mehran;Mirmohammadi, Mohsen;Asadi, Mohsen;Tameh, Fatemeh Izadi
    • Advances in environmental research
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    • v.4 no.4
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    • pp.233-246
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    • 2015
  • High amounts of air pollution in crowded urban areas are always considered as one of the major environmental challenges especially in developing countries. Despite the errors in air pollution prediction, the forecasting of future data helps air quality management make decisions promptly and properly. We studied the air quality of the Aqdasiyeh location in Tehran using factor analysis and the Box-Jenkins time series methods. The Air Quality Control Company (AQCC) of the Municipality of Tehran monitors seven daily air quality parameters, including carbon monoxide (CO), Nitrogen Monoxide (NO), Nitrogen dioxide ($NO_2$), $NO_x$, ozone ($O_3$), particulate matter ($PM_{10}$) and sulfur dioxide ($SO_2$). We applied the AQCC data for our study. According to the results of the factor analysis, the air quality parameters were divided into two factors. The first factor included CO, $NO_2$, NO, $NO_x$, and $O_3$, and the second was $SO_2$ and $PM_{10}$. Subsequently, the Box- Jenkins time series was applied to the two mentioned factors. The results of the statistical testing and comparison of the factor data with the predicted data indicated Auto Regressive Integrated Moving Average (0, 0, 1) was appropriate for the first factor, and ARIMA (1, 0, 1) was proper for the second one. The coefficient of determination between the factor data and the predicted data for both models were 0.98 and 0.983 which may indicate the accuracy of the models. The application of these methods could be beneficial for the reduction of developing numbers of mathematical modeling.

NO2 gas sensing characteristics of patterned carbon nanotube mats (패턴이 형성된 탄소나노튜브 매트의 이산화질소 감응 특성)

  • Cho, Woo-Sung;Moon, Seung-Il;Paek, Kyeong-Kap;Park, Jung-Ho;Ju, Byeong-Kwon
    • Journal of Sensor Science and Technology
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    • v.15 no.3
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    • pp.199-204
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    • 2006
  • Carbon nanotube (CNT) mats grown by thermal chemical vapor deposition on a micromachined substrate with a chrome heater and a diaphragm were investigated as sensing materials of resistive gas sensors for nitrogen dioxide ($NO_{2}$) gas. The aligned CNT mats fabricated into mesh and serpentine shapes by the patterned cobalt catalyst layer. CNT mats showed a p-type electrical resistivity with decreasing electrical resistance upon exposure to $NO_{2}$. All sensors exhibited a reversible response at a thermal treatment temperature of $130^{\circ}C$ for about 5 minutes. The resistance change to $NO_{2}$ of the mesh-shaped CNT mats was larger than that of the serpentine-shaped CNT mats.