• Macromolecular Research
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• v.17 no.9
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• pp.631-637
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• 2009

This study examined the unique self-doping behavior of carboxylated polyaniline (PCA). The self-doped PCA was synthesized using an environmentally benign enzymatic polymerization method with cationic surfactants. XPS showed that HCl-doped PCA contained approximately 34% of protonated amines but self-doped PCA contained 9.6% of the doped form of nitrogen at pH 4. FTIR and elemental analysis showed that although the PCA was doped with the proton of strong acids at low pH via the protonation of amines, the self-doping mechanism of PCA at pH > 4 was mainly due to hydrogen bonding between the carboxylic acid group and amine group.

• Proceedings of the Safety Management and Science Conference
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• 2012.04a
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• pp.221-232
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• 2012

Cycle analysis has been performed to find out the optimum design point of the BOG re-liquefaction plant. The cycle state, defined by three cycle variables, was mainly described by the three cold temperatures of the three-pass heat exchanger, on which the constraints by the heat exchanger are imposed. The cycle states which are confined within a domain limited by the temperature constraints were the primary issue of this study. The BOG mass within the domain was analyzed first and then the cycle performance was related to the BOG mass afterwards, which enabled us to explain the observed behavior of the cycle performance under the temperature constraints by the heat exchanger. A good cycle performance could be ensured if the two cold Nitrogen temperatures of the three temperatures were placed close together near $-140^{\circ}C$ while the BOG temperature is kept far above enough, but not too far, from $-140^{\circ}C$ such that it does not interfere in their optimum temperature range.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2009.05a
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• pp.302-305
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• 2009

This paper examines the effect of nitride formation on formability for Cu bearing high strength extra low carbon (ELC) steel sheets. For this purpose, we have investigated the effect of addition of aluminium (Al) and boron (B) on texture and precipitation behavior of the ELC steel during continuous annealing. Mechanical properties and microstructures of the ELC steel sheets were analyzed as well using uni-axial tensile test, electron back-scattered diffraction (EBSD) technique and transmission electron microscopy (TEM) following pilot rolling and continuous annealing. It has been found that the addition of Al and B increases the precipitation of AlN and BN. What is more, the scavange of solute nitrogen is effective in increasing the formability of the ELC steels. In addition, the Al and B addition improves the aging property of the ELC steel.

• Progress in Superconductivity and Cryogenics
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• v.7 no.3
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• pp.1-4
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• 2005

As high temperature superconductor applications became a reality due to increase in coated conductor performance, it is important to understand their stability behavior to design safe electrical power systems. Coated conductors can be stabilized with different metals and alloys for different types of application, to yield excellent electrical, thermal and mechanical performance. We have experimentally studied the dependence of quench and recovery characteristics of stainless steel stabilized coated conductors on the amplitude of current and duration time. Stability test of 3cm long sample were performed in a liquid nitrogen bath cooling condition by applying a short period over current pulses for 50 and 100ms, with amplitude up to ~6 times the critical current. The transport current that flows before and after the current pulse was fixed at about ~80-85% critical current. We analyzed the quench and recovery phenomena of the test sample using the current voltage characteristic.

• Environmental Engineering Research
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• v.15 no.1
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• pp.41-48
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• 2010

This paper describes the influence of nutrient salts eluted from the bottom of a closed water area where polluted sediment has been deposited by inflowing river water. The elution pattern was monitored at our experimental facility. Both the sediment pore water and water above the bottom were sampled using a dialyzer sampler (peeper). The pore water of the eutrophicated sediment contained a large amount of nutrient salts, and the effect of elution was confined to a limited area of the bottom surface. The nutrient concentration of the sediment pore water was closely related to both the water temperature and dissolved oxygen (DO) concentration. The eluted nutrients from the sediment provided a source for phytoplankton and algae growth. This experimental data indicated that the water quality of the surface was not directly connected to the eluted nutrient salts, while it was indirectly affected by the total ecosystem, including all the organisms within an area and their environment.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.965-966
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• 2007

For practical electrical insulation design of high temperature superconducting (HTS) power apparatuses, knowledge of the dielectric behavior of insulators in cryogenic liquid such as liquid nitrogen ($LN_2$) is essential. So in this paper, we discussed experimental investigations of breakdown and V-t characteristics of several insulators such as Kapton and glass fiber reinforced plastic (GFRP) that are candidates of insulator for HTS apparatus in cryogenic liquid. And we investigated the degradation of these insulation samples after breakdown with the microscope and SEM photograph. Moreover, survival and hazard analysis was performed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.288-289
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• 2005

As high temperature superconductor applications became a reality due to increase in coated conductor performance, it is important to understand their stability behavior to design safe electrical power systems. We have experimentally studied the dependence of quench and recovery characteristics of coated conductors on the amplitude of current and duration time. The sample used in the present study is stabilized with stainless steel. Stability tests of 3 cm long sample were performed in a liquid nitrogen bath cooling condition by applying a short period over current pulses for 50 and 100 ms, with amplitude up to ~ 6 times of the critical current. The transport current that follows before and after the current pulse was fixed about ~85% the critical current. We analyzed the quench recovery using the current voltage characteristic.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2007.04a
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• pp.73-73
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• 2007

Amorphous BON and Si-DLC thin films were synthesized by the RF plasma enhanced CVD method, and their oxidation behavior was studied up to $500^{\circ}C$ in air. The oxidation of both films was accompanied by evaporation of volatile species. The oxidation of BON film was preceded by nitrogen escape from the film, and oxygen penetration into the film. The oxidation of Si-DLC film was preceded by carbon escape probably as CO or $CO_2$from the film, and oxygen penetration into the film. The inwardly transported oxygen simply stayed in the oxidized BON and Si-DLC thin films.

• Bulletin of the Korean Chemical Society
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• v.21 no.1
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• pp.39-43
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• 2000

New coordination polymers of general form, $$[CoL_2X_2]_n$$ (L = 3,3'-oxybis(pyridine) (obp), 1,4-bis(3-pyri-doxy) benzene (bpob); X = Cl, NCS), have been prepared via a slow diffusion method. The reaction of the present linkers with cobalt(II) ion affords infinite 2-dimensional sheet products. For $[Co(obp) $_2Cl_2]_n$$, the local geometry of the cobalt center is an octahedral arrangement with four nitrogen donors and two chlorine ions in trans positions. $$[Co(bpob)_2(NCS)_2]_n$$ has provided a similar structure: the local geometry of the cobalt atom is an octahedral arrangement with four pyridine units and two NCS groups in transpositions. The obp and bpob linkers connect two cobalt(II) ions defining the edges of 40- and 60-membered $[Co(II)]_4$ ring, respectively. Thermal analyses of the coordination polymers show significant thermal behavior associated with the characteristic structures.

• Korean Journal of Materials Research
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• v.2 no.4
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• pp.285-292
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• 1992

Ultrathin(8nm) oxynitride (SiOxNy) film have been formed on Si(100) by rapid thermal processing(RTP) in $O_2$and $N_2$O as reactants. Compared with conventional furnace $O_2$ oxide, the oxynitride dielectrics shows better characteristics of I-V and TDDB, and less flat-band voltage shift. The oxynitride has a behavior of Fowler-Nordheim tunneling in the region of V 〉${\varphi}_0$ simialr to pure Si$O_2$oxide. The relative dielectric constant of oxynitride is higher than that of conventional pure oxide. Excellent diffusion harrier property to dopant(B$F_2$) is also observed. Nitrogen depth profiles by SIMS, AES, and XPS show nitrogen pile - up at Si$O_2$/Si interface, which can explain the improved properties of oxynitride dielectrics.