• 한국물환경학회지
• /
• 제23권3호
• /
• pp.397-402
• /
• 2007

Anammox reactor seeded with sewage sludge from RBC reactor and anaerobic granule from full-scale UASB reactor treating distillery wastewater was operated. Mixed granule and suspended sludge in the ammonium oxidizing process were taken and analyzed to investigate microbial community structure by molecular methods such as gene cloning and phylogenetic tree analysis after 250 days of continuous cultivation. The average nitrogen removal rate showed $0.9kg\;N/m^3-day$ after 250 days of continuous operation, then the maximum nitrogen removal rate showd $1.9kg\;N/m^3-day$ when $2.1kg\;N/m^3-day$ of nitrogen loading rate was applied. As results of gene cloning and phylogenetic tree analysis, Three kinds of phylum were found to be Proteobacteria, Acidobacteria and Planctomycetes (anammox bacteria) in mixed granule. Five kinds of phylum were found to be Proteobacteria, Chlorobi, Planctomycetes, Nitrospirae and Verrucomicrobia in suspended sludge. We found planctomycete KSU-1 and putative new anammox bacteria in the reactor. Microbial structure represented different consortia depending on the types of sludge in the anammox reactor.

• 한국물환경학회지
• /
• 제20권6호
• /
• pp.571-576
• /
• 2004

Since anaerobic/anoxic/oxic process, which is a typical mainstream biological nitrogen and phosphorus removal process, utilizes influent organic matter as an external carbon source for phosphorus release in anaerobic or anoxic stage, influent COD/T-P ratio gives a strong influence on performance of phosphorus removal process. In this study, a bench scale experiment was carried out for SBR process to investigate nitrogen and phosphorus removal at various influent COD/T-P ratio and nitrate loadings of 23~73 and 1.6~14.3g $NO_3{^-}-N/kg$ MLSS, respectively. The phosphorus release and excess uptake in anoxic condition were very active at influent COD/T-P ratios of 44 and 73. However, its release and uptake was not obviously observed at COD/T-P ratio of 23. Consequently, phosphorus removal efficiency was decreased. In addition, the phosphorus release and uptake rate in anoxic condition increased as the nitrate loading decreased. Specific denitrification rate had significantly high correlation with organic materials and nitrate loadings of the anoxic phase too. The rate of phosphorus release and uptake in the anoxic condition were $0.08{\sim}0.94kg\;S-P/kg\;MLSS{\cdot}d$ and $0.012{\sim}0.1kg\;S-P/kg\;MLSS{\cdot}d$, respectively.

• 한국물환경학회지
• /
• 제20권6호
• /
• pp.603-609
• /
• 2004

The objective of this study was to determine the optimal operation conditions in an anoxic oxic process to eliminate both organic and nitrogen matters in swine wastewater. For the purpose of this, the removal efficiency was evaluated with various HRTs and internal recycling ratio. During the whole 580 days of experiment, HRTs had been gradually decreased in an order of 20, 14, 12 and l0days, and the internal recycle ratio was kept at 20Q. So as to determine the effect of the internal recycle ratio on the nitrogen removal, the internal recycle ratio had been gradually increased from 20Q to 50Q while HRT was maintained at 12days. As a result, it was shown that the removal efficiency of organic matter was above 95% regardless of changing of HRTs. The average influent concentration of TCODcr and SCODcr were 24,854 mg/L and 18,920 mg/L, respectively. Average removal efficiency of TKN was shown to be nearly 98% when HRT was kept at 12days; however, the $NH_4{^+}-N$ concentration of effluent was shown to be increased when the loading rate of $NH_4{^+}-N$ was increased to $0.602 kgNH_4{^+}-N/m^3$-day by means of decreasing HRT to 10days. It was concluded that nitrogen loading rates should be more considered rather than organic loading rates in case of determining an optimal HRT. When gradually increasing the internal recycle ratio from 20Q to 50Q, the removal efficiency of organic matters and TKN were 96% and 98%, respectively so that no significant changes in removal efficiency was detected. However, when the internal recycle ratio was kept at 50Q, it was revealed that the $NO_3-N$ concentration of effluent seemed to drop and the average $NO_3-N$ concentration of effluent was around 52 mg/L.

• 상하수도학회지
• /
• 제32권1호
• /
• pp.19-25
• /
• 2018

The objectives of this study were to evaluate the removal characteristics of total nitrogen, the influence factor of denitrification and the optimum operating condition in the pigment wastewater treatment using PAC-A/O process. The operating conditions of PAC-A/O process were mean BOD volumetric loading $0.86kgBOD/m^3/day$, mean F/M ratio 0.072~0.13 kgBOD/kgMLVSS/day and mean C/N ratio 3.47, respectively. The conditions of anoxic process in the field plant test were mean pH 8.3~8.7 and mean temperature $34.1{\sim}44.0^{\circ}C$. The ORP bending point knee was eventually appeared in the ORP -107 mV and $NO_3{^-}-N$ removal efficiency was increased according to the ORP decrease. In the ORP -107 mV below condition, the removal efficiency of T-N and $NO_3{^-}-N$ was 92.3~95.0% and 98.5~99.7%. Denitrification rate was calculated to be 1.581~1.791 mg $NO_3{^-}-N/gMLSS/hr$. The experimental results showed that the ORP control in the PAC-A/O process could be an effective method for treatment of pigment wastewater.

• 한국물환경학회지
• /
• 제18권4호
• /
• pp.435-440
• /
• 2002

A pilot scale SBR (effective volume, $20m^3$) for the treatment of piggery wastewater treatment was performed with three different kinds of wastewater; fermenter effluent, scraper type and slurry type. The react phase in SBR was performed by sub-cycle operation consisting of repeated short cycle of anoxic-aerobic step. The fermenter effluent was characterized by the rapid nitrification and $NO_X-N$ accumulation due to depletion of organic matter in wastewater. The scraper type wastewater showed appropriate nitrogen removal efficiency, however, a poor response capacity for high loading rate often resulted in increased nitrogen concentration in effluent. Moreover, severe P release was the most serious problem in scraper type wastewater. SBR treated slurry type wastewater with high nitrogen removal efficiency to satisfy effluent quality requirement. It was thought that high concentration of organic matter in slurry made it possible to uptake P during SBR operation, where P concentration of 140mgP/l was decreased to 8mgP/l. As results, SBR was suitable to treat slurry type wastewater which has been discharged to the ocean till now.

• 상하수도학회지
• /
• 제14권2호
• /
• pp.147-156
• /
• 2000

In this study, the optimal operation parameters of MLE(Modified Ludzack-Ettinger) process treating the liquid supernatant separated from the slurry excreta of swine feedlot was studied as a promising biological treatment process. The nitrogen removal characteristics with different volume ratio between nitrification and denitrification reactor and the operational effect with different nitrogen loading rate, and different C/N($COD_{Cr}/TKN$) ratio were investigated. Based on the laboratory results, pilot MLE plant was operated to examine the effect of ambient temperature for five months including winter. The denitrification reactor which is 20% of total volume was proposed as the most optimal volume fraction for nitrification and denitrification. The optimum ratios of F/M and $F_N/M$ were increased with increase of the C/N ratio. However, optimum F/M ratio was changed more rapidly than $F_N/M$ ratio with increase of the C/N ratio. Therefore, MLE process is desirable to be controlled by F/M ratio in the range of high C/N ratio and by $F_N/M$ ratio in the range of low C/N ratio. Pilot MLE plant showed the higher removal efficiencies of COD and TKN in winter than in summer and was operated most stably at the temperature of $20{\sim}25^{\circ}C$ for mixed liqour.

• 한국수산과학회지
• /
• 제29권2호
• /
• pp.230-237
• /
• 1996

본 연구는 살수여상공법을 양어장 순환수 처리 장치로 설치하여 유기물질 제거 효율, 암모니아 제거효율, 동력학적 상수, 슬러지 생산량과 산소소요량 등의 최적 운전방법을 도출하였다. 유기물질 부하율이 $0.500\~0.082kg\;COD/m^3/day$에서 $66.4\~81.2\%$의 SCOD 제거 효율과 $74.5\~84.0\%$의 SBOD 제거 효율을 보였다. 암모니아 부하율이 $0.271\~0.044kg\;NH_4^+-N/M^3/day$에서 $43.7\~61.8\%$ 의 암모니아성 질소 제거 효율을 보였으며 암모니아 제거량은 $27.2\~119.5mg\;NH_4^+-N/L/day$로 나타났다. Eckenfelder 식에 의해 구한 K, n값은 각각 $0.168\;min^{-1}$과, 0.132로 나타났으며 총 생성된 슬러지 생산량은 0.233g VSS/day로 kg BOD 제거량당 생성되는 슬러지 생산량은 0.572 kg VSS/kg $BOD_{rem}$로 나타났다. 산소소요량은 3.89mg $O_2/L/hr$로 수리학적부하가 $6.712\~40.341\;m^3/m^2/day$에서 $1.33\~7.22\;mg\;O_2/L/hr$로 수리학적 부하가 증가할수록 산소소요량이 증가하였으며 미생물당 산소소모율은 1.08kg $O_2/kg$ VSS로 나타났다.

• 한국환경보건학회지
• /
• 제22권1호
• /
• pp.99-106
• /
• 1996

The purpose of this study is to observe a specific removal efficiency of synthethetic wastewater which is managed by upflow submerged type at porous media which was sinteringed on a comparative low temperature 600$\circ$C, was annexed slag and humus soil with main material kaolinite. Observing removal efficiency quality of each media, a mixed media of kaolinite and humus soil by gravity percent 60, 40% respectively showed the most excellent removal utility, and applied predictive models for suspended culture kinetics without consideration diffusion limitation, and when analyzed kinetic which had been processed by this study the removal efficiency accompanied by carbon, nitrogen, phosphorous volumetric loading rate variation standed for a comparative large change rate 61~71%, it means the selection of the most proper load factor had a great effect on the highly removal efficiency, yield coefficient(Y) and specific microbial attach equation showed 1.53 mgVSS/mgCOD, $m_p=10039.4\times ((S_0)/(6.75+S_0))$ repectively.

• 환경위생공학
• /
• 제12권2호
• /
• pp.75-81
• /
• 1997

The study was investigated with denitrification of wastewater containing nitrate using upflow anaerobic sludge blanket process. Contents of this study were the determination of nitrate removal efficiency by various hydrogen donor addition, relationship between HRT, nitrate loading rate and growth constant of microorganism in case or various hydrogen donor addition etc. Results from this study were summurized as follows. In case of adding methanol, ethanol, sodium acetate as hydrogen donor, treatability of wastewater contained 200mg/l as nitrate was about 91%. But in addition of ethanol, sodium acetate in wastewater contained 40mg/l as nitrate, nitrate removal efficiency was 80%. While the treatment of nitrate showed the yield coefficient of microorganisms(Y) as 234.8, 234.35, and 247.68 g/VSS/g nitrate, respectively, showed specific growth rate(K) as 0.885, 0.934 and 0.917 respectively.

• 한국대기환경학회지
• /
• 제25권6호
• /
• pp.503-511
• /
• 2009

VOC mixture was fed to a trickle bed air biofilter (TBAB) with step-change in influent mixture concentrations from 50 ppmv to 1,000 ppmv, corresponding to loadings of $5.7\;g/m^3/hr$ to $114.1\;g/m^3/hr$. VOC mixture was an equimolar ratio of two aromatic VOCs, i.e., toluene and styrene, and two oxygenated VOCs, i.e., methyl ethyl ketone (MEK) and methyl isobutyl ketone (MIBK). The TBAB system employed backwashing as biomass control. The experimental results showed that a critical loading rate for VOC mixture removal was determined to be about $60\;g/m^3/hr$, and critical loading rates for individual VOCs in the mixture were different. Specifically, toluene content in the mixture played a major role in the biofilter overall performance. As VOC mixture was fed beyond the critical loading rate, reacclimation of the biofilter to reach the 99% removal efficiency following backwashing was delayed, which was a critical factor in the biofilter performance. In the mass balance analysis, 63.8% of the carbon equivalent in VOCs removal was used for $CO_2$ production during the experimental runs. The 82.6% nitrogen utilized in the biofilter was contributed to microbial cell synthesis. The obtained results were compared against consistently high efficient performance of TBAB for VOC mixture by employing backwashing as biomass control.