• Ocean and Polar Research
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• v.25 no.3
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• pp.277-286
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• 2003

Nitrification performance of fixed film biofilters using coarse sand, loess bead, or styrofoam beads in biofilter columns 1 meter high and 30cm in diameter were studied at different hydraulic and organic matter loading rates. Synthetic wastewater was supplied to the culture tank in order to maintain desired TAN concentrations in inlet water to biofilters. All the biofilters were conditioned 5 months before start of sampling. TAN and $NO_2-N$ conversion rates increased with an increase in the hydraulic loading rate (HLR). However, the improvement in biofilter performance was not linearly correlated to HLR in styrofoam bead filters. This is mainly due to the characteristics of the styrofoam beads used. TAN conversion rates of sand filters increased with the increase of HLR up to $200m^3/m^2$. per day. No increase in the TAN conversion rate was observed at the highest HLR since flooding on the media surface took place. HLR had a significant impact on the TAN conversion rates in loess bead filter up to the highest HLR tested (P<0.05). TAN conversion rates were much less at organic matter loading rates of 9 and 18kg $O_2/m^3$ per day than those without the addition of organic matter in styrofoam bead filters. The addition of glucose resulted in a reduction of the TAN conversion rate from 540 to 284g $TAN/m^3$ per day. No significant difference of TAN conversion rates between the two organic matter loading rates was found (p<0.05). This indicates that the impact of organic matter on nitrification becomes less and less sensitive with an increase in the COD/TAN ratio. At an organic matter loading rate of 9kg $O_2/m^3$. per day, a great reduction of TAN conversion rates was observed in sand filters and loess bead filters. Clearly, organic matter can be one of the most Important Impacting factors on nitrification. $NO_2-N$ conversion rates showed a similar trend for TAN. Based on the TAN and nitrite conversion rates, styrofoam beads showed the best performance among the three filter media tested. Also, the low gravity and price of styrofoam beads make the handling easier and more cost-effective for commercial application. The results obtained at the highest organic matter loading rates can be used in the biofilter design in recirculating aquaculture system.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.7
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• pp.783-792
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• 2007

To investigate the effects of alkalinity on the nitrification capability of the nonwoven fabric filter bioreactor(NFBR), an experiment was performed for 641 days at a hydraulic retention time of approximately 11 hours by changing the influent concentration of $NH_3-N$ from 54 mg/L to 1,400 mg/L and alkalinity from 43 mg/L to 10,480 mg/L. The MLSS concentration reduced from an initial value of 2,650 mg/L down to 830 mg/L, then increased up to 8,340 mg/L. Though the volumetric loading rate varied in a range of $0.120\sim3.130$ kg $NH_3-N/m^3-day$, the F/M ratio showed a narrow range of $0.067\sim0.414$ kg $NH_3-N/kg$ MLSS-day. The average nitrification efficiency at each experimental stage resulted in the range of $35.2\sim100%$, and the maximum nitrification rate was 2.970 kg $N/m^3-day$ or 0.489 g N/g MLVSS-day. The nitrifiers' fraction of the MLVSS increased up to 100% from an initial value of 7.1% and the biofilm formed on the nonwoven fabric filter showed a very low nitrifiers' fraction of mere 2.2%. The growth yield of the MLSS and the alkalinity consumption rate were computed to be 0.117 g VSS/g N removed and 7.08 g alkalinity/g $NO_x^--N$ produced, respectively. Results of the research suggest that NFBR could be an adequate process for nitrification of wastewaters with high ammonia concentrations.

• Environmental Engineering Research
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• v.9 no.3
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• pp.130-142
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• 2004

• Journal of Korean Society of Environmental Engineers
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• v.32 no.5
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• pp.477-486
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• 2010

This study was performed with the object in which it improves the nitrification by using RBC, that is one of the biological waste water treatment process. By applying the Modified Dephanox process to RBC in this research in order to evaluate the improvement of the nitrification by RBC a research was conducted. There is the most conspicuous feature of the process of using RBC. it is that the nitrification can be smoothly performed even if the suspended solid of the high concentration as the interference factor in the nitrification tank is flowed in. Moreover, as a result of experiment, TCOD removal efficiency of the process showed up more than about 90%. when influent TCOD loading rate was 0.04~0.1 kg / $day{\cdot}m^3$. and T-N removal efficiency is high at about 75% in spite of the process operating of the laboratory scale was observed. Also, As increasing influent ${PO_4}^{3-}$-P, T-P loading rate, ${PO_4}^{3-}$-P, T-P removal efficiency was increased. Finally, it was elucidated that the utilization of RBC in external nitrification system resulted in not only high nitrification performance but also stable system operation by minimizing inhibitory effect of overflowed suspended solid (SS).

• Membrane Journal
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• v.28 no.1
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• pp.31-36
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• 2018

The purpose of this study is to investigate the changes of sludge characteristics according to the changes of influent sewage flowrate in the advanced wastewater treatment processes including MBR, SBR, and $A_2O$. The ratio of the actual sewage flowrate to the design flowrate is decreased from 100% to 70, 40%, and 10%, and the specific denitrification rate and ammonia oxidation (nitrification) rate was measured. The specific nitrification rate of the sludge collected from the aeration tank of each process was measured at a similar value ($0.10gNH_4/gMLVSS/day$) in all three process under the condition of 100% of sewage flowrate. It has tended to decrease significantly as the sewage flowrate decreased from 70% to 40%. The specific denitrification rate was also decreased by ~50% as the sewage flowrate decreased. However, considering the total nitrogen concentration in the influent and the microbial concentration in the reactor, the changes in kinetic parameter did not affect overall nitrogen removal. Therefore, it can be concluded that stable nitrogen removal will be possible under low influent flowrate condition if the MLVSS concentration is kept high.

• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.689-696
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• 2007

Kinetic analysis was important to develope the biological nutrient removal process effectively. In this research, anoxic-anaerobic-aerobic system was operated to investigate kinetic behavior on the nutrient removal reaction. Nitrification and denitrification were important microbiological reactions of nitrogen. The kinetics of organic removal and nitrification reaction have been investigated based on a Monod-type expression involving two growth limiting substrates : TKN for nitrification and COD for organic removal reaction. The kinetic constans and yield coefficients were evaluated for both these reactions. Experiments were conducted to determine the biological kinetic coefficients and the removal efficiencies of COD and TKN at five different MLSS concentrations of 5000, 4200, 3300, 2600, and 1900 mg/L for synthetic wastewater. Mathematical equations were presented to permit complete evaluation of the this system. Kinetic behaviors for the organic removal and nitrification reaction were examined by the determined kinetic coefficient and the assumed operation condition and the predicted model formulae using kinetic approach. The conclusions derived from this experimental research were as follows : 1. Biological kinetic coefficients were Y=0.563, $k_d=0.054(day^{-1})$, $K_S=49.16(mg/L)$, $k=2.045(day^{-1})$ for the removal of COD and $Y_N=0.024$, $k_{dN}=0.0063(day^{-1})$, $K_{SN}=3.21(mg/L)$, $k_N=31.4(day^{-1})$ for the removal of TKN respectively. 2. The predicted kinetic model formulae could determine the predicted concentration of the activated sludge and nitrifier, investigate the distribution rate of input carbon and nitrogen in relation to the solid retention time (SRT).

• Journal of environmental and Sanitary engineering
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• v.11 no.2
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• pp.43-52
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• 1996

Using rotating biological contactor(RBC) with artificial endogenous stage and aerobic fixed biofilm reactor(AFBR), organic material removal and biological nitrification of piggery wastewater has been studied at a pilot plant. RBC was operated in the endogenous phase at a interval of every 25 days. The concentration of COD, BOD and TKN in influent wastewater were from 2,940 to 3,800 mg/L, from 1,190 to 1,850 mg/L and from 486 to 754 mg/L respectively. The maximum active biomass content represented as VSS per unit aera was $2.0mg/cm$^{2}$ and biofilm dry density of $17mg/cm^{3}$ was observed at biofilm thickness of $900{\;}{\mu}m$. It was observed that the pilot scale RBC/AFBR process exhibited 72 percentage to 93 percentage of BOD removal, In order to obtain more than 90 percentage of BOD removal, the organic loading rate to the RBC/AFBR process should be maintained less than $0.09{\;}m^{3}/m^{2}{\cdot}day(125.9g{;\}BOD/m^{3}{\cdot}d$. The TKN removal efficiencies was from 45.5 to 90.9 percentage according to vary influent loading rate, It was estimated that the RBC/AFBR process consumed approximately 6.2 mg/L(as $CaCO_{3}$) of alkalinity per 1 mg/L of $NH_{3}$-N oxidized as the nitrification took piace.

• Journal of Microbiology and Biotechnology
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• v.12 no.3
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• pp.377-381
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• 2002

Recently, interests to remove nitrogen in the nitritation process have increased because of its economical advantages, since it could be a short-cut process to save both oxygen for nitrification and carbon for denitrification compared to a typical nitrification. However, the kinetics related with the nitritation process has not yet been fully understood. Furthermore, many useful models which have been successfully used for wastewater treatment processes cannot be used to estimate effluent nitrite concentration for evaluating performance of the nitritation process, since the process rate equations and population of microorganisms for nitrogen removal in these models have been set up only for the condition of full nitrification. Therefore, the present study was conducted to estimate an effluent nitrite concentration in the nitritation process with a concept of enzymatic inhibition kinetics based on long-term laboratory experiments. Using a nonlinear least squares regression method, kinetic parameters were accurately determined. By setting up a process rate equation along with a mass balance equation of the nitrite-oxidizing step, an effluent nitrite concentration in the nitritation process was then successfully estimated.

• Environmental Engineering Research
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• v.19 no.1
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• pp.23-29
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• 2014

In this study, aerobic granules were applied to a lab-scale aerobic granule sludge airlift reactor (AGSAR) and the ammonium nitrogen oxidation performance was evaluated at different ammonium nitrogen loading rate (NLR). At least 99% of the initial ammonium nitrogen was oxidized at an NLR of 0.27 and 0.53 kg $NH_4{^+}-N/m^3{\cdot}day$, for both aerobic granules (control), and nitrifying aerobic granules (NAGs). The ammonium nitrogen oxidation deteriorated, when the NLR was increased to 1.07 kg $NH_4{^+}-N/m^3{\cdot}day$. The NAGs were characterized by complete nitrification, while partial nitrification was observed in the control.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.5
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• pp.521-529
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• 2007

Nutrient removal from synthetic wastewater was investigated using a MLE (Modified-Ludzack Ettinger) type MBBR (Moving Bed Biofilm Reactor), with different phenol ($C_6H_5OH$) concentrations, in order to determine the inhibition effects of phenol on biological nutrient removal and the biodegradation of phenolic wastewater. The wastewater was prepared by mixing a solution of molasses with known amounts of phenol and nutrients. The experiments were conducted in a lab-scale MLE type MBBR, operated with four different phenol concentrations (0, 67, 100 and 168mg/L) in the synthetic feed. Throughout the experiments, the ratio of the phenolic COD concentration to the total COD was varied from 0 to 1. Throughout batch test, the SNR (Specific Nitrification Rate) and SDNR (Specific Denitrification Rate) were significantly influenced by changes of the phenol concentration. Phenol was inhibitory to the nitrification/denitrification process, and showed greater inhibition with higher initial phenol concentrations. The SNR observed with 0, 67, 100 and 168mg phenol/L were very different like 10.12, 6.95, 1.51 and $0.35mg\;NH_{3^-}N/gMLVSS$ hr, respectively. Similarly, the SDNR observed at 0, 67, 100 and 168mg phenol/L were different like 0.322, 0.143, 0.049and 0.006mgN/gMLVSS day, respectively.