• Journal of Environmental Science International
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• v.8 no.5
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• pp.617-623
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• 1999

This study was carried out to obtain the optimal operating parameter on organic matters and nutrient removal of mixed wastewater which was composed of sewage and stable wastewater using SBR. A laboratory scale SBR was operated with An/Ae(Anaerobic/Aerobic) ratio of 3/3, 2/4 and 4/2(3.5/2.5) at organic loading rate of 0.14 to 0.27 kgBOD/$m^3$/d. TCOD/SCOD ratio of mixed wastewater was 3, so the important operating factor depended upon the resolving the particulate parts of wastewater. Conclusions of this study were as follows: 1) For mixed wastewater, BOD and COD removal efficiencies were 93-96% and 85-89%, respectively. It was not related to each organic loading rate, whereas depended on An/Ae ratio. During Anarobic period, the amount of SCOD consumption was very little, because ICOD in influent was converted to SCOD by hydrolysis of insoluble matter. 2) T-N removal efficiencies of mixed wastewater were 55-62% for Exp. 1, 66-76% for Exp. 2, and 67-81% for Exp. 3, respectively. It was found that nitrification rate was increased according to organic concentration in influent increased. Therefore, the nitrification rate seemed to be achieved by heterotrophs. During anoxic period, denitrification rate depended on SCOD concentration in aerobic period and thus, was not resulted by endogenous denitrification. However, the amount of denitrification during anaerobic period were 3.5-14.1 mg/cycle, and that of BOD consumed were 10-40 mg/cycle. 3) For P removal of mixed wastewater, EBPR appeared only Mode 3($3^＊$). It was found that the time in which ICOD was converted to VFA should be sufficient. For mode 3 in each Exp., P removal efficiencies were 74, 87, and 81%, respectively. But for 45-48 of COD/TP ratio in influent, P concentration in effluent was over 1 mg/L. It was caused to a large amount of ICOD in influent. However, as P concnetration in influent was increased, the amounts of P release and uptake were increased linearly.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.7
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• pp.479-484
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• 2013

This study was performed to examine the effect of copper on the biodegradability, nitrification, denitrification and oxygen uptake rate (OUR) using batch reactor and continuous flow stirred tank reactor (CSTR) of anaerobic/anoxic/oxic ($A_2/O$). The results of this study can be summarized as follows. In the case of the effect of copper on organic treatment, the bad effect initiated when it was above 4.5 mg/L copper with batch reactor and above 2.0 mg/L copper with CSTR. Concerning the case on nitrification and removal of nitrogen, it showed bad effect when copper was above 4.5 mg/L with batch reactor for nitrification and 1.0 mg/L with CSTR for the removal of nitrogen. The bad effect on the removal of phosphorus began when it was 4.5 mg/L copper with batch reactor and 2 mg/L copper with CSTR. In the case of OUR, it decreased as microbial activity was affected when copper concentration was above 1.5 mg/L in both case of batch reactor and CSTR.

• Environmental Engineering Research
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• v.25 no.2
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• pp.251-257
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• 2020

This study was performed to verify the possibility of nitrification and denitrification in a single reactor. In batch type experiment, optimal point of experimental conditions could be found by performing the experiments. When supply location of microbubbles was located at half of width of the aeration tank and operating pressure of 0.5 bar, it was possible for zones in the aeration tank to be separated into anoxic and aerobic by controlling air suction rate according to operating pressure of the generator. To be specific, the concentration of dissolved oxygen (DO) in zone 1 and 2 of the aeration tank could be maintained as less than 0.5 mg/L. Also, in the case of concentration of oxygen in zone 3 and 4, the concentration of DO was increased up to 1.7 mg/L due to effects of microbubbles. In continuous flow type experiment based on the results of batch type experiments, the removal efficiency of nitrogen based on T-N was observed as 39.83% at operating pressure of 0.5 bar and 46.51% at operating pressure of 1 bar so it was able to know that sufficient air suction rate should be required for nitrification. Also, denitrification process could be achieved in a single reactor by using ejector type microbubble generator and organic matter and suspended solid could be removed. Therefore, it was possible to verify that zones could be separated into anoxic and aerobic and nitrification and denitrification process could be performed in a single reactor.

• Korean Journal of Soil Science and Fertilizer
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• v.31 no.3
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• pp.233-237
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• 1998

Mineralization of organic N is an important factor in determining the appropriate rate for organic waste application to cropland. The mineralization of organic N was examined using sandy soil amended with three kind of compost (municipal solid waste+biosolid, yard trimmings, yard trimmings+biosolid), respectively. During the 12-week incubation, the mineralization of organic N was determined by analyzing the inorganic N in leachates from unamended and amended soils. Soils amended with com posts made of biosolid had higher initial $NH_4-N$ concentration than unamended soil. Soil amended with compost made of yard trimmings only had slightly lower initial inorganic N concentration than unamended soil. In the soil amended with com post made of yard trimmings+biosolid, however, nitrification rate was enhanced in the first week of incubation. Net N mineralization and nitrification were positive in all treatments. Although the greatest net N mineralization occurred in the soil amended with compost made of yard trimmings+biosolid, the greatest net mineralization and nitrification rates occurred in unamended soil.

• Journal of Korean Society on Water Environment
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• v.23 no.1
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• pp.19-26
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• 2007

The lab-scale BNR processes fed with Municipal Wastewater Before or After Primary Clarifier (MWBPC or MWAPC) were operated to observe the behavior of particle organic matter in terms of nitrification and denitrification efficiency. As a result of the fractionation of the COD from MWBPC or MWAPC using an aerobic respirometric serum bottle reactor, the total mass of biodegradable organic matter from MWBPC is about 52% greater than the mass from MWAPC. Batch reactors were operated to observe the effect of the Particulate Organic Matter (POM) on substrate utilization for denitrification. Although the consumption of POM for denitrification was observed, the increment of the Specific Denitrification Rate (SDNR) was not great. In terms of the effect of POM on nitrification at different HRTs, activate sludge reactors were operated to determine the optimal HRT when MWBPC and MWAPC were fed relatively. All reactors showed a great organic matter removal efficiency. Reactors fed with MWAPC had obtained the nitrification efficiency above 90% when the HRT of 4 hr, at least, was maintained, while reactors fed with MWBPC had same efficiency when the HRT longer than 5 hr was kept. Three parallel $A^2/O$ systems fed with MWBPC or MWAPC relatively were operated to investigate the effects of POM on BNR processes with varying the HRT of an anoxic reactor. For all systems, the efficiency of organic matter removal and denitrification, respectively, was great and about the same. In case of denitrification efficiency, system with MWAPC had 1.5% lower than system with MWBPC at the same HRT of anoxic reactor of 2 hr, and the increasing the HRT of the anoxic reactor by 1 hr in systems fed with MWBPC resulted in a 3.5% increment. The denitrification rate was similar while the consumption of organic matter in systems fed with MWBPC was higher than system fed with MWBPC. It suggests that POM in MWBPC was not be used significantly as a substrate for denitrification in system with the HRT of 3 hr of an anoxic reactor.

• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.761-765
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• 2007

The study were conducted in order to investigate the effect of operating parameters including the internal recycle (nitrification return) rates, hydraulic retention times (HRTs) and temperature when using a cilium media method. The first experiment was for evaluating the effect of HRT (12 hr, 10 hr, 8 hr, 6 hr, 4 hr). The second experiment was for analyzing effect of internal recycle rate (100%, 200%, 300%, 400%). As a result of the first experiment, BOD was removed to 97~98% for 6~8 hr HRT. Effluent water quality was not significantly influenced with HRT within that range. However the nitrogen removal was sensitive to HRT. T-P removal efficiency was invariable at various HRTs. The average BOD removal efficiency was about 97% in spite of change of internal recycle rate while T-N removal efficiency was increased at the internal recycle rate of 100~200%, but invariable at the internal recycle rate of 200~300%.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.1
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• pp.7-14
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• 2006

In this study, nitrogen removal characteristics of SBR3 process, which is two-sludge system of sequencing batch reactor(SBR) type, were investigated, with comparison of those of SBR1 process, which is conventional SBR process, and SBR2 process, which was designed to enhance denitrification efficiency through step-feeding of wastewater, using domestic wastewater. SBR3 process of two-sludge type can perform external nitrification, on which nitrification occurs in separated reactor, and enhanced denitrification using biosorbed organics. In the results with domestic wastewater, T-N removal efficiency of SBR3 process was better than those of SBR1 and SBR2 processes. It was observed that bigger difference of T-N removal efficiency between SBR3 process and SBR1 & SBR2 processes was showed at low C/N ratio than that at high C/N ratio resulting from more efficient use of organics by biosorption mechanism in denitrification of SBR3 process than those of SBR1 and SBR2 processes. In addition, T-N removal efficiency of SBR3 process according to influent T-N loading rate was better than those of SBR1 and SBR2, even though influent T-N loading rate of SBR3 process was higher than that of SBR1 and SBR2 process resulting from operation of SBR3 process in short hydraulic retention time(HRT) by external nitrification.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.53-60
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• 2000

The effects of ammonia loading on nitrification, especially on nitrite build-up, in an activated carbon fluidized bed reactor were investigated by increasing the ammonia loading rate stepwise from 0.1 to $7.5kg\;NH_3-N/m^3{\cdot}day$. Although effluent nitrite concentration and nitrification efficiency fluctuated at the loading rates above $1.8kg\;NH_3-N/m^3{\cdot}day$, an average nitrification efficiency of 90% was achieved. Nitrite build-up began at an ammonia loading rate of $l.8kg\;NH_3-N/m^3{\cdot}day$, at which the free ammonia concentration was estimated to be above 1 mg/L. During the nitrite build-up, the ratio of influent $NH_3-N$ concentration to the DO concentration of the reactor liquor and the ratio of effluent $NH_3-N$ concentration to the DO concentration of the reactor liquor was measured to be above 100 and 2, respectively. Considering the advantages of nitritation/denitrification, a fluidized bed reactor could be an effective means for biological nitrification of wastewaters with high ammonia concentration.

• Environmental Engineering Research
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• v.24 no.2
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• pp.254-262
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• 2019

The impact of free cyanide ($CN^-$) and thiocyanate ($SCN^-$) on the $CN^-$ (CDO) and $SCN^-$ degraders (TDO) to nitrify and denitrify aerobically was evaluated under alkaline conditions. The CDO's were able to nitrify under cyanogenic conditions, achieving $NH_4{^+}-N$ removal rates above 1.66 mg $NH_4{^+}-N.L^{-1}.h^{-1}$, except when $CN^-$ and $SCN^-$ loading was 15 mg $CN^-/L$ and 50 mg $SCN^-.L^{-1}$, respectively, which slightly inhibited nitrification. The TDO's were able to achieve a nitrification rate of 1.59 mg $NH_4{^+}-N.L^{-1}.h^{-1}$ in the absence of both $CN^-$ and $SCN^-$, while the presence of $CN^-$ and $SCN^-$ was inhibitory, with a nitrification rates of 1.14 mg $NH_4{^+}-N.L^{-1}.h^{-1}$. The CDO's and TDO's were able to denitrify aerobically, with the CDO's obtaining $NO_3{^-}-N$ removal rates above 0.67 mg $NO_3{^-}-N.L^{-1}.h^{-1}$, irrespective of the tested $CN^-$ and $SCN^-$ concentration range. Denitrification by the TDO's was inhibited by $CN^-$, achieving a removal rate of 0.46 mg $NO_3{^-}-N.L^{-1}.h^{-1}$ and 0.22 mg $NO_3{^-}-N.L^{-1}.h^{-1}$ when $CN^-$ concentration was 10 and 15 mg $CN^-.L^{-1}$, respectively. However, when the CDO's and TDO's were co-cultured, the nitrification and aerobic denitrification removal rates were 1.78 mg $NH_4{^+}-N.L^{-1}.h^{-1}$ and 0.63 mg $NO_3{^-}-N.L^{-1}.h^{-1}$ irrespective of $CN^-$ and $SCN^-$ concentrations.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.4
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• pp.429-437
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• 2007

This study aims to develop a sulfur-using denitrification process which is possible a renovation to advanced treatment plant submerging a simple module in activated sludge aeration tank. At first, the impact factor of sulfur-using denitrification was appreciated by the batch test. Secondly, reflecting a dissolved oxygen effect of sulfur-using denitrification that was confirmed by the batch test, in a continuous nitrification/sulfur-using denitrification, high-rate nitrogen removal reaction was induced at optimum condition controlling DO concentration according to phases. Also, inside and outside of sulfur-using denitrification module was covered with microfilter and the module was considered as an alternative of clarifier. Result of batch test for sulfur-using denitrification, $NO_2{^-}N$ was lower for consumption of alkalinity and sulfur than that of $NO_3{^-}-N$. These results revealed the accordance of theoretical prediction. In continuous nitrification/sulfur-using denitrification experiment, actual wastewater was used as a influent, and influent nitrogen loading rates were increased 0.04, 0.07, 0.11, $0.14kg\;N/m^3-day$ by changing hydraulic retention times. At this time, nitrogen loading rates of packed sulfur were increased 0.23, 0.46, 0.69, $0.93kg\;N/m^3-day$. As a result, nitrification efficiency was about 100% and denitrification efficiency was 93, 81, 79, 72%. Accordingly, nitrogen removal was a high-rate. Also the module of sulfur-using denitrification covered with microfilter did not make a fouling phenomena according to increased flux. And the module was achieved effluent suspended solids of below 10 mg/L without a clarifier. In conclusion, it is possible a renovation to advanced treatment plant submerging a simple module packed sulfur in activated sludge aeration tank of traditional facilities. And the plant used the module packed sulfur is expected as a effective facilities of high-rate and the smallest.