• 대한화학회지
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• 제40권6호
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• pp.457-461
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• 1996

• Bulletin of the Korean Chemical Society
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• 제33권10호
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• pp.3373-3377
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• 2012

A series of polystyrene-supported 1-(propyl-3-sulfonate)-3-methyl-imidazolium hydrosulfate acidic ionic liquid (PS-$[SO_3H-PMIM][HSO_4]$) catalysts were prepared and tested for mononitration of simple aromatics compounds with nitric acid. It was found that the reactivity of the catalysts increased with increasing $[SO_3H-PMIM][HSO_4]$ content. The para-selectivity was not only related to the $[SO_3H-PMIM][HSO_4]$ content but also the substituent groups in aromatics. A reaction mechanism of nitration over this new catalyst was proposed. The catalytic activity of this catalyst decreased slightly after fifth runs in the synthesis of nitrotoluene.

• 한국해양공학회지
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• 제23권3호
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• pp.30-34
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• 2009

Oil hydraulic piston pumps are being extensively used in the world, because of simple design, light weight and effective cost etc. An oil hydraulic pump is likely to have serious problems of high leakage, friction and low energy efficiency according to large time use. In the oil hydraulic piston pumps the clearance between the valve block and piston plays an important role for volumetric and overall efficiency. In this paper, the wear property of the SACM645 material used the hydraulic piston pump has been work out by experimentation with variable heat treatment. To investigate the effect according to the piston surface condition, seven different types specimen were prepared. From the wear test results, induction hardening and nitration were definitely superior to the others. On the whole, nitration was estimated for high strength material to wear resistance.

• 한국소음진동공학회논문집
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• 제12권4호
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• pp.294-301
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• 2002

Vibration control of a plate using an optical fiber sensor and a piezoelectric actuator is considered in the present study, An aluminum plate with attached Extrinsic Fabry-Perot Interferometer (EFPI) and piezoelectric actuator is prepared for experimental investigation. Vibration level of EFPI that can represent the mechanical strain without severe distortion Is validated by forced nitration experiment. A linear time invariant system model is constructed based on the experimentally obtained frequency responses, and an optimal controller is designed for the multi-modal vibration suppression. Control performance is presented in frequency and time domains. It is found that the nitration level of the first three modes can be greatly reduced. The effect of low-pass filtering used to eliminate high frequency noise on the stability and control performance is also considered.

• 소음진동
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• 제11권2호
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• pp.336-345
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• 2001

This research presents a nonlinear model to analyze the ball bearing nitration due to the waviness in a rigid rotor supported by multi-row ball bearings. The waviness of a ball and each races is modeled by the superposition of sinusoidal function, and the position vectors of inner and outer groove radius center are defined with respect to the mass center of the rotor in order to consider five degrees of freedom of a general rotor-bearing system. The waviness of a ball bearing is introduced to these position vectors to use the Hertzian contact theory in order to calculate the elastic deflection and nonlinear contact force resulting from the waviness while the rotor has translational and angular motion. They can be determined by solving the nonlinear equations of motion with five degrees of freedom by using the Runge-Kutta-Fehlberg algorithm. Numerical results of this research are validated with those of prior researchers. The proposed model can calculate the translational displacement as well as the angular displacement of the rotor supported by the multi-row ball bearings with waviness. It also characterizes the nitration frequencies resulting from the various kinds of waviness in rolling elements, the harmonic frequencies resulting from the nonlinear load-deflection characteristics of ball bearing. and the sideband frequencies resulting from the waviness interaction.

• BMB Reports
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• 제38권5호
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• pp.577-583
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• 2005

Subtilisin QK, which is newly identified as a fibrinolytic enzyme from Bacillus subtilis QK02, has the ability of preventing nitrotyrosine formation in bovine serum albumin induced by nitrite, hydrogen peroxide and hemoglobin in vitro verified by ELISA, Western-blot and spectrophotometer assay. Subtilisin QK also attenuates the fluorescence emission spectra of bovine serum albumin in the course of oxidation caused by nitrite, hydrogen peroxide and hemoglobin. Furthermore, subtilisin QK could suppress the transformation of oxy-hemoglobin to met-hemoglobin caused by sodium nitrite, but not the heat-treated subtilisn QK. Compared with some other fibrinolytic enzymes and inactivated subtilisin QK treated by phenylmethylsulfonylfluoride, the ability of inhibiting met-hemoglobin formation of subtilisin QK reveals that the anti-oxidative ability of subtilisin QK is not concerned with its fibrinolytic function. Additionally, nitrotyrosine formation in proteins from brain, heart, liver, kidney, and muscle of mice that is intramuscular injected the mixture of nitrite, hydrogen peroxide and hemoglobin is attenuated by subtilisin QK. Subtilisin QK can also protect Human umbilical vein endothelial cell (ECV-304) from the damage caused by nitrite and hydrogen peroxide.

• 한국소음진동공학회논문집
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• 제12권12호
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• pp.921-928
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• 2002

Main sources of the nitration of a gear-pair system are backlash and transmission error, the difference between required and actual rotation during gear meshing. This paper presents the nonlinear dynamic characteristics of gear motions due to the existence of backlash and periodic variation of meshing stiffness, which is assumed as a one-term harmonic component. Gear motions are classified as three types with the consideration of backlash. Each response is calculated using the harmonic balance method and confirmed by numerical integration. The responses with the increase of the rotating speed show abrupt changes in its magnitude for the variation of the preload, exciting force, and damping coefficient. The result also shows that there is a chaotic motion with some specific design parameters and operating conditions In gear diving system. Consequently the design of gear driving system with low nitration and noise requires the study on the effects of nonlinear dynamic characteristics due to stiffness variation and backlash.

• 분석과학
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• 제12권1호
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• pp.34-39
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• 1999

에스트로겐의 일종인 에스트론은 수은 전극에서 전기 화학적 행동을 보이지 않기 때문에 폴라로그래피로 직접 정량하기는 어렵다. 에스트로겐의 nitro 유도체들은 전기화학적 활성을 갖기 때문에 본 물질을 nitration시켜 전압-전류법으로 정량하였다. Nitration 반응은 sodium nitrite를 사용하여, $100^{\circ}C$ 항온조에서 30분동안 가열하였다. 순환 전압-전류법으로 에스트론의 전기 화학적 행동을 조사하였고, 시차 펄스 음극 벗김 전압-전류법으로는 미량의 에스트론을 정량하는 방법을 연구하였다. 그 결과 borate buffer 용액내에서 nitrated estrone의 환원 전위는 -0.61 V에서 선명한 봉우리를 나타내었다. Nitrated estrone은 수은 전극에서 비가역과정이고, 수은 방울에 강하게 흡착되었다. 에스트론을 정량하기 위한 최적조건은 0.05 M sodium nitrite, 0.01 M sodium borate, 흡착 수집 전위는 -0.1 V(vs. Ag/AgCl) 및 pH 11.0 이었다. 흡착 수집 시간은 2분 그리고 주사 속도는 10 mV/sec일 때 에스트론의 검출한계는 $1{\times}10^{-9}M$이었다.

• 한국군사과학기술학회지
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• 제5권4호
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• pp.49-56
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• 2002

For the purpose of the increase in the performance and thermal stability of PBX's, the mixed formal consisting of BDNPF, DNPBF and BDNBF were synthesized. In order to find out the optimal condition for the synthesis of energetic plasticizer, BDNPF, DNPBF and BDNBF, the synthetic procedures have been investigated. We synthesized DNP-OH and DNB-OH through oxidative nitration and controlled various composition of mixed formal by $H_{2}SO_{4}$ and s-trioxane to investigate optimal composition, and then characterized its thermo-physical properties.

• 한국동물학회:학술대회논문집
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• 한국동물학회 2001년도 한국생물과학협회 학술발표대회
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• pp.265.2-265
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• 2001

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