• 한국표면공학회지
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• 제56권5호
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• pp.320-327
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• 2023

In this study, the nickel hydroxide (Ni(OH)₂) electrode for supercapacitor was prepared via hydrothermal method. Based on the nickel (Ni) foam, the electrode does not require any additional binder material or post-processing. Nickel nitrate (Ni(NO₃)₂) and hexamethylenetetramine (C₆H₁₂N₄) were used for synthesis, and the synthesis condition was 12 hours at 80 ℃. X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) were used to analyze the structural characteristics of the electrode, and it shown that the nickel hydroxide was successfully prepared after only the one-step hydrothermal synthesis. The electrochemical properties were analyzed through the half-cell test. The prepared electrode shown a pair of oxidation/reduction peaks, indicating that the driving method included the redox reaction on the electrode surface. After the charge/discharge test, the specific capacitance was calculated as the value of 438 F/g at 3 A/g.

• 한국표면공학회지
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• 제32권3호
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• pp.360-362
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• 1999

Formation of the nickel-cadmium alloy in the negative electrode of nickel-cadmium cell subjected to continuous charging at elevated temperatures ($40~45^{\circ}C$) is shown to be one of the causes of the 'stepped' discharge curves. The alloy has been characterized by electrode potential measurement and X-ray diffraction method. The potential lowering during discharge is related to discharge of the alloy. X -ray diffraction suggests that the nickel-cadmium alloy can be formed during charge in negative electrode by interaction of the two metals. Addition of Ni $(OH)_2$ into $Cd{\;}(OH)_2$ active material is found to form the alloy more readily than sintered negative electrode alone.ode alone.

• Journal of Electrochemical Science and Technology
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• 제1권2호
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• pp.117-120
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• 2010

Materials used as fuel cell electrode should be light, high conductive, high surface area for reaction, catalytic surface and uniformity of porous structure. Nickel is widely used in electrode materials because it itself has catalytic properties. When used as electrode materials, nickel of only a few im on the surface may be sufficient to conduct the catalytic role. To manufacture the nickel with porous structure, Electroless nickel plating on carbon fiber be conducted. Because electroless nickel plating is possible to do uniform coating on the surface of substrate with complex shape. Acidic bath and alkaline bathe were used in electroless nickel plating bath, and pH and temperature of bath were controlled. The rate of electroless plating in alkaline bath was faster than that in acidic bath. As increasing pH and temperature, the rate of electrolee plating was increased. The content of phosphorous in nickel deposit was higher in acidic bath than that in alkaline bath. As a result, the uniform nickel deposit on porous carbon fiber was conducted.

• 전기화학회지
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• 제3권2호
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• pp.76-80
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• 2000

Electrochemical oxidation of ethanol has been studied at nickel and $RuO_2-modified$ nickel electrodes in 1 M KOH using electrochemical impedance spectroscopy. Equivalent circuits have been worked out from simulation of impedance data to model oxidation of ethanol as well as the passivation of the electrode. The charge-transfer resistances for oxidation of these electrodes became smaller in the presence of ethanol than in its absence. The nickel substrate facilitated ethanol oxidation at $RuO_2-modified$ nickel electrodes. We also describe the Performance of nanosized electrocatalysts of the same composition in comparison to those of the bulk electrodes. The nanosized electrodes were obtained by electrode-positing the alloy from complexed form of these metal ions with fourth and fifth generation polyamidoamine dendrimers.

• 한국표면공학회지
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• 제15권3호
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• pp.146-151
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• 1982

The electrochemical reaction behavior of nickel electrode of the nickel-cadium battery system in potassium hydroxide solution has been studied by cyclic voltammetry, controlled potential electrolysis and X-ray diffraction method. It has been found that the reaction mechanism of positive nickel electrode for charging was assumed to be proten transfer step with a rate controlling diffusion process and char-ging state of positive electrode was amorphous $\beta$-NiOOH.

• 한국표면공학회지
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• 제32권3호
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• pp.363-365
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• 1999

The improved method comprises electrochemically deposition of nickel hydroxide into the sintered nickel plaque cathode from nickel aqueous electrolyte at acid pH in a treating zone containing an anode. The electrochemical impregnation was examined under various conditions. Deposition condition of fine active material was obtained from the impregnation of a high temperature and also high current density. This method also could be decreased swelling and buckling of the plaque. A nickel electrode prepared by electrochemical impregnation is useful as the positive in nickel-cadmium cells. The utilization of the active material indicated almost 100% based on a one electron charge.

• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.612-617
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• 2021

In the case of a metal sulfide electrode, it is used as an anode or cathode active material in a lithium battery. The reason is that the voltage exists between 0.8 and 2.0 V via lithium electrode and the discharge and charge capacity is high. In order to manufacture nickel sulfide for electrode, which are widely used, nano-nickel powder was sulfided using ammonium polysulfide, and single-phase NiS electrodes were manufactured through heat treatment. The prepared NiS electrode had a high initial capacity of 500 mAh/g or more, and was stabilized after 20 cycles to maintain a capacity of 400 mAh/g or more until 100 cycles.

• 한국재료학회지
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• 제20권11호
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• pp.592-599
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• 2010

A porous nickel-tin nano-dendritic electrode, for use as the anode in a rechargeable lithium battery, has been prepared by using an electrochemical deposition process. The adjustment of the complexing agent content in the deposition bath enabled the nickel-tin alloys to have specific stoichiometries while the amount of acid, as a dynamic template for micro-porous structure, was limited to a certain amount to prevent its undesirable side reaction with the complexing agent. The ratios of nickel to tin in the electro-deposits were nearly identical to the ratios of nickel ion to tin ion in the deposition bath; the particle changed from spherical to dendritic shape according to the tin content in the deposits. The nickel to tin ratio and the dendritic structure were quite uniform throughout the thickness of the deposits. The resulting nickel-tin alloy was reversibly lithiated and delithiated as an anode in rechargeable lithium battery. Furthermore, the resulting anode showed much more stable cycling performance up to 50 cycles, as compared to that resulting from dense electro-deposit with the same atomic composition and from tin electrodeposit with a similar porous structure. From the results, it is expected that highly-porous nickel-tin alloys presented in this work could provide a promising option for the high performance anode materials for rechargeable lithium batteries.

• 한국세라믹학회지
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• 제45권6호
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• pp.368-373
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• 2008

An electrode for supercapacitor using 3-dimensional porous nickel foam as a current collector and cobalt oxide as an active material was prepared and characterized in terms of morphology observation, crystalline property analysis, and the investigation of electrochemical property. The electrode surface showed that the cobalt oxide was homogeneously coated as the crystalline phase of $Co_3O_4$. Cyclic voltammetry for the $Co_3O_4$/nickel foam electrode exhibited higher specific capacitance values (445 F/g at 10 mV/s and 350 F/g at 200 mV/s) and excellent capacitance retention ratio (99% after $10^4$ cycles). It was proved that the nickel foam substrate played the roles in reducing the interfacial resistance with cobalt oxide and in improving the electrode density by embedding greater amount of cobalt oxide within it.

• Bulletin of the Korean Chemical Society
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• 제33권12호
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• pp.3993-3997
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• 2012

Three-dimensional porous nickel foam was used as a current collector to prepare a Co-Ni oxide/Ni foam electrode for a supercapacitor. The synthesized Co-Ni oxide was proven to consist of mixed oxide phases of $Co_3O_4$ and NiO. The Co-Ni oxide/Ni foam electrode prepared was characterized by morphological observation, crystalline property analysis, cyclic voltammetry, and impedance spectroscopy. Cyclic voltammetry for the electrode showed high specific capacitances, such as 936 F $g^{-1}$ at 5 mV $s^{-1}$ and 566 F $g^{-1}$ at 200 mV $s^{-1}$, and a comparatively good cycle performance. These improved results were mainly due to the dimensional stability of the nickel foam and its high electrical contact between the electrode material and the current collector substrate.