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http://dx.doi.org/10.7316/KHNES.2021.32.6.612

Electrochemical Properties of Lithium Batteries with Nickel Sulfide by Ammonium Polysulfide  

RYU, HO SUK (Deptmemt Advanced Aerospace Materials Engineering, Kyungwoon University)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.32, no.6, 2021 , pp. 612-617 More about this Journal
Abstract
In the case of a metal sulfide electrode, it is used as an anode or cathode active material in a lithium battery. The reason is that the voltage exists between 0.8 and 2.0 V via lithium electrode and the discharge and charge capacity is high. In order to manufacture nickel sulfide for electrode, which are widely used, nano-nickel powder was sulfided using ammonium polysulfide, and single-phase NiS electrodes were manufactured through heat treatment. The prepared NiS electrode had a high initial capacity of 500 mAh/g or more, and was stabilized after 20 cycles to maintain a capacity of 400 mAh/g or more until 100 cycles.
Keywords
Nickel sulfide; Ammonium polysulfide; Lithium battery; Sulfide electrode; Electrochemical property;
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1 G. B. Cho, S. M. Park, S. S. Jeong, K. W. Kim, and T. H. Nam, "Structural and electrochemical properties of thermal sulfurized Ni-Ti alloy for the integration electrode", Materials Letters, Vol. 60, No, 5, 2006, pp. 643-645, doi: https://doi.org/10.1016/j.matlet.2005.09.051.   DOI
2 K. Zhang, F. Chen, H. Pan, L. Wang, D. Wang, Y. Jiang, L. Wang, and Y. Qian, "Study on the effect of transition metal sulfide in lithium-sulfur battery", Inorg. Chem. Front., Vol. 6, No. 2, 2019, pp. 477-481, doi: https://doi.org/10.1039/C8QI01193A.   DOI
3 S. C. Han, H. S. Kim, M. S. Song, J. H. Kim, H. J. Ahn, and J. Y Lee, "Nickel sulfide synthesized by ball milling as an attractive cathode material for rechargeable lithium batteries", J. Alloys and Comp., Vol. 351, No. 1-2, 2003, pp. 273-278, doi: https://doi.org/10.1016/S0925-8388(02)01037-X.   DOI
4 S. C. Han, H. S. Kim, M. S. Song, J. H. Kim, H. J. Ahn, and J. Y Lee, "Charge-discharge mechanism of mechanically alloyed NiS used as a cathode in rechargeable lithium batteries", J Alloys and Comp., Vol. 361, No. 1-2, 2003, pp. 247-251, doi: https://doi.org/6.   DOI
5 S. Ni, X. Yang, and T, Li, "Fabrication of a porous NiS/Ni nanostructured electrode via a dry thermal sulfuration method and its application in a lithium ion battery", J. Mater. Chem., Vol. 22, No. 6, 2012, pp. 2395-2397, doi: https://doi.org/10.1039/C2JM15394G.   DOI
6 K. S. Lee, S. T. Myung, K. Amine, H. Yashiro, and Y. K. Sun, "Structural and electrochemical properties of layered Li [Ni1-2xCoxMnx] O2 (x = 0.1-0.3) positive electrode materials for Li-Ion batteries", J. Electrochem. Soc., Vol. 154, No. 10, 2007, pp. A971-A977. Retrieved from https://iopscience.iop.org/article/10.1149/1.2769831.   DOI
7 J. Z. Wang, S. L. Chou, S. Y. Chew, J. Z. Sun, M. Forsyth, D. R. MacFarlane, and H. K. Liu, "Nickel sulfide cathode in combination with an ionic liquid-based electrolyte for rechargeable lithium batteries", Solid State Ionics, Vol. 179, No. 40, 2008, pp 2379-2382, doi: https://doi.org/10.1016/j.ssi.2008.09.007.   DOI
8 S. C. Han, H. S. Kim, M. S. Song, P. S. Lee, J. Y. Lee, and H. J. Ahn, "Electrochemical properties of NiS as a cathode material for rechargeable lithium batteries prepared by mechanical alloying", J. Alloys and Comp., Vol. 349, No.1-2, 2003, pp. 290-296, doi: https://doi.org/10.1016/S0925-8388(02)00882-4.   DOI
9 D. Mondal, G. Villemure, and C. Song, "Synthesis, characterization, and evaluation of unsupported porous NiS sub-micrometer spheres as a cathode material for lithium batteries", J. Applied Electrochem., Vol. 44, 2014, pp. 599-606, doi: https://doi.org/10.1007/s10800-014-0658-2.   DOI
10 N. Mahmood, C. Zhang, and Y. Hou, "Nickel sulfide/nitrogen-doped graphene composites: phase-controlled synthesis and high performance anode materials for lithium ion batteries" Small, Vol. 9, No. 8, 2013, pp. 1321-1328, doi: https://doi.org/10.1002/smll.201203032.   DOI
11 T. S. Sonia, P. Anjali, S. Roshny, V. Lakshmi, R. Ranjusha, K. R. V. Subramanian, S. V. Nair, and A. Balakrishnan, "Nano/micro-hybrid NiS cathodes for lithium ion batteries", Ceramics International, Vol. 40, No. 6, 2014, pp. 8351-8356, doi: https://doi.org/10.1016/j.ceramint.2014.01.041.   DOI
12 N. H. Idris, M. M. Rahman, S. L. Chou, J. Z. Wang, D. Wexler, and H. K. Liu, "Rapid synthesis of binary α-NiS-β-NiS by microwave autoclave for rechargeable lithium batteries", Electrochimica Acta, Vol. 8, 2011, pp. 456-462, doi: https://doi.org/10.1016/j.electacta.2011.09.066.   DOI