• Title/Summary/Keyword: NiMo

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Influence of Ion-Nitriding on Dynamic Fracture Toughness in Cr Alloy Steels (크롬합금강의 동적파괴인성에 미치는 이온실화처리의 영향)

  • 오세욱;윤한기;장래웅;김기술
    • Journal of Ocean Engineering and Technology
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    • v.2 no.1
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    • pp.150-162
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    • 1988
  • The dynamic fracture toughness, $K_{Id}$,is measured in the heat-treated and ion-nitrided Cr-Mo, Ni-Cr-Mo steel using standard and Precracked Charpy specimens an imstrumented impact machine. The value of $K_{Id}$and both the energy of initiate fracture, and the total energy of fracture. Since the $K_{Id}$values of the precraked impact specimens are in accord with their theoretical ones, this testing method is sufficently practical. The effect of ion-nitriding are found to be larger than the heat-treaded specimen.

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Interaction of Molybdenum Oxide with Titania : Raman Spectroscopic Study

  • Hack Sung Kim;Sang Hoon Han;Kwan Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.2
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    • pp.138-143
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    • 1991
  • Laser Raman spectroscopy has been used to study the interaction of $MoO_3$ with $TiO_2$. The bulk molybdenum oxide appeared to spread on the surface of titania under the submonolayer coverage. The surface polymolybdate was observed to be very stable with respect to the repeated treatment of reduction and subsequent calcination. Owing to the interaction of molybdate and titania, the phase transformation of $TiO_2$ seemed to be strongly retarded. The additives such as Co and Ni reacted readily with $MoO_3$ to form the corresponding molybdate salts. Nevertheless, the polymolybdate species appeared to be more stable on the titania surface than the molybdate salts.

Evaluation of PWHT cracking susceptibility of the Cr-Mo steel alloys (Cr-Mo 합금강의 후열처리 균열 감수성 평가)

  • Kim, Sang-Jin;Kim, Ki-Soo;Lee, Young-Ho
    • 대한공업교육학회지
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    • v.31 no.1
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    • pp.200-210
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    • 2006
  • This C-ring test, normally employed for evaluating susceptibility to stress-corrosion cracking, was determined to be a suitable small scale test to evaluate PWHT(Post-Weld Heat Treatment) cracking susceptibility. This test is possible to incorporate an actual weld, to introduce a notch into the coarse grained HAZ(Heat Affected Zone), to load the coarse grained HAZ any level of stress ad, most importantly, since the C-ring is an approximately constant strain type test, the stress decreases with time at temperature in a manner similar to that of an actual steel weldment. The procedure employed in making the C-ring was presented in the experimental procedure section, however, several points deserve further discussion. The walls of the weld groove are made along radial lines form the center of th var in order to obtain an HAZ which is oriented perpendicular to the walls of the machined C-ring. Therefore, the plane of maximum stress will be aligned through the HAZ and, therefore, crack propagation will not be forced to deviate form the plane of maximum stress in order to remain in the coarse grained HAZ as is the case with the Y groove test.

Development of High Performance WGS Catalyst for Fuel Processor Applications (연료 개질기용 고성능 수성가스 전환반응 촉매 개발)

  • Lee, Yoon-Ju;Ryu, Jong-Woo;Kim, Dae-Hyun;Choi, Eun-Hyung;Noh, Won-Suck;Lee, Sang-Deuk;Moon, Dong-Ju
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.451-454
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    • 2006
  • WGS reaction over Mo2C and ceria based catalysts was investigated to develop an alternative commercial Cu-Zn/Al2O3 catalyst for fuel processor and hydrogen station. The Mo2C catalysts were prepared by a temperature programmed method and the various metal supported cerium oxide catalysts were prepared by an Impregnation method. The catalysts were characterized by the N2 physisorption, Co chemisorption, XRD, TEM and TPR. It was found that Mo2C and 0.2wt% Pt-40wt%, Ni/CeO2 catalysts had higher activity and stability than the Cu-Zn/Al203 above $260^{\circ}C$. Moreover, CO conversion of more than 85% was observed at $280{\sim}300^{\circ}C$. But all catalysts were deactivated during the thermal cycling runs. The results suggest that these catalysts are an attractive candidate for the alternative Cu-Zn/Al2O3 catalyst for fuel processor and hydrogen station applications.

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Content of Heavy Metals in Coal Fly Ash from the Samcheonpo and the Seocheon Power Plant (삼천포와 서천 화력발전소에서 발생하는 석탄회중의 중금속 함량에 관한 연구)

  • Yoon, Chung-Han;Oh, Keun-Chang;Kim, Yong-Woong;Shin, Bang-Sup
    • Economic and Environmental Geology
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    • v.28 no.2
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    • pp.147-154
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    • 1995
  • Coal fly ashes collected from the Samcheonpo and the Seocheon Power Plants were analyzed for major and minor components and heavy metals such as As, Cd, Co, Cr, Cu, Ga, Hg, Mo, Ni, Pb, Sb, V and Zn in order to suggest basic data to apply coal fly ash as fertilizer or soil ameliorator. The specific gravity of the samples was less than 2.0, and amounts of organic matter range from 5.0% to 12.3%. The identified minerals by XRD were mainly quartz, mullite and pyrite in anthracite coal, and mainly quartz and mullite in bituminous coal. Generally, the contents of heavy metal elements analyzed were lower less than those of soil, though higher in some samples. Element couples of some elements( e.g., As-Mo, Zn ; Mo-As, Sb, V, Zn ; Sb-Zn ) show positive correlations with each other, but the high correlations of toxic elements such as As, Pb, Cd and Hg indicate to give attention to apply coal fly ash as fertilizer or soil ameliorator.

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Effects of Heat Treatment and Ti addition on Microstructures in Modified Invar Alloys (개량형 인바합금의 미세조직에 미치는 열처리 및 Ti 첨가 영향)

  • Huh, Min-Sun;Lee, Jung-Han;Lee, Chan-Gyu;Lee, Jae-Hyun
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.6
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    • pp.412-419
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    • 2000
  • There has been a considerable attention on Invar alloys due to its low thermal expansion property. A low thermal expansion property of Invar alloys, lower than $10^{-6}$ near the room temperature, is attractive for electric transmission lines and precision machine tools. However, the expansion property of Invar alloys is limited below about 520K, and mechanical properties are relatively low to apply to electric transmission line. In order to improve mechanical properties in this alloy, Ti alloying element was added to the $Ni_{38}-Mo_2-Cr_1-Fe$ invar alloy. The microstructure Ti added alloy showed finer than that of the unalloyed one. It was found that the (Mo, Ti), Mo carbide formed by Ti addition obstacled grain growth by pinning effect and supplyed recrystallization sites during heat-treatment. Optimum heat-treatment conditions with Ti addition were also discussed in the modified Invar alloy.

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Effects of pH and Chloride Concentration on Corrosion Behavior of Duplex Stainless Steel and Titanium Alloys Ti 6Al 2Nb 1Ta 1Mo at Elevated Temperature for Pump Impeller Applications

  • Aymen A., Ahmed;Ammar Yaseen, Burjes;Ammar Yaseen, Burjes
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.454-465
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    • 2022
  • The objective of this study was to determine effects of temperatures and pH of sodium chloride solution with MgCl2 ions on corrosion resistance of duplex stainless-steel X2CrNiMoN22-5-3 (DSS) and Ti 6Al 2Nb1Ta1Mo (Ti). Effects of sodium chloride concentration on corrosion resistance were also studied. Corrosion behavior and pitting morphology of duplex stainless steel (DSS) and Ti alloys were evaluated through potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). It was found that a decrease in pH significantly reduced the corrosion resistance of both alloys. Changes in chloride concentration and temperature had more substantial impact on corrosion behavior of DSS than on Ti alloys. Pitting corrosion was formed on DSS samples under all conditions, whereas crevice corrosion was developed on Ti samples with the presence of magnesium chloride at 90 ℃. In conclusion, magnesium chloride ions in an exceedingly strong acidity solution appear to interact with re-passivation process at the surface of these alloys and influence the resulting surface topography.

Trend of Researches for Human Effects of Electromagnetic Fields (전자파 인체영향 연구동향)

  • Kwon, J.H.
    • Electronics and Telecommunications Trends
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    • v.31 no.3
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    • pp.42-49
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    • 2016
  • 전자파 인체영향 관련 다양한 연구들이 유럽은 물론 미국, 일본, 중국 등 기술 선진국을 중심으로 전세계적으로 진행되고 있다. 특히, 유럽에서는 FP7 RTD 프로젝트의 일환으로 국가 간 혹은 관련 산업 간 컨소시엄을 구성하여 1990년대부터 전자파에 의한 인체영향과 관련된 다양한 프로젝트가 수행되었으며 현재도 다양한 주제의 프로젝트들이 수행 중이다. 본고에서는 유럽을 중심으로 진행 중인 전자파 인체영향 관련 프로젝트, 즉 휴대전화 전자파와 인체영향에 대해 연구를 수행하는 Interphone Study, Mobi-Kids Study, 그리고 Mobi-Kids 연구결과 및 프로토콜을 기반으로 일반인에 대해 누적되고 종합적인 전자파 영향 연구를 수행하는 GERoNiMO 프로젝트, 그리고 노출량 저감 관련 LEXNET 프로젝트에 대해 소개하였다.

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Colored Cubic Zirconia(CCZ) Single Crystal Growth by Skull Method (SKull법에 의한 Colored Cubic Zirconia(CCZ)단결정 성장)

  • 김석호;최종건;정대식;오근호
    • Journal of the Korean Ceramic Society
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    • v.25 no.5
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    • pp.443-448
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    • 1988
  • Colored Cubic Zircona(CCZ) single crystals were grown by the skull melting method. The grown crystals were doped with up to 0.1wt% transition (Cu, Ni, Co, Ti, Fe, Mo, Cr, V, Mn) metal ions on ZrO2-Y2O3(9.5~10mol%) and their Optical transmission spectra(λ=300~800nm)data were obtained. Various colors were pronounced due to dopant effects in the grown Crystals.

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Determination of Cation Charge Density in Mica-type Layered Aluminosilicates by N-alkylammonium Method (N-alkylammonium법에 의한 Mica형 층상 규산 알루미늄의 양이온 전하 밀도의 측정)

  • 최진호;박중철;김창은;이창교
    • Journal of the Korean Ceramic Society
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    • v.22 no.4
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    • pp.3-8
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    • 1985
  • The layer charge densities and interlayer C. E. C(cation exchange capacity) of ten mica-type aluminosilicates from Yong-il Pohang-prefacture were determined by n-alkylammonium method which is based on the mo-nolayer-doubelelayer structural transition of ni-alkylammonium ion in interlayer space of the layered silcates. The upper and lower limits of layer charge and interlyer C, E, C estimated were about 0.25~0.36 eq/(Si, $Al)_4$ O10 and 69~99meq/100g, respectively.

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