• Title/Summary/Keyword: Ni-W alloy

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Development of textured Ni and Ni alloy(Ni-W and Ni-Cu) substrates for YBCO coated conductor (YBCO 박막선재용 Ni 및 Ni 합금 기판의 집합도 분석)

  • 지봉기;김민우;김찬중
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.24-26
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    • 2003
  • We fabricated Ni and Ni alloy substrates for YBCO coated conductors. The Ni and Ni alloy substrate was fabricated by powder metallurgy technique and cold rolling. The texture of substrates had a strong 4-fold symmetry and [111]∥ND texture after annealing temperature of 100$0^{\circ}C$. The measured full-width half-maximum (FWHM) of in-plane and out-of-plane was in the range of 6$^{\circ}$-10$^{\circ}$. The powder metallurgy technique is fabrication of the substrates for considered to be suitable for the application of YBCO coated conductors.

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Effect of Sulfur on the High-temperature Oxidation of Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si Alloys (Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si 합금의 고온 산화에 미치는 S의 영향)

  • Lee, Dong Bok;Lee, Kyong-Hwan;Bae, Geun Soo;Cho, Gyu Chul;Jung, Jae Ok;Kim, Min Jung
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.386-391
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    • 2017
  • Two kinds of steels whose compositions were Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) were centrifugally cast, and oxidized at $900^{\circ}C$ for 50-350 h in order to find the effect of sulfur on the high-temperature oxidation of Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) alloys. These alloys formed oxide scales that consisted primarily of $Cr_2O_3$ as the major oxide and $Cr_2MnO_4$ as the minor one through preferential oxidation of Cr and Mn. They additionally formed $SiO_2$ particles around the scale/alloy interface as well as inside the matrices. The high affinity of Mn with S led to the formation of scattered MnS inclusions particularly in the 0.35S-containing cast alloy. Sulfur was harmful to the oxidation resistance, because it deteriorated the scale/alloy adherence so as to accerelate the adherence and compactness of the formed scales.

Investigation of Initiation of Electroless Ni-P and Ni-Cu-P deposition on pure iron

  • Yiyong, W-U;Kim, M.;S.C. Kwon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.11a
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    • pp.10-10
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    • 2001
  • In this paper, initial depositing process of electroless Ni-Cu-P alloy was investigated by means of SEM, TEM and AES. The results show that the initial deposition is inhomogeneous and there exist different transition layers between different coatings and substrates, which are decided by the structures and compositions of the bath. For Ni-P binary alloy, its deposition takes place superiorly at grain boundary and on some grains with beneficial texture, the thickness of transition layer composed of Ni-Fe-P reaches 2000 angstrom. But during initiation of Ni-Cu-P trinary alloy, only at grain boundary is prIor to be deposited electrolessly, transited layer contains Ni-Fe-Cu-P and is decreased to about 500 angstrom. The structures of the films of Ni-P and Ni-Cu-P are crystalline at the initial depositing stage. The mechanisms of the process are put forward in this paper.

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Microstructures of W-Mo-Ni-Fe Heavy Alloys

  • Lin, Kuan-Hong;Hsu, Chen-Siang;Lin, Shun-Tian
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.937-938
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    • 2006
  • Tungsten heavy alloys with different ratios of Mo and Ni-Fe matrix were liquid-phase-sintered to investigate their microstructural evolution. Results indicated that increased Mo in the alloy promoted the formation of a (W,Mo)(Ni,Fe) type intermetallic compound in the furnace-cooled condition. It was a monoeutectic reaction when the added Mo content was higher than 49at.%, or a eutectic reaction when this value was between 37at,% to 49at.%. When Mo was added between 25at.% to 37at.%, the precipitation of the intermetallic compound took place by either a eutectoid or peritectoid reaction.

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Trend of the Corrosion resistance Elevation by Ni-W-P Alloy Plating (Ni-W-P합금도금 내식성향상 기술동향)

  • Kim, Yu-Sang;Seo, Yun-Seok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.201-201
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    • 2011
  • 크롬대체도금으로 개발 추진되고 있는 전기Ni-W합금도금피막은 경질크롬 도금피막보다도 고온에서 경도 및 내 산성이 우수하고, 유리성형용 금형으로 사용되고 있다. 최근 일본에서는 지금까지의 무전해Ni-W-P합금피막에 비해서 텅스텐, 인의 함유율이 높고, 질산 이외의 염산, 황산의 산성 환경과 암모니아, 수산화나트륨 등의 알칼리성 환경에서도 부식이나 변색이 생기지 않는 무전해Ni-W-P합금도금기술을 크롬도금을 대체하는 도금으로서 개발하고 있다.

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Effects of Deposition Conditions on Properties of CuNi thin Films Fabricated by Co-Sputtering of Dual Targets (이중 타겟의 동시 스퍼터링을 이용한 CuNi 박막 제작시 증착변수가 박막의 물성에 미치는 영향)

  • Seo, Soo-Hyung;Lee, Jae-Yup;Park, Chang-Kyun;Park, Jin-Seok
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.1
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    • pp.11-16
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    • 2001
  • CuNi alloy films are deposited by co-sputtering of dual targets (Cu and Ni, respectively). Effects of the co-sputtering conditions, such as powers applied to the targets, deposition pressures, and substrate temperatures, on the structural and electrical properties of deposited films are systematically investigated. The composition ratio of Ni/Cu is almost linearly decreased by increasing the DC power applied to the Cu target from 25.6 W to 69.7 W with the RF power applied to the Ni target unchanged(140 W). it is noted that the chamber pressure during deposition and the film thickness give rise to a change of the Ni/Cu ratio within the films deposited. The former may be due to a higher sputtering yield of Cu atom and the latter due to the re-sputtering phenomenon of Cu atoms on the surface of deposited film. The film deposited at higher pressures or at lower substrate temperatures have a smaller crystallite size, a higher electrical resistivity, and much more voids. This may be attributed to a lower surface mobility of sputtered atoms over the substrate.

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Fundamental Study on Ni-Base Self-Fluxing Alloy Coating by Thermal Spraying(I) - Effect of Splat Behavior of Sprayed Particles on Mechanical Properties of Coating Layer - (Ni-기 자융성합금의 코팅에 관한 기초적 연구(I) - 용사입자의 편평거동이 코팅층의 기계적 특성에 미치는 영향 -)

  • Kim, Y.S.;Kim, H.S.;Nam, K.W.
    • Journal of Power System Engineering
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    • v.1 no.1
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    • pp.70-79
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    • 1997
  • Ni-base self-fluxing alloy powder particles were flame sprayed onto the SS400 mild steel substrate surface. The effects of both substrate temperature and spraying distance on the splat behavior of sprayed particles were examined. The results obtained are summarized as follows: 1) In the splat behavior of Ni-base self-fulxing alloy particles sprayed onto the SS400 mild steel substrate, splashing was observed under the room temperature condition. On the contrary, it showed circular plate pattern in the substrate temperature range over 373K. 2) It was cleared that there was close relationship between mechanical properties of coating layer and splat behavior of sprayed particles. 3) From the experimental results, optimum spraying conditions showed excellent mechanical properties in the case of Ni-base self fluxing alloy sprayed onto the SS400 mild substrate were 473K of substrate temperature and 250mm of spraying distance.

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A Study on Oxidation Mechanism in Mechanically Alloyed ODS Ni-base Alloy

  • Kim, I.H.;Kwun, S.I.;Park, J.P.;Lee, W.S.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2003.10a
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    • pp.65-66
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    • 2003
  • 1. The oxidation resistance of $Y_{2}O_{3}$ containing Ni-base alloy is superior to that of the alloy without $Y_{2}O_{3}$. 2. The appearance of oxides of Ni-20Cr-20Fe-5Nb-$1Y_{2}O_{3}$ alloy is similar to that of oxides in commercial PM1000 and MA754 alloy. 3. The oxides in ODS alloy are grown mainly at particle boundaries.

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