• Title/Summary/Keyword: Ni-Mo

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국내 주요 철강산업지역으로부터 거리에 따른 주거지역의 호흡성 분진(PM10)과 유해 무기물질의 노출 및 오염원 기여도 평가

  • Kim, Mo-Geun;Jo, Wan-Geun
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.11a
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    • pp.29-32
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    • 2005
  • 주거지역 A와 주거지역 B의 PM10 평균농도 비교에서 산업지역과 인접한 주거지역 A에서 계절에 관계없이 26-32% 높은 농도를 나타내어 산업지역에 인접한 주거지역 A가 먼 주거지역 B 보다 PM10의 영향에 더 크게 노출된 것을 확인 할 수 있었다. PM10에 포함된 Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn 등의 무기성분은 대부분 인위적인 발생원과 관련성이 있는 대기 오염물질로, 인위적인 배출원의 영향정도를 파악하기 위하여 풍성계수 분석결과 높은 풍성계수를 나타내어 인위적인 오염원임을 확인 할 수 있었고, 그 평균농도는 주거지역 A가 주거지역 B 보다 높게 나타나 주거지역 A가 주거지역 B 보다 산업 오염원의 노출에 더 많은 영향을 받는 다는 것을 확인 할 수 있었다. 또한 이들 무기화합물질의 상관성 분석결과 높은 상관성과 통계적인 유의성 (p<0.01)이 있었으며, 공통의 오염원을 추정 할 수 있었다. PM10의 가능한 오염원 기여도 평가에 있어서, 주거지역 A에서는 제철관련 오염원과 토양오염원의 공통 오염원 기여도가 33.4%로 나타나 산업관련 오염원의 기여도를 뚜렷하게 분리하여 평가하기는 곤란하였으나, 주거지역 B에서 토양관련 오염원의 독립적인 농도 기여도가 54%로 높게 나타났기 때문에, 상대적으로 산업지역과 인접한 주거지역 A에서 산업관련 오염원 기여도가 높은 것을 알 수 있었다.

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The Analysis of Spectrum on the Barkhausen Noise of Hysteresis Loops on Neutron Irradiated Material

  • Sim, Cheul-Muu;Chang, Kee-Ok;Park, Kook-Nam;Cho, Man-Soon;Park, Chang-Oong
    • The Journal of the Acoustical Society of Korea
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    • v.18 no.1E
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    • pp.7-12
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    • 1999
  • In relation to a non-destructive evaluation of irradiation damages, the changes in the hysteresis loop and Barkhausen noise amplitude and the harmonics frequency due to a neutron irradiation were measured and evaluated. The Mn-Mo-Ni low alloy steel of RPV was irradiated to a neutron fluence of 2.3 ×10/sup 19/ n/㎠ (E ≥1 MeV) at 288℃. The saturation magnetization of neutron irradiated metal did not change. The neutron irradiation caused the coercivity to increase, whereas susceptibility to decrease. The amplitude of Barkhausen noise parameters associated with the domain wall motion were decreased by a neutron irradiation. The spectrum of Barkhausen noise is analysed with an applied frequency of 4 Hz and 8 Hz, sampling time of 50 μ sec and 20 μ sec. The harmonic frequency shows 4 Hz, 8 Hz, 12 Hz and 16 Hz reflected from an unirradiated specimen. On the contrary, the harmonic frequency disappeared on the irradiated specimen. In addition to the amplitude, the harmonic frequency of Barkhausen noise is taken into accounts as a promising tool for monitoring the irradiation induced degradation of the reactor materials such as a SA508 of PWR-RPV steel and a Zr₄ of HANARO-CNH.

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The Characteristics of Fatigue Cracks Emanating from Micro Hole Defects Located Opposite Position of the Shaft Cross Section (축 단면 내 대칭 위치의 미소 원공 결함에서 발생한 피로균열 특징)

  • Song, Sam-Hong;Bae, Jun-Su;Ahn, Il-Hyuk
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.211-216
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    • 2001
  • The components with the circular cross section have the symmetric combination parts for rotating balance and the crack emanates from the symmetric combination parts. The symmetric cracks from symmetric combination parts make a decrease in the component fatigue life more than single crack. In this study, to estimate the behavior of symmetric cracks, the fatigue test was performed using rotary bending tester on the specimen with a symmetric defects in circular cross section. The material used in this study is Ni-Cr-Mo steel alloy. Under the same stress, the result from the rotary bending fatigue test turned out that the symmetric cracks made a decrease in the fatigue life by 35% more than single crack and the relation between log a and cycle ratio $N/N_f$ obtained linearly.

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Creep Crack Growth Properties of Rotor Steel under Constant Load and $C_t$ Condition (일정하중 및 일정$C_t$에서 로터강의 크리프 균열전파특성)

  • Jeong, Soon-Uk;Lee, Hun-Sik;Kim, Young-Dae
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.501-506
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    • 2001
  • The creep crack growth properties in 3.5NiCrMoV steel were investigated at $550^{\circ}C$ by using CT specimen under constant $C_t$ condition that was held during crack growth of 1mm distance. $C_t$ lely on load line displacement rate and $C^*$ usually increase with crack length though load is reduced in order to maintain constant $C_t$ value as crack growth. Fully coalesced area(FCA) ahead of crack tip tend to increase as $C_t$ increase to the critical value, and after that value FCA decrease. For the tertiary creep stage of crack growth test, the most of displacement is due to the steady state creep, except only small part due to the primary creep and other effects. Therefore, tests were mainly interrupted in the tertiary stage to obtain high value of $C_t$. At constant load and $C_t$ region, crack growth slope was 0.900 and 0.844 each, on the other hand $C^*$ slope was 0.480.

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Fabrication of polycrystalline Si films by rapid thermal annealing of amorphous Si film using a poly-Si seed layer grown by vapor-induced crystallization

  • Yang, Yong-Ho;An, Gyeong-Min;Gang, Seung-Mo;An, Byeong-Tae
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.58.1-58.1
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    • 2010
  • We have developed a novel crystallization process, where the crystallization temperature is lowered compared to the conventional RTA process and the metal contamination is lowered compared to the conventional VIC process. A very-thin a-Si film was deposited and crystallized at $550^{\circ}C$ for 3 h by the VIC process and then a thick a-Si film was deposited and crystallized by the RTA process at $680^{\circ}C$ for 5 min using the VIC poly-Si layer as a crystallization seed layer. The RTA crystallized temperature could be lowered up to $50^{\circ}C$, compared to RTA process alone. The poly-Si film appeared a needle-like growth front and relatively well-arranged (111) orientation. In addition, the Ni concentration in the poly-Si film was lowered to $3{\times}10^{17}\;cm^{-3}$ and that at the poly-Si/$SiO_2$ interface was lowered to $5{\times}10^{19}\;cm^{-3}$. The reduction in metal contamination could be greatly helpful to achieve a low leakage current in poly-Si TFT, which is the critical parameter for commercialization of AMOLED.

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Phase transition properties of tungsten contained vanadium oxides film (텅스텐 첨가에 따른 바나듐 막의 상전이 특성 변화에 대한 연구)

  • Choi, Jong-Bum;Jo, Jung-Ho;Lee, Yong-Hyun;Choi, Byung-Yul;Lee, Moon-Seok;Kim, Byung-Ik;Shin, Dong-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.208-209
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    • 2005
  • 바나듐 산화물은 반도성-금속성으로 상전이 하는 CTR특성의 대표적인 산화물로 상전이 온도인 68$^{\circ}C$에서 저항의 급변 특성을 보인다. 여기에 Fe, Ni, Mo, Ti, W과 같은 금속성 산화물을 첨가함에 따라 상전이온도를 움직일 수 있다. 그중 $WO_3$를 첨가함으로써 상전이온도를 상온까지 낮출 수 있다. Inorgnic sol-gel 법에 의해 바나듐-텅스텐 sol을 제조 하였으며, 제조된 sol을 기판에 코팅한 후 환원분위기에서 열처리 하여 막을 얻었다. 온도-저항 특성 측정 결과 순수 바나듐 막은 상전이 온도는 68$^{\circ}C$ 전기저항 감소폭은 $10^4$order 이였으나 바나듐-텅스텐막의 상전이 온도는 38$^{\circ}C$, 전기저항 감소폭은 $10_{15}$order 로 감소함을 확인 하였다.

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Effect of buffer layer on YBCO film deposited on Hastelloy substrate ($CeO_2$의 상전이에 따른 YBCO 박막의 결정성 및 특성의 변화)

  • Kim, Sung-Min;Lee, Sang-Yeol
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.873-875
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    • 1999
  • We have fabricated good quality superconducting $YBa_{2}Cu_{3}O_{7-\delta}$ thin films on Hastelloy(Ni-Cr-Mo alloys) metallic substrate with $CeO_2$ and $BaTiO_3$ buffer layers in-situ by pulsed laser deposition in a multi-target processing chamber. We have chosen $CeO_2$ as a buffer layer which has cubic structure of $5.41{\AA}$ lattice parameter and only 0.2% of lattice mismatch with YBCO. $CeO_2$ layer may be helpful for power transmission due to its conducting property. In order to enhance the crystallization of YBCO films on metallic substrates. we deposited $CeO_2$ and $BaTiO_3$ buffer layers at various temperatures. The YBCO superconducting tape fabricated with $BaTiO_3$ and $CeO_2$ buffer layers shows 85K of transition temperature and about $8.4{\times}10^4A/cm^2$ of critical current density at 77K.

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Hardenability of Ductile Cast Iron (구상흑연주철의 경화능)

  • Lee, Y.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.1 no.1
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    • pp.13-23
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    • 1988
  • The hardenability of alloyed ductile cast irons was studied for 54 different alloy compositions obtained from eight commercial and laboratory foundries. The alloying elements investigated for their effects on hardenability were Si(2.0 to 3.0%), Mn(0.0 to 0.8%), Mo(0.0 to 0.6%), Cu(0.0 to 1.5%), and Ni(0.0 to 1.5%). Two hardenability criteria, a first-pearlite hardenability criterion and a half-hard hardenability criterion, were used to determine hardenability of ductile irons. Prediction models for each hardenability criterion were developed by multiple regression analysis and were well agreed with previous experimental results. Molybdenum was the most potent hardenability promoting element followed by manganese, copper and nickel ; silicon had little effect on hardenability and reduced the hardenability as silicon content increased. When alloying elements were presented in combination, strong synergistic effects on the hardenability were observed especially between molybdenum, copper and nickel. The hardenability of ductile iron was strongly influenced by austenitizing temperature. Increasing austenitizing temperature up to $955^{\circ}C$, hardenability increased gradually but decreasing rate and then decreased as temperature increased above $955^{\circ}C$. Unless reducing segregation by very long-time annealing treatment, the hardenability of ductile iron was not significantly influenced by segregation of alloying elements.

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Creep Crack Propagation Properties of Rotor Steel under Constant Load and Constant Ct Condition (일정하중 및 일정Ct에서 로터강의 크리프 귤열전파 특성)

  • Jeong, Soon-Uk
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.5
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    • pp.105-111
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    • 2001
  • The creep crack growth properties in 3.3NiCrMoV steel were investigated at 55$0^{\circ}C$ by using CT specimen under constant load and constant Ct condition that was held during crack growth of Imm distance. Ct lelied on load line displacement rate, C*usually increased with crack length though load is reduced in order to maintain constant Ct value as crack growth and appeared scatter band. At constant load and Ct region, crack growth slope was 0.900 and 0.844 each, on the other hand C* slope was 0.480. Fully coalesced area(FCA) ahead of crack tip increased as Ct increase to the critical value, and after that value FCA decreased. For the tertiary creep stage of crack growth test, the most of displacement was due to the steady state creep, except only small part due to the primary creep and other effects. Therefore, tests were mainly interrupted in the tertiary stage to obtain high value of Ct.

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반응성 스퍼터의 Se Cracker Reservoir Zone 온도에 따른 특성분석

  • Kim, Ju-Hui;Park, Rae-Man;Kim, Je-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.585-585
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    • 2012
  • $Cu(In_{1-x}Ga_x)Se_2$(CIGS) 박막 태양전지는 Chalcopyrite 계 박막 태양전지로 Cu, In, Ga, Se 각 원소의 조성을 적절히 조절하여 박막을 성장시킨다. 성장시킨 CIGS 박막은 광흡수계수가 $10^5cm^{-1}$로 다른 물질보다 뛰어나고 직접 천이형 반도체로서 얇은 두께로도 고효율의 박막 제작이 가능하다. CIGS 태양전지를 제조하는 방법은 3-stage 동시 증착법, 금속 전구체의 셀렌화 공정법, 전기 증착법 등이 있다. 그 중에 금속 전구체의 셀렌화 공정법은 다른 제조 방법에 비해 대면적 생산에 유리한 장점이 있다. 하지만 아직 상대적으로 3-stage 동시 증착법에 비해 낮은 에너지 변환 효율이 보고된다. 본 실험에서는 기존의 금속 전구체의 셀렌화 공정법과는 달리 전구체 증착과 셀렌화 공정을 동시에 하고, Se cracker를 통하여 Se 원료를 주입하는 방식인 반응성 스퍼터링 공정에서 reservoir zone의 온도 변화에 따른 특성을 분석하였다. Se cracker의 reservoir zone 온도가 증가할수록 Cu/(In+Ga) 비가 증가한다. CIGS 박막 태양전지의 구조는 Al/Ni/ITO/i-ZnO/CdS/CIGS/Mo/Soda lime glass이다. CIGS 박막의 조성비가 Cu/(In+Ga)=0.89, Ga/(In+Ga)=0.17인 박막 태양전지에서 개방전압 0.34 V, 단락전류밀도 $32.61mA/cm^2$, 충실도 56.2% 그리고 변환 효율 6.19%를 얻었다. 본 연구는 2011년도 지식경제부의 재원으로 한국에너지 기술평가원(KTEP)의 지원을 받아 수행한 연구 과제입니다(No.20093020010030).

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