• 한국해양학회지
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• 제18권1호
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• pp.29-42
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• 1983

濟州道周圍 大陸棚地域과 韓半島 南海沿岸에서 總 39個의 海底堆積物中의 重金屬含量이 測定되었다. 濟州道周圍의 平均含量은 Zn 59.1ppm, Mn 362.6ppm, Cr 63.8ppmiouPb 15-7ppm, Co 10.0ppm, Ni 28.9ppm, Cu 10.5ppm, Fe 2.7%로 나타났다. 南海沿岸에서는 Zn 79.5ppm, Mn 384ppm, Pb 8.6ppm, Ni 17.8ppm, Cu 23.2ppm, Fe 1.59%로 나타났다. 濟州道周圍에서는 細粒質堆積物이 分布하는 北西部가 기타 地域에 比해 높다. 反面 南海沿岸에서는 地域的 傾向成이 나타나지 않지만 馬山灣과 鎭海灣은 周圍隣近陸上의 産業活動에 의한 影響으로 他地域에 比해 높게 나타난다. 그러나 馬山灣과 鎭海內灣에서 Zn과 cu의 高含量을 除外 하고는 全體的으로 世界沿岸堆積物의 平均치에 미치지 못하는 낮은 含量이다. 각 表示成分間의 相關性은 濟州道周圍에서 Zn-Cu, Ni-Cu, Fe-cu, Cr-Cu, Co-Zn, Ni-Zn, Cr-Zn, Ni-Co, Fe-Co, Cr-Co, Fe-Ni, Cr-Ni, Cr-Fe간에 密集한 正의 相關性이 나타나며, Pb, Mn을 除外한 全元元素成分이 粒度와 良好한 正의 相關性을 나타내 粒子가 細立일수록 元素의 吸着率이 크다. 南海沿岸에서는 Cu-Zn, Cu-ni 및 Ni-Mn를 除外하고는 相關關係가 不良하다. 이는 堆積環境이 地域別로 다르고 또한 陸上의 人爲的 活動에 따른 流入含量의 差異에서 온 것으로 생각된다.

• Corrosion Science and Technology
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• 제13권2호
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• pp.41-47
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• 2014

The isothermal corrosion tests of several types of stainless steels, Ni-based alloys, and ferritic-martensitic steels (FMS) were carried out at the temperature of 550 and $650^{\circ}C$ in SFR S-$CO_2$ environment (200 bar) for 1000 h. The weight gain was greater in the order of FMSs, stainless steels, and Ni-based alloys. For the FMSs (Fe-based with low Cr content), a thick outer Fe oxide, a middle (Fe,Cr)-rich oxide, and an inner (Cr,Fe)-rich oxide were formed. They showed significant weight gains at both 550 and $650^{\circ}C$. In the case of austenitic stainless steels (Fe-based) such as SS 316H and 316LN (18 wt.% Cr), the corrosion resistance was dependent on test temperatures except SS 310S (25 wt.% Cr). After corrosion test at $650^{\circ}C$, a large increase in weight gain was observed with the formation of outer thick Fe oxide and inner (Cr,Fe)-rich oxide. However, at $550^{\circ}C$, a thin Cr-rich oxide was mainly developed along with partially distributed small and nodular shaped Fe oxides. Meanwhile, for the Ni-based alloys (16-28 wt.% Cr), a very thin Cr-rich oxide was developed at both test temperatures. The superior corrosion resistance of high Cr or Ni-based alloys in the high temperature S-$CO_2$ environment was attributed to the formation of thin Cr-rich oxide on the surface of the materials.

• 한국표면공학회지
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• 제29권5호
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• pp.386-392
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• 1996

The epitaxial TM/bcc-Cr(001) (TM=Fe, Co, Ni) multilayers have been prepared using MBE. The crystal structure, interlayer exchange coupling and magnetoresistance of those multilayers have been discussed. The structure of Fe, Co and Ni grown on bcc-Cr(001) exhibited bcc(001), distorted hcp(1120) and fcc(110), respectively. In Fe/Cr multilayes, an oscillatory exchange coupling has been observed, but not observed in Ni/Cr system, which may come from the large mixing at interfaces. Large MR ratio (116%, 4.2K) has been obtained in Fe/Cr system, but only 2% in Co/Cr system. This difference can be understood from the view point of the relative potential geight for down spin electrons between TM and Cr.

• 대한금속재료학회지
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• 제49권2호
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• pp.153-160
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• 2011

The AISI 216L stainless steel with a composition of Fe-16Cr-6Ni-6Mn-1.7Mo (wt.%) was oxidized at $700{\sim}900^{\circ}C$ in air for 100 h. At $700^{\circ}C$, a thin $Mn_{1.5}Cr_{1.5}O_4$ oxide layer with a thickness of $0.4{\mu}m$ formed. At $800^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $FeCr_2O_4$ oxide layer with a total thickness of $30{\mu}m$ formed. The non-adherent scale formed at $800^{\circ}C$ was susceptible to cracking. At $900^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $Mn_{1.5}Cr_{1.5}O_4$ oxide layer formed, whose total thickness was $10{\sim}15{\mu}m$. The scales formed at $900^{\circ}C$ were non-adherent and susceptible to cracking. 216 L stainless steel oxidized faster than 316 L stainless steel, owing to the increment of the Mn content and the decrement of Ni content.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2003년도 춘계학술발표회 초록집
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• pp.74-75
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• 2003

• 한국세라믹학회지
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• 제51권5호
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• pp.505-510
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• 2014

The properties of black ceramic pigments including thermal and glaze stability were systematically investigated so that these pigments could be used to decorate porcelain products. Various compositions of $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ and $Co(Fe,Cr)_2O_4$ powders were synthesised using a solid state reaction method. The obtained $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ powders showed single phases of spinel structure after calcination processes at $1000^{\circ}C$ and $1200^{\circ}C$, respectively. CIE $L^*a^*b^*$ colourimetric parameters of glazed $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ pigments were analyzed according to the different amounts of Cr substitution. In addition, the amount of $Cr^{+6}$ remaining in the $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ pigments was also measured.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1316-1317
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• 2006

The paper investigates the possibility to avoid extrinsic embrittlement of $Ni_3Al$, also increasing the high temperature strength, by alloying with both Fe - of a high strengthening effect and Cr - able to remove a part of diffused oxygen along the grain boundaries. As Cr homogenization in $Ni_3Al$ is difficult because of its low diffusion coefficient, for its improving a mechanical alloying (MA) step before the compound synthesis by Self-propagating High-temperature Synthesis (SHS) was adopted. The obtained better homogenization resulted in higher mechanical resistance and deformability than of the unalloyed $Ni_3A/Ni_3Al$ alloys of the same composition obtained without MA step.

• 한국주조공학회지
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• 제17권3호
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• pp.258-266
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• 1997

The purpose of this study is to improve hardness and wear resistance of high strength yellow brass by adding Fe, Cr, Mn, Si and Ni. Results showed that NiO, $FeCr_2O_4$ and intermetallic compound $Mn_5Si_3$ were produced when Ni, Fe-Cr and Mn-Si were added to the yellow brass. The hardness and wear tests showed the best results with the presence of the product precipitates and intermetallic compound. The calculation of relative wear resistance by volume fraction of each phases showed that the relative wear resistance of $Mn_5Si_3$ had the highest value, that of ${\beta}$ phase had the lowest. Observation of the worn surface showed that the main wear mechanism were found to be the abrasive wear, and also showed that the wear is caused by mechanical failure at the early stage.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2009년도 춘계학술대회 논문집
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• pp.278-281
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• 2009

Selective laser sintering(SLS), a kind of rapid prototyping technology, can provide a process to form many types of coatings. Coated layers by selective laser melting are highly influenced by substrate, powder and laser parameters such as laser power, scan rate, fill spacing and layer thickness. Therefore an attempt to fabricate Fe-Ni-Cr coating on AISI H13 tool steel has been performed by selective laser sintering. In this study, Fe-Ni-Cr coating was produced by experimental facilities consisting of a 200W fiber laser which can be focused to 0.08mm and atmospheric chamber which can control atmospheric pressure with Ar. With power increase or energy density decrease, line width was decreased and line surface quality was improved with energy density increase. Surface quality of coating layer was improved with fill spacing optimization or layer thickness decrease.

• 한국표면공학회지
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• 제37권1호
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• pp.28-39
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• 2004

The effect of trace metallic additives on microstructure, surface appearance and hardness of zinc electrodeposits was investigated by using sulfate bath and flow cell system. The preferred orientation of Zn deposit with Fe additive was (103)(104)+(002) mixed texture and that of Zn deposits with both Fe-Ni and Fe-Co additives was (10 1), while Zn deposits with Fe-Cr additives had (002) preferred orientation. The surface morphology of the zinc deposits was closely related to the preferred orientation of the deposits. The glossiness of Zn deposit with Fe-Ni additives was higher than that of pure Zn deposit, while the glossiness of Zn deposits with both Fe-Co and Fe-Cr additives was lower than that of pure Zn deposit. The hardness of Zn deposits with both Fe-Ni and Fe-Co additives was noticeably higher than that of Zn-Fe deposit, while that of Zn deposit with Fe-Cr additives was similar to that of Zn-Fe deposit.