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http://dx.doi.org/10.4191/kcers.2014.51.5.505

Effect of Chrome Substitution on Coloration Characteristics of Black Ceramic Pigments  

Lee, Ji-Hyeon (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
Hwang, Hae-Jin (Division of Material Science and Engineering, Inha University)
Kim, Jin-Ho (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
Hwang, Kwang-Taek (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
Han, Kyu-Sung (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
Publication Information
Journal of the Korean Ceramic Society / v.51, no.5, 2014 , pp. 505-510 More about this Journal
Abstract
The properties of black ceramic pigments including thermal and glaze stability were systematically investigated so that these pigments could be used to decorate porcelain products. Various compositions of $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ and $Co(Fe,Cr)_2O_4$ powders were synthesised using a solid state reaction method. The obtained $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ powders showed single phases of spinel structure after calcination processes at $1000^{\circ}C$ and $1200^{\circ}C$, respectively. CIE $L^*a^*b^*$ colourimetric parameters of glazed $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ pigments were analyzed according to the different amounts of Cr substitution. In addition, the amount of $Cr^{+6}$ remaining in the $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ pigments was also measured.
Keywords
Black ceramic pigment; Glaze; Solid state reaction; Hexavalent chromium;
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Times Cited By KSCI : 5  (Citation Analysis)
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